Binder Effect on Electrochemical Performance of Zinc Electrodes For Nickel-Zinc Batteries

Gizem Cihanoğlu; Özgenç Ebil

doi:10.18596/jotcsa.370774

EN

Binder Effect on Electrochemical Performance of Zinc Electrodes For Nickel-Zinc Batteries

Abstract

Polyethylene glycol (PEG) and polyvinyl alcohol (PVA) were used as a zinc electrode binder at different concentrations to enhance the electrochemical behavior of zinc electrodes for nickel-zinc (NiZn) batteries. ZnO powders synthesized by mechanochemical and hydrothermal precipitation methods were mixed with lead oxide, calcium hydroxideand binder to prepare zinc electrodes in pouch cell NiZn batteries. Scanning Electron Microscopy (SEM) and X-Ray Diffraction (XRD) analysis reveal that initial morphology of zinc electrode changes drastically regardless of the binder type and its loading after charge/discharge process, and even the charge/discharge process is not complete. The results show that the presence of PEG causes better discharge capacity compared to that of PVA as a binder. Zinc electrode prepared using commercial ZnO powder and 3 wt.% PEG gives the optimum discharge capability, with a specific capacity of approximately 311 mAhg^-1, while zinc electrodes prepared using ZnO powder synthesized from ZnCl₂ and Zn(NO₃)₂.6H₂O and 6 wt.% PEG exhibit high specific energy of 255 and 275 mAhg^-1, respectively. The results suggest a relationship between binder loading and battery capacity, but in-situ analysis of microstructural evolution of zinc electrode during charge/discharge process is needed to confirm this relationship.

Keywords

Zinc electrode,NiZn secondary batteries,PEG,PVA

References

1. Huang H, Zhang L, Zhang WK, Gan YP, Shao H. Preparation and electrochemical properties of ZnO/conductive-ceramic nanocomposite as anode material for Ni/Zn rechargeable battery. J Power Sources. 2008 Oct; 184:663-7. DOI: 10.1016/j.jpowsour.2008.01.004.
2. Cheng J, Zhang L, Yang YS, Wen YH, Cao GP, Wang XD. Preliminary study of single flow zinc-nickel battery. Electrochem Commun. 2007 Nov; 9:2639-42. DOI: 10.1016/j.elecom.2007.08.016.
3. Zhang XG, editor. Corrosion and Electrochemistry of Zinc. Springer; 1996. ISBN: 1475798784.
4. Huggins RA, editor. Advanced Batteries. Springer; 2009. ISBN: 9780387764238.
5. Acton QA, editor. Sulfur Acids-Advances in Research and Application: 2013 Edition. Scholarly Editions; 2013. ISBN: 978-1-481-69276-2.
6. Müeller S, Holzer F, Haas O. Optimized zinc electrode for the rechargeable zinc-air battery. J Appl Electrochem. 1998 Sept; 28: 895-8. DOI: 10.1023/A:1003464011815.
7. Yuan YF, Tu JP, Wu HM, Li Y, Shi DQ, Zhao XB. Effect of ZnO nanomaterials associated with Ca(OH)2 as anode material for Ni–Zn batteries. J Power Sources. 2006 Sept; 159:357-60. DOI: 10.1016/j.jpowsour.2006.04.010.
8. Shivkumar R, Paruthimal Kalaignan G, Vasudevan T. Studies with porous zinc electrodes with additives for secondary alkaline batteries. J Power Sources. 1998 Sept; 75:90-100. DOI: 10.1016/S0378-7753(98)00096-2.

