METAL-ORGANIC FRAMEWORKS (MOFs) DERIVED FROM CARBOXYLATE LIGAND AS POTENTIAL MATERIALS FOR REMEDIATION OF Cu (II) AND Pb (II) FROM AQUEOUS SOLUTION

Year 2019, , 165 - 176, 15.06.2019

Hussein Kehinde Okoro , Oluwaseyi Ayika Adedibu Tella , Jane Ngila

https://doi.org/10.18596/jotcsa.454010

Cited By: 2

Abstract

The remediation of cadmium and lead ions from their respective aqueous solutions was carried out with the use of metal-organic frameworks (MOFs) developed from copper and zinc with benzene-1,4-dicarboxylic acid (BDC). The experimental adsorption process was done in batches to determine the equilibrium characteristics, thermodynamics and kinetics of the sorption processes. The result was then tested using Langmuir, Freundlich, and Temkin isotherm equations with Langmuir being the best fitted isotherm, while the kinetics isotherm used were pseudo first order and pseudo second order. The result obtained shows that the MOFs are great potential adsorbent for the studied metals.

Keywords

Metal-Organic Frameworks, Lead, Copper

References

• 1. Okoro HK, Ige JO, Iyiola OA, Ngila JC. Fractionation profile, mobility patterns and correlations of heavy metals in estuary sediments from olonkoro river, in tede catchment of western region, Nigeria. Environmental nanotechnology, monitoring & management. 2017;8:53–62.
• 2. Gielar A, Helios-Rybicka E, Möller S, Einax JW. Multivariate analysis of sediment data from the upper and middle Odra River (Poland). Applied Geochemistry. 2012;27(8):1540–5.
• 3. Mobasherpour I, Salahi E, Asjodi A. Research on the batch and fixed-bed column performance of red mud adsorbents for lead removal. soil and water. 2014;4:5.
• 4. Okoro HK, Adeyinka A, Jondiko OE, Ximba BJ. Physico-chemical analysis of selected groundwater samples of Ilorin town in Kwara State, Nigeria. Scientific Research and Essays. 2012;7(23):2063–9.
• 5. Aguayo-Villarreal IA, Bonilla-Petriciolet A, Hernández-Montoya V, Montes-Morán MA, Reynel-Avila HE. Batch and column studies of Zn2+ removal from aqueous solution using chicken feathers as sorbents. Chemical Engineering Journal. 2011;167(1):67–76.
• 6. Venkatesham V, Madhu G, Satyanarayana S, Preetham H. Adsorption of lead on gel combustion derived nano ZnO. Procedia Engineering. 2013;51:308–13.
• 7. Yang H, Rose N. Distribution of Hg inthe lake sediments across the UK. Science of the Total Environment. 2003;304:391–404.
• 8. Okoro HK, Fatoki OS, Adekola FA, Ximba BJ, Snyman RG. Geochemical assessment of sediment in Cape Town harbour, South Africa. Bulletin of the Chemical Society of Ethiopia. 2014;28(1):17–28.
• 9. Okoro H, Alao S, Adebayo G, Basheer K. Evaluation of heavy and trace metals in fingernails of young school children and adults in Ilorin, Kwara State, Nigeria. Journal of Applied Sciences and Environmental Management. 2015;19(2):319–24.
• 10. Aman T, Kazi AA, Sabri MU, Bano Q. Potato peels as solid waste for the removal of heavy metal copper (II) from waste water/industrial effluent. Colloids and Surfaces B: Biointerfaces. 2008;63(1):116–21.
• 11. Paknikar K, Pethkar A, Puranik P. Bioremediation of metalliferous wastes and products using inactivated microbial biomass. 2003;
• 12. Kuppler RJ, Timmons DJ, Fang Q-R, Li J-R, Makal TA, Young MD, et al. Potential applications of metal-organic frameworks. Coordination Chemistry Reviews. 2009 Dec;253(23–24):3042–66.
• 13. Li Z, Ma Z, van der Kuijp TJ, Yuan Z, Huang L. A review of soil heavy metal pollution from mines in China: Pollution and health risk assessment. Science of The Total Environment. 2014 Jan;468–469:843–53.
