THE GRAPHENE OXIDE EFFECT ON THE OPTICAL PROPERTIES OF NIPA-GO COMPOSITES
Abstract
Poly (N-isopropylacrylamide) (NIPA)-Graphene oxide (GO) composites were polymerizated radically with various contents of GO solution. The gelation process was performed by Steady State Fluorescence Spectroscopy. The results of gelation were modelled by Percolation and Classical Model, respectively. Our results show that the critical exponent of gel fraction is agree with percolation model till 25 µl content of GO solution. On the other hand, the optical energy band gap of the NIPA-GO composite was decided by using UV spectroscopy from the absorbance measurement in the range of 200-800 nm. The effect of graphene oxide dopant on the gap has been examined for NIPA-GO composites. In conclusion, their gelation process and optical energy band gap behavior were investigated and correlated to the GO content in the composites.
Keywords
References
- Huang Y, Zeng M, Ren J, Wang J, Fan L, Xu Q, Preparation and swelling properties of graphene oxide/poly(acrylic acid-co-acrylamide) super-absorbent hydrogel nanocomposites. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2012 May; 401: 97- 106. DOI:10.1016/j.colsurfa.2012.03.031.
- Zhang L, Wang Z, Xu C, Li Y, Gao J, Wang W, Lui Y, High strength graphene oxide/polyvinyl alcohol composite hydrogels. Journal Material Chemistry, 2011 April; 2: 10399- 10406. DOI: 10.1039/C0JM04043F.
- Shen J, Yan B, Li Ti, Long Y, Li N, Ye M, Study on graphene-oxide-based polyacrylamide composite hydrogels. Composites: Part A, 2012 September; 43: 1476- 1481. DOI:10.1016/j.compositesa.2012.04.006.
- Wang J, Liu C, Shuai Y, Cui X, Nie L, Controlled release of anticancer drug using graphene oxide as a drug-binding effector in konjac glucomannan/sodium alginate hydrogels, Colloids and Surfaces B: Biointerfaces, 2014 January; 113: 223- 229. DOI:10.1016/j.colsurfb.2013.09.009.
- Dušek K, Editor, Coexistence of Phases and the Nature of First- Order Phase Transition in Poly- N- isopropylacrylamide Gels. Hirotsu S: Advanced Polymer Science, Springer Berlin Heidelberg; 1993. 110: 1- 26 p. ISBN: 978-3-540-56970-1.
- Yang Y, Song X, Yuan L, Li M, Liu J, Ji R, Zhao H, Synthesis of PNIPAM polymer brushes on reduced graphene oxide based on click chemistry and RAFT polymerization. Journal of Polymer Science, Polymer Chemistry, 2012 October; 50: 329- 337. DOI: 10. 1002/pola.25036.
- Zhu S, Li J, Chen Y, Chen Z, Chen C, Li Y, Cui Z, Zhang D, Grafting of graphene oxide with stimuli-responsive polymers by using ATRP for drug release, Journal of Nanoparticle Research, 2012 September; 14: 1132- 42. DOI: 10.1007/s11051-012-1132-x.
- Bai H, Li C, Wang X, Shi G, A pH-sensitive graphene oxide composite hydrogel. Chemistry Communication, 2010 February; 46: 2376-78, DOI: 10.1039/C000051E.
Details
Primary Language
English
Subjects
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Journal Section
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Authors
Publication Date
January 8, 2017
Submission Date
August 19, 2016
Acceptance Date
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Published in Issue
Year 2016 Volume: 3 Number: 3