9. McBreen J, Gannon E. The electrochemistry of metal oxide additives in pasted zinc electrodes. Electrochim Acta. 1981 Oct; 26 1439-46. DOI: 10.1016/0013-4686(81)90015-3.
10. Shivkumar R, Kalaignan GP, Vasudevan T. Effect of additives on zinc electrodes in alkaline battery systems. J Power Sources. 1995 May; 55:53-62. DOI: 10.1016/0378-7753(94)02170-8.
11. Adler TC, McLarnon FR, Cairns EJ. Low-zinc-solubility electrolytes for use in zinc/nickel oxide cells. J Electrochem Soc. 1993 Oct; 140:289-94. DOI: 10.1149/1.2221039.
12. Iwakura C, Murakami H, Nohara S, Furukawa N, Inoue H. Charge–discharge characteristics of nickel/zinc battery with polymer hydrogel electrolyte. J Power Sources. 2005 Dec; 152, 291-294. DOI: 10.1016/j.jpowsour.2005.03.175.
13. Yuan YF, Tu JP, Wu HM, Li Y, Shi DQ. Size and morphology effects of ZnO anode nanomaterials for Zn/Ni secondary batteries. Nanotechnology. 2005 Apr; 16:803-8. DOI: 10.1088/0957-4484/16/6/031.
14. Yang JL, Yuan YF, Wu HM, Li Y, Chen YB, Guo SY. Preparation and electrochemical performances of ZnO nanowires as anode materials for Ni/Zn secondary battery. Electrochim Acta. 2010 Sept; 55:7050-4. DOI: 10.1016/j.electacta.2010.06.075.
15. Perez MG, O’Keefe MJ, O’Keefe T, Ludlow D. Chemical and morphological analyses of zinc powders for alkaline batteries. J Appl Electrochem. 2006 Feb; 37:225-31. DOI: 10.1007/s10800-006-9239-3.
16. Yuan YF, Tu JP, Wu HM, Li Y, Shi DQ, Zhao XB. Effect of ZnO nanomaterials associated with Ca(OH)2 as anodematerial for Ni–Zn batteries. J Power Sources. 2006 Sept; 159:357-60. DOI: 10.1016/j.jpowsour.2006.04.010.
17. Yang CC, Chien WC, Wang CL, Wu CY. Study the effect of conductive fillers on a secondary Zn electrode based on ball-milled ZnO and Ca(OH)2 mixture powders. J Power Sources. 2007; 172:435-45. DOI: 10.1016/j.jpowsour.2007.07.053.
18. Yuan YF, Yu LQ, Wu HM, Yang JL, Chen YB, Guo YB, Tu JP. Electrochemical performances of Bi based compound film-coated ZnOas anodic materials of Ni–Zn secondary batteries. Electrochim Acta. 2011 Apr; 56:4378-83. DOI: 10.1016.j.electacta.2011.01.006.
19. Shivkumar R, Kalaignan GP, Vasudevan T. Studies with porous zinc electrodes with additives for secondary alkaline batteries. J Power Sources. 1998 Sept; 75:90–100, DOI: 10.1016/S0378-7753(98)00096-2.
20. Lee SH, Yi CW, Kim K. Characteristics and electrochemical performance of the TiO2-coated ZnO anode for Ni-Zn secondary batteries. J Phys Chem C. 2011 Dec; 115:2572–7, 2011. DOI: 10.1021/jp110308b.
21. Zeng D, Yang Z, Wang S, Ni X, Ai D, Zhang Q. Preparation and electrochemical performance of In-doped ZnO as anode material for Ni-Zn secondary cells. Electrochim Acta. 2011 Apr; 56:4075–80. DOI: 10.1016/j.electacta.2011.01.119.
22. Hilder M, Winther-Jensen B, Clark NB. The effect of binder and electrolyte on the performance of thin zinc-air battery. Electrochim Acta. 2012 May; 69:308-14. DOI:10.1016/j.electacta.2012.03.004.
23. Masri MN, Nazeri MFM, Ng CY, Mohamad AA. Tapioca binder for porous zinc anodes electrode in zinc–air batteries. J King Saud University—Engineering Sci. 2015 July; 27:217–24. DOI: 10.1016/j.jksues.2013.06.001.
24. Lee CW, Eom Sw, Sathiyanarayanan K, Yun MS. Preliminary comparative studies of zinc and zinc oxide electrodes on corrosion reaction and reversible reaction for zinc/air fuel cells. Electrochim Acta. 2006 Dec; 52:1588–91. DOI: 10.1016/j.electacta.2006.02.063.
25. Müller S, Holzer F, Haas O. Optimized zinc electrode for the rechargeable zinc-air battery. J Appl Electrochem. 1998 Sept ; 28:895–8. DOI: 10.1023/A:1003464011815.
26. Wu GM, Lin SJ, Yang CC. Alkaline Zn-air and Al-air cells based on novel solid PVA/PAA polymer electrolyte membranes. J Membr Sci. 2006 Sept; 280:802–8. DOI: 10.1016/j.memsci.2006.02.037.
27. Yang CC, Lin SJ. Alkaline composite PEO-PVA-glassfibre-mat polymer electrolyte for Zn-air battery. J Power Sources. 2002 Nov; 112:497–503. DOI: 10.1016/S0378-7753(02)00438-X.
28. Masri MN, Mohamad AA. Effect of adding potassium hydroxide to an agar binder for use as the anode in Zn-air batteries. Corros Sci. 2009 Dec; 51:3025-9. DOI: 10.1016/j.corsci.2009.08.027.
29. Ein-Eli Y, Auinat M, Starosvetsky D. Electrochemical and surface studies of zinc in alkaline solutions containing organic corrosion inhibitors. J Power Sources, 2003 Mar; 114:330-7. DOI: 10.1016/S0378-7753(02)00598-0.
30. Saleem M, Sayyad MH, Karimov KHS, Ahmad Z. Fabrication of investigation of the charge-discharge characterization of Zinc-PVA-KOH-Carbon Cell. Acta Phys Pol A. 2009 Dec; 116:1021-4. DOI: 10.12693/APhys/PolA.116.1021.
31. Wu Q, Zhang J, Sang S. Preparation of alkaline solid polymer electrolyte based on PVA–TiO2–KOH–H2O and its performance in Zn–Ni battery. J Phys and Chem Solids. 2008 Nov; 69, 2691-5. DOI: 10.1016/j.jpcs.2008.06.132.
32. Payer G, Ebil Ö. Zinc electrode morphology evolution in high energy density nickel-zinc batteries. J Nanomater. 2016 Feb; 2016:1-9. DOI: 10.1155/2016/1280236.
33. Brett CMA, Brett AMO, editor. Electrochemistry: Priciples, Methods, and Applications. Oxford University Press; 1994. ISBN: 978-0198553885.
34. Gileadi E, editor. Electrode Kinetic for Chemists, Chemical Engineers, and Materials Scientists. John Wiley & Sons; 1993. ISBN: 978-0-471-18858-2.
35. Minakshi M, Appadoo D, Martin DE. The anodic behavior of planar and porous zinc electrodes in alkaline electrolyte. Elctrochem Solid-State Lett. 2010 Jan; 13:A77-80. DOI: 10.1149/1.3387672.
36. Chen T, Pan L, Loh TAJ, Chua DHC, Yao Y, Chen Q, Li D, Qin W, Sun Z. Porous nitrogen-doped carbon microspheres as anode materials for lithium ion batteries. Dalton Trans. 2014 Jun; 43:14931-3-5. DOI: 10.1039/C4DT01223B.

