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The Effect of the Hydrothermal and Thermal Deactivations on the Adsorptive Properties and Liquid Permeability of a Silica Gel

Year 2021, , 477 - 482, 31.05.2021
https://doi.org/10.18596/jotcsa.753130

Abstract

Three samples taken from a silica gel Hypersil were hydrothermally treated, washed and dried under different conditions. The portions from the obtained samples were heated over a temperature range of 300 and 850 °C for 16 h. Surface area and pore volume all of the treated samples were respectively determined by nitrogen adsorption data at 77 K and mercury porosimetry. The volumetric flow rate and permeability of the isopropyl alcohol on the columns filled with the prepared samples were determined depending both the inlet pressure and packing pressure. The optimum conditions to prepare a column filling materials with the heights permeability were discussed.

Supporting Institution

Ankara University Research Fund

Project Number

16L043013

Thanks

The authors are thankful to the Edinburgh University for experimental support and the Ankara University Research Fund (Project No: 16L043013) for financial support to this work.

References

  • 1. Scott RPW, Kucera P. Some aspect of the chromatographic properties of thermally modified silica gel. Journal of Chromatographic Science 1975;13:337-43.
  • 2. Du Fresne von Hohenesche C, Ehwald V, Unger KK. Development of standardoperation procedures for the manufacture of n-octadecyl bonded silicas as packing material in certified reference columns for reserved-phase liquid chromatography. Journal of Chromatography A 2004;1025:177-87.
  • 3. Skudas R, Grimes BA, Thommes M, Unger KK. Flow-through pore characteristics of monolithic silicas and their impact on column performance in high-performance liquid chromatography. Journal of Chromatography A 2009;1216:2625-36.
  • 4. Shirasaka H, Shimonosono T, Hirata Y, Sameshima S. Analysis of gas permeability of porous alumina powder compacts. Journal of Asian Ceramic Societies 2013;1:368-73.
  • 5. Rouquerol F, Rouquerol J, Sing KSW, Llewellyn P, Maurin G. Adsorption by powders and porous solids. Elsevier; 2014.
  • 6. Choi J, Fujita H, Ogura M, Sakoda A. Confinement effect on enthalpy of fusion and melting point of organic phase change materials