• 14. Sagar T, Shah P. Adsorptive Removal of Hazardous Waste Materials using Metal-Organic Frameworks. In 2014. p. 469–71.
• 15. Ruyra À, Yazdi A, Espín J, Carné-Sánchez A, Roher N, Lorenzo J, et al. Synthesis, Culture Medium Stability, and In Vitro and In Vivo Zebrafish Embryo Toxicity of Metal-Organic Framework Nanoparticles. Chemistry - A European Journal. 2015 ubat;21(6):2508–18.
• 16. Mahata P, Ramya KV, Natarajan S. Synthesis, structure and optical properties of rare-earth benzene carboxylates. Dalton Transactions. 2007;(36):4017.
• 17. Sajid M, Ilyas M, Basheer C, Tariq M, Daud M, Baig N, et al. Impact of nanoparticles on human and environment: review of toxicity factors, exposures, control strategies, and future prospects. Environmental Science and Pollution Research. 2015 Mar;22(6):4122–43.
• 18. Adediran G, Tella A, Mohammed H. Adsorption of Pb, Cd, Zn, Cu and Hg ions on Formaldehyde and Pyridine Modified Bean Husks. Journal of Applied Sciences and Environmental Management [Internet]. 2010 Jun 1 [cited 2019 Apr 4];11(2). Available from: http://www.ajol.info/index.php/jasem/article/view/55019
• 19. Pally N. Synthesis and Structures of New Three-Dimensional Copper Metal-Organic Frameworks [Internet] [Master of Science Thesis]. [Kentucky, USA]: Western Kentucky University; 2013. Available from: http://digitalcommons.wku.edu/theses/1295
• 20. Ryder MR, Tan J-C. Nanoporous metal organic framework materials for smart applications. Materials Science and Technology. 2014 Nov;30(13):1598–612.
• 21. Tella AC, Owalude SO, Olatunji SJ, Adimula VO, Elaigwu SE, Alimi LO, et al. Synthesis of zinc-carboxylate metal-organic frameworks for the removal of emerging drug contaminant (amodiaquine) from aqueous solution. Journal of Environmental Sciences. 2018 Feb;64:264–75.
• 22. Jimoh T, Buoro A, Muriana M. Utilization of Blighia sapida (Akee apple) pod in the removal of lead, cadmium and cobalt ions from aqueous solution. JECE. 2012 Jul;4(10):178–87.
• 23. Afkhami A, Saber-Tehrani M, Bagheri H. Simultaneous removal of heavy-metal ions in wastewater samples using nano-alumina modified with 2,4-dinitrophenylhydrazine. Journal of Hazardous Materials. 2010 Sep;181(1–3):836–44.
• 24. Shooto N, Dikio E, Wankasi D, SIKHWIVHILU L. Synthesis, Morphology and Lead Ion Adsorption Properties of Metal Organic Frameworks of Copper and Cobalt. CSJ. 2015;6(4):1000113.
• 25. Barka N, Ouzaouit K, Abdennouri M, Makhfouk ME. Dried prickly pear cactus (Opuntia ficus indica) cladodes as a low-cost and eco-friendly biosorbent for dyes removal from aqueous solutions. Journal of the Taiwan Institute of Chemical Engineers. 2013 Jan;44(1):52–60.
• 26. Ajmal M, Rao RAK, Ahmad R, Ahmad J. Adsorption studies on Citrus reticulata (fruit peel of orange): removal and recovery of Ni(II) from electroplating wastewater. Journal of Hazardous Materials. 2000 Dec;79(1–2):117–31.
• 27. Demirbas E, Kobya M, Konukman AES. Error analysis of equilibrium studies for the almond shell activated carbon adsorption of Cr(VI) from aqueous solutions. Journal of Hazardous Materials. 2008 Jun;154(1–3):787–94.
• 28. Okoli I. Adsorption Studies of Heavy Metals by Low-Cost Adsorbents. JASEM. 2014;18(3):443–8.
• 29. Dikio E, Farah A. Synthesis, Characterization and Comparative Study of Copper and Zinc Metal Organic Frameworks. Chemical Science Transactions. 2013 Oct 4;2(4):1386–94.
• 30. Wu Y, Zhang B, Li F, Zhu W, Xu D, Hannam P, et al. Electrospun fibrous mats as a skeleton for fabricating hierarchically structured materials as sorbents for Cu2+. Journal of Materials Chemistry. 2012;22(11):5089