Details

Primary Language

English

Subjects

Engineering, Chemical Engineering

Journal Section

Research Article

Authors

Gizem Cihanoğlu This is me
Türkiye

Özgenç Ebil ^* This is me
Türkiye

Publication Date

December 15, 2017

Submission Date

December 11, 2017

Acceptance Date

December 23, 2017

Published in Issue

Year 2018 Volume: 5 Number: 1

DOI

https://doi.org/10.18596/jotcsa.370774

IZ

https://izlik.org/JA93XX46SS

Cite

RIS / Bibtex

APA

Cihanoğlu, G., & Ebil, Ö. (2017). Binder Effect on Electrochemical Performance of Zinc Electrodes For Nickel-Zinc Batteries. Journal of the Turkish Chemical Society Section A: Chemistry, 5(1), 65-84. https://doi.org/10.18596/jotcsa.370774

AMA

1.Cihanoğlu G, Ebil Ö. Binder Effect on Electrochemical Performance of Zinc Electrodes For Nickel-Zinc Batteries. JOTCSA. 2017;5(1):65-84. doi:10.18596/jotcsa.370774

Chicago

Cihanoğlu, Gizem, and Özgenç Ebil. 2017. “Binder Effect on Electrochemical Performance of Zinc Electrodes For Nickel-Zinc Batteries”. Journal of the Turkish Chemical Society Section A: Chemistry 5 (1): 65-84. https://doi.org/10.18596/jotcsa.370774.

EndNote

Cihanoğlu G, Ebil Ö (December 1, 2017) Binder Effect on Electrochemical Performance of Zinc Electrodes For Nickel-Zinc Batteries. Journal of the Turkish Chemical Society Section A: Chemistry 5 1 65–84.

IEEE

[1]G. Cihanoğlu and Ö. Ebil, “Binder Effect on Electrochemical Performance of Zinc Electrodes For Nickel-Zinc Batteries”, JOTCSA, vol. 5, no. 1, pp. 65–84, Dec. 2017, doi: 10.18596/jotcsa.370774.

ISNAD

Cihanoğlu, Gizem - Ebil, Özgenç. “Binder Effect on Electrochemical Performance of Zinc Electrodes For Nickel-Zinc Batteries”. Journal of the Turkish Chemical Society Section A: Chemistry 5/1 (December 1, 2017): 65-84. https://doi.org/10.18596/jotcsa.370774.

JAMA

1.Cihanoğlu G, Ebil Ö. Binder Effect on Electrochemical Performance of Zinc Electrodes For Nickel-Zinc Batteries. JOTCSA. 2017;5:65–84.

MLA

Cihanoğlu, Gizem, and Özgenç Ebil. “Binder Effect on Electrochemical Performance of Zinc Electrodes For Nickel-Zinc Batteries”. Journal of the Turkish Chemical Society Section A: Chemistry, vol. 5, no. 1, Dec. 2017, pp. 65-84, doi:10.18596/jotcsa.370774.

Vancouver

1.Gizem Cihanoğlu, Özgenç Ebil. Binder Effect on Electrochemical Performance of Zinc Electrodes For Nickel-Zinc Batteries. JOTCSA. 2017 Dec. 1;5(1):65-84. doi:10.18596/jotcsa.370774

Cited By

https://doi.org/

Characteristics of Ni-Zn Rechargeable Batteries with Zn Anode Prepared by Using Nano-Cellulose as its Binder Agent

Materials Science Forum

https://doi.org/10.4028/www.scientific.net/MSF.1028.105

Triethanolamine-modified binder with synergistic effects on Zn anode in improving the cycling stability of aqueous rechargeable Zn Ni batteries

Journal of Energy Storage

https://doi.org/10.1016/j.est.2023.108430

Advanced Polymeric Binders in Aqueous Zinc Ion Batteries: Dynamic Diselenide Bonds as Unique Cofactors for Improving Redox Kinetics

ACS Sustainable Chemistry & Engineering

https://doi.org/10.1021/acssuschemeng.4c08335