Novel Straight-chained Sulfanyl Members of Arylamino-1,4-naphthoquinones: Synthesis and Characterization

Year 2017, , 597 - 606, 12.05.2017

Nilufer Bayrak

https://doi.org/10.18596/jotcsa.301558

Cited By: 1

Abstract

The aim of this paper is to describe the synthesis and characterization of new members of straight-chained sulfanyl derivatives of arylamino-1,4-naphthoquinones. 2-(4-(trifluoromethyl)phenylamino)-3-chloronaphthalene-1,4-dione (3a) and 2-(3-(trifluoromethyl)phenylamino)-3-chloronaphthalene-1,4-dione (3b) compounds which prepared by means of nucleophilic substitution reactions between 2,3-dichloro-1,4-naphthoquinone (1) and arylamines containing trifluoro group at meta and para positions (2a, 2b) were used as building blocks for straight-chained sulfanyl arylamino-1,4-naphthoquinones. The structures of all the novel compounds (5a-f) were established by spectroscopic evidence including IR, ¹H NMR, ¹³C NMR, and MS data.

Keywords

Sulfanyl 1, 4-naphthoquinone, Arylamine, Trifluoromethyl group

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