ELECTRORHEOLOGICAL PROPERTIES OF BIODEGRADABLE CHITOSAN/EXPANDED PERLITE COMPOSITES

Volume: 3 Number: 3 January 8, 2017
EN

ELECTRORHEOLOGICAL PROPERTIES OF BIODEGRADABLE CHITOSAN/EXPANDED PERLITE COMPOSITES

Abstract

In this study, chitosan (CS)/expanded perlite (EP) composites with different chitosan fractions (10%, 20% and 50%) were prepared by absorbing chitosan into porous networks of expanded perlite, as a new hybrid smart electrorheological (ER) material. Structural and morphological characterizations of the composites were carried out by FTIR and SEM-EDS techniques. Also, apparent density, particle size, and conductivity of the CS/EP composites were determined. Finally, the effects of electric field strength (E), shear rate, shear stress, and temperature onto ER behavior of the CS/EP/silicone oil system were investigated. The CS/EP/SO ER fluid system showed reversible electrorheological activity when subjected to external electric field strength by showing shear thinning non-Newtonian viscoelastic behavior. The yield stress value reached to 1250 Pa under E = 3 kV/mm for CS/EP3 composite. 

References

  1. Lin, KF, Hsu CY, Huang TS, Chiu WY, Lee YH, Young TH. A novel method to prepare chitosan/montmorillonite nanocomposites. Journal of Applied Polymer Science. 2005 SEP; 98: 2042-47. DOI: DOI: 10.1002/app.22401.
  2. Zhang WL, Liu YD, Choi HJ, Kim SG. Electrorheology of Graphene Oxide. ACS Appl. Mater. Inter. 2012 APR; 4: 2267-72. DOI: 10.1021/am300267f.
  3. Cabuk M, Yavuz M, Unal HI. Colloidal, electrorheological, and viscoelastic properties of polypyrrole-graft-chitosan biodegradable copolymer. J. Intel. Mat. Syst. Str. 2015 MAR; 26: 1799-810. DOI: 0.1177/1045389X15577652.
  4. Kittur FS, Prashanth KVH, Sankar KU, Tharanathan RN. Characterization of chitin, chitosan and their carboxymethyl derivatives by differential scanning calorimetry. Carbohydrate Polymers. 2002 APR; 49: 185-93. DOI: doi:10.1016/S0144-8617(01)00320-4.
  5. Hong CH, Sung JH, Choi HJ. Effects of medium oil on electroresponsive characteristics of chitosan suspensions. Colloid and Polymer Science. 2009 MAY; 287: 583-89. DOI: 10.1007/s00396-009-2006-3.
  6. Jang WH, Cho YH, Kim JW, Choi HJ, Sohn JI, Jhon MS. Electrorheological fluids based on chitosan particles. Journal of Material Science Letters. 2001; 20: 1029-31. DOI: 10.1023/A:1010960424567.
  7. Choi US, Park YS. Electrorheological behavior of chitosan adipicate suspension as anhydrous ER fluid. Journal of Industrial and Engineering Chemistry. 2001 JUL; 7: 281-4. DOI:10.1016/j.polymer.2005.10.133.
  8. Dogan M, Alkan M. Removal of methyl violet from aqueous solution by perlite. J. Colloid Interface Sci. 2003 OCT; 267: 32–41. DOI: doi:10.1016/S0021-9797(03)00579-4.

Details

Primary Language

English

Subjects

-

Journal Section

-

Publication Date

January 8, 2017

Submission Date

July 1, 2016

Acceptance Date

-

Published in Issue

Year 2016 Volume: 3 Number: 3

APA
Çabuk, M. (2017). ELECTRORHEOLOGICAL PROPERTIES OF BIODEGRADABLE CHITOSAN/EXPANDED PERLITE COMPOSITES. Journal of the Turkish Chemical Society Section A: Chemistry, 3(3), 119-130. https://doi.org/10.18596/jotcsa.26894
AMA
1.Çabuk M. ELECTRORHEOLOGICAL PROPERTIES OF BIODEGRADABLE CHITOSAN/EXPANDED PERLITE COMPOSITES. JOTCSA. 2017;3(3):119-130. doi:10.18596/jotcsa.26894
Chicago
Çabuk, Mehmet. 2017. “ELECTRORHEOLOGICAL PROPERTIES OF BIODEGRADABLE CHITOSAN EXPANDED PERLITE COMPOSITES”. Journal of the Turkish Chemical Society Section A: Chemistry 3 (3): 119-30. https://doi.org/10.18596/jotcsa.26894.
EndNote
Çabuk M (January 1, 2017) ELECTRORHEOLOGICAL PROPERTIES OF BIODEGRADABLE CHITOSAN/EXPANDED PERLITE COMPOSITES. Journal of the Turkish Chemical Society Section A: Chemistry 3 3 119–130.
IEEE
[1]M. Çabuk, “ELECTRORHEOLOGICAL PROPERTIES OF BIODEGRADABLE CHITOSAN/EXPANDED PERLITE COMPOSITES”, JOTCSA, vol. 3, no. 3, pp. 119–130, Jan. 2017, doi: 10.18596/jotcsa.26894.
ISNAD
Çabuk, Mehmet. “ELECTRORHEOLOGICAL PROPERTIES OF BIODEGRADABLE CHITOSAN EXPANDED PERLITE COMPOSITES”. Journal of the Turkish Chemical Society Section A: Chemistry 3/3 (January 1, 2017): 119-130. https://doi.org/10.18596/jotcsa.26894.
JAMA
1.Çabuk M. ELECTRORHEOLOGICAL PROPERTIES OF BIODEGRADABLE CHITOSAN/EXPANDED PERLITE COMPOSITES. JOTCSA. 2017;3:119–130.
MLA
Çabuk, Mehmet. “ELECTRORHEOLOGICAL PROPERTIES OF BIODEGRADABLE CHITOSAN EXPANDED PERLITE COMPOSITES”. Journal of the Turkish Chemical Society Section A: Chemistry, vol. 3, no. 3, Jan. 2017, pp. 119-30, doi:10.18596/jotcsa.26894.
Vancouver
1.Mehmet Çabuk. ELECTRORHEOLOGICAL PROPERTIES OF BIODEGRADABLE CHITOSAN/EXPANDED PERLITE COMPOSITES. JOTCSA. 2017 Jan. 1;3(3):119-30. doi:10.18596/jotcsa.26894

Cited By