Hydrothermal Synthesis and Crystal Structure of Zn(II) Coordination Polymer with the Rigid 4,4'-azobispyridine

Year 2020, , 43 - 48, 15.02.2020

Figen Arslan Biçer

https://doi.org/10.18596/jotcsa.536258

Cited By: 3

Abstract

The new metal complex with phenylsuccinic acid (H₂psa)
and 4,4'-azobispyridine (4,4’-abpy), {[Zn(psa)(H₂O)₃(µ-4,4'-abpy)](H₂O)}_n
(I), was synthesized by hydrothermally process. The
structure of I has been characterized
by IR spectra, elemental analysis, and single crystal X-ray diffraction. Single
crystal X-ray analysis reveals that the psa ligand O-coordinated to the Zn(II)
ion and distorted octahedral geometry of Zn(II) ion is completed by bridging
4,4’-abpy and three aqua ligands.

Keywords

Coordination polymers, 4'-azobispyridine, phenyl succinic acid

Project Number

KBÜBAP-18-YL-060

References

• 1. Zhang J-P, and Chen X-M. Metal–Organic Frameworks for Second-Order Nonlinear Optics. Struct Bond. 2014; 157:1–26.
• 2. Leong WL, and Vittal JJ. One-Dimensional Coordination Polymers: Complexity and Diversity in Structures, Properties, and Applications. Chem. Rev. 2011; 111:688–764.
• 3. Janiak C, and Vieth JK. MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs). New J. Chem., 2010; 34:2366–2388.
• 4. Li B, Liu H, Xu Y, Chen J, Wang H, Xu Z. Synthesis and crystal structure of two cobalt complexes: [Co2(4,4′-azpy)5(H2O)6][ClO4]4·(H2O)10·(4,4′-azpy)4 with a novel two-dimensional large rectangle organic–inorganic hybrid network and one-dimensional chain complex {[Co(3,3′-azpy)(H2O)4][ClO4]2·[3,3′-azpy]3}n (4,4′-azpy4,4′-azobispyridine, 3,3′-azpy3,3′-azobispyridine).J. Mol. Struct. 2001; 597:21-30.
• 5. Dey R, Ghoshal D. Syntheses and characterization of two supramolecular self-assembled Mn(II) compounds using trans 4,4′-azobispyridine as a bridging ligand: Effect of π–π interactions in the formation of a solid-state structure. Polyhedron. 2012; 34:24-30.
• 6. Theilmann O, Saak W, Haase D, Beckhaus R. Reactions of Low-Valent Titanocene(II) Fragments with trans-4,4′-Azobispyridine (RN═NR, R = C5H4N): Formation of Tetranuclear Molecular Squares by trans−cis Isomerization. Organometallics. 2009; 28:2799-2807.
• 7. Arslan F. Synthesis, crystal structure and spectrothermal characterization of zinc(II) salicylato complex with 2,2′-azobispyridine, [Zn(Hsal)2(H2O)(abpy)]·H2O. Dyes and Pigments. 2007; 75:521-525.
• 8. Zhuang Z, Cheng J, Wang X, Yin Y, Chen G, Zhao B, Zhang H, Zhang G. Spectroscopy of 4,4′-azopyridine by density functional theory and surface-enhanced Raman scattering. J. Mol. Struct. 2006; 794:77-82.
• 9. Noro S, Kitagawa S, Nakamura T, Wada T. Synthesis and Crystallographic Characterization of Low-Dimensional and Porous Coordination Compounds Capable of Supramolecular Aromatic Interaction Using the 4,4‘-Azobis(pyridine) Ligand. Inorg. Chem. 2005; 44:3960-3971.
• 10. Zhuang Z, Shanga X, Wanga X, Ruana W, Zhaoa B. Density functional theory study on surface-enhanced Raman scattering of 4,4′-azopyridine on silver. Spectrochim. Acta Part A. 2009; 72:954-958.
• 11. Niu Y, Song Y, Hou H, Zhu Y. The syntheses, crystal structures and optical limiting effects of HgI2 adduct polymers bridged by bipyridyl-based ligands. Inorganica Chimica Acta. 2003; 355:151-156.
• 12. Launay J, Tourrel-Pagis M, Lipskier J, Marvaud V, Joachim C. Control of intramolecular electron transfer by a chemical reaction. The 4,4'-azopyridine/1,2-bis(4-pyridyl)hydrazine system. Inorg. Chem. 1991; 30:1033-1038.
• 13. Thuery P. Uranyl–organic bilayer assemblies with flexible aromatic di-, tri- and tetracarboxylic acids. CrystEngComm, 2009, 11:1081-1088.
• 14. Hu S, Zhang P, Yu F-Y, Lin D-R, Chen M-X. Constructions of two photoluminescent 3D coordination polymers comprising of hydroxide-bridged cadmium chain and polynuclear cadmium macrocycle using phenylsuccinic acid. J. Mol. Struct. 2013; 1051:72-77.
• 15. Baldwin D A, Lever A B P, Parish R V. Complexes of 2,2'-azopyridine with iron(II), cobalt(II), nickel(II), copper(I), and copper(II). Infrared study. Inorg. Chem. 1969; 8(1):107-115.
• 16. a) Sheldrick G M, SHELX97, Programs for Crystal Structure Analysis (release 97–1), University of Göttingen, Germany, 1997; b) Sheldrick G M, SHELXL97, Program for the Refinement of Crystal Structures, University of Göttingen, Germany, 1997.
• 17. Gomez G E, Bernini M C, Brusau E V, Narda G E, Vega D, Kaczmarek A M, Van Deun R, Nazzarro M. Layered exfoliable crystalline materials based on Sm-, Eu- and Eu/Gd-2-phenylsuccinate frameworks. Crystal structure, topology and luminescence properties. Dalton Trans., 2015; 44:3417-3429.
• 18. Wang J, Zhang Y, Liu X-Q, Xiao J, Zhou H, Yuan A-H. Two Zn(II) and Co(II) compounds with dicarboxylates and curved 4,4′-azopyridine ligands: Syntheses, crystal structures and gas sorption properties. Microporous and Mesoporous Materials. 2012; 159:100-104.