Research Article

Effect of Calcium Stearate on the Thermal Conductivity of Geopolymer Foam

Volume: 7 Number: 2 June 23, 2020
EN

Effect of Calcium Stearate on the Thermal Conductivity of Geopolymer Foam

Abstract

Geopolymers are considered an alternative to conventional cement recently. The use of fly ash and blast furnace slag in geopolymer, which are waste products considered as an environmentally friendly product due to the solution to the storage of wastes also. Geopolymer concrete production is also reported to be 44-64% less than the cement that causes the most CO2 emissions. CO2 emissions are reduced due to the minimum processed natural minerals and industrial waste products used in the geopolymer system. For this reason, this study comes to the fore in terms of the evaluation of wastes. Production of porous geopolymers is potential in use in many industrial applications such as filtering, thermal insulation, light structural material, and catalysis. By controlling the pore type, pore size distribution, pore connectivity, and shape of porosities, potential usages are differentiated. In this study, closed porosity geopolymer foams were produced by the geopolymerization technique with the help of hydrogen peroxide and calcium stearate (CaS) as a surfactant. The thermal conductivity, density, and strength values was correlated with the changing pore size distribution depending on the amount of surfactant and foaming agent. In this study, porous geopolymers with density values 450-500 kg/m3, 0.069 W/mK thermal conductivity, and 2.1 MPa strength value was reached. The reduction in pore sizes due to CaS increase was analyzed. However, we did not observe a decrease in thermal conductivity values due to the reduction of the pore size. Exciting results for CaS content on thermal conductivity were reported.

Keywords

Supporting Institution

Afyon Kocatepe Üniversitesi

Project Number

19.Fen.Bil.01 BAP

Thanks

A part of this study was presented orally in 4th International Powder and Porous Materials Symposium 09-11 September, 2019, Marmaris, Turkey. This work was financially supported by Afyon Kocatepe University under the contract of 19.Fen.Bil.01 BAP Project and also it is supported by a TUBİTAK project 218M778.

References

  1. 1. Duxson P, Fernández-Jiménez A, Provis JL, Lukey GC, Palomo A, Van Deventer JSJ. Geopolymer technology: The current state of the art. J Mater Sci. 2007;42(9):2917–33.
  2. 2. Dhananjay KP, V V. Fly Ash as Sustainable Material for Green Concrete - A State of Art. Int J Res Eng Sci Technol. 2015;1(2):17–24.
  3. 3. Petrillo A, Cioffi R, Ferone C, Colangelo F, Borrelli C. Eco-sustainable Geopolymer Concrete Blocks Production Process. Agric Agric Sci Procedia [Internet]. 2016;8:408–18. Available from: http://linkinghub.elsevier.com/retrieve/pii/S2210784316300377
  4. 4. Duran Atiş C, Bilim C, Çelik Ö, Karahan O. Influence of activator on the strength and drying shrinkage of alkali-activated slag mortar. Constr Build Mater. 2009;23(1):548–55.
  5. 5. Çevik S. The Effect of Oil Consumption and Oil Prices on CO2 Emissions in the Industrial Sector. 2017;19(4):93–110.
  6. 6. Dean, B., Dulac, J., Petrichenko, K., and Graham P. Towards a zero-emission, efficient, and resilient buildings and construction sector. In: Global Status Report [Internet]. 2016. p. 1–48. Available from: https://www.worldgbc.org/sites/default/files/UNEP 188_GABC_en (web).pdf
  7. 7. Abdollahnejad Z, Pacheco-Torgal F, Félix T, Tahri W, Barroso Aguiar J. Mix design, properties and cost analysis of fly ash-based geopolymer foam. Constr Build Mater [Internet]. 2015;80(May 2010):18–30. Available from: http://dx.doi.org/10.1016/j.conbuildmat.2015.01.063
  8. 8. Jiménez Rivero A, De Guzmán Báez A, Navarro JG. New composite gypsum plaster - Ground waste rubber coming from pipe foam insulation. Constr Build Mater. 2014;55(2014):146–52.

Details

Primary Language

English

Subjects

Polymer Science and Technologies

Journal Section

Research Article

Publication Date

June 23, 2020

Submission Date

December 17, 2019

Acceptance Date

May 18, 2020

Published in Issue

Year 2020 Volume: 7 Number: 2

APA
Kurtulus, C., & Başpınar, M. S. (2020). Effect of Calcium Stearate on the Thermal Conductivity of Geopolymer Foam. Journal of the Turkish Chemical Society Section A: Chemistry, 7(2), 535-544. https://doi.org/10.18596/jotcsa.660727
AMA
1.Kurtulus C, Başpınar MS. Effect of Calcium Stearate on the Thermal Conductivity of Geopolymer Foam. JOTCSA. 2020;7(2):535-544. doi:10.18596/jotcsa.660727
Chicago
Kurtulus, Cansu, and Mustafa Serhat Başpınar. 2020. “Effect of Calcium Stearate on the Thermal Conductivity of Geopolymer Foam”. Journal of the Turkish Chemical Society Section A: Chemistry 7 (2): 535-44. https://doi.org/10.18596/jotcsa.660727.
EndNote
Kurtulus C, Başpınar MS (June 1, 2020) Effect of Calcium Stearate on the Thermal Conductivity of Geopolymer Foam. Journal of the Turkish Chemical Society Section A: Chemistry 7 2 535–544.
IEEE
[1]C. Kurtulus and M. S. Başpınar, “Effect of Calcium Stearate on the Thermal Conductivity of Geopolymer Foam”, JOTCSA, vol. 7, no. 2, pp. 535–544, June 2020, doi: 10.18596/jotcsa.660727.
ISNAD
Kurtulus, Cansu - Başpınar, Mustafa Serhat. “Effect of Calcium Stearate on the Thermal Conductivity of Geopolymer Foam”. Journal of the Turkish Chemical Society Section A: Chemistry 7/2 (June 1, 2020): 535-544. https://doi.org/10.18596/jotcsa.660727.
JAMA
1.Kurtulus C, Başpınar MS. Effect of Calcium Stearate on the Thermal Conductivity of Geopolymer Foam. JOTCSA. 2020;7:535–544.
MLA
Kurtulus, Cansu, and Mustafa Serhat Başpınar. “Effect of Calcium Stearate on the Thermal Conductivity of Geopolymer Foam”. Journal of the Turkish Chemical Society Section A: Chemistry, vol. 7, no. 2, June 2020, pp. 535-44, doi:10.18596/jotcsa.660727.
Vancouver
1.Cansu Kurtulus, Mustafa Serhat Başpınar. Effect of Calcium Stearate on the Thermal Conductivity of Geopolymer Foam. JOTCSA. 2020 Jun. 1;7(2):535-44. doi:10.18596/jotcsa.660727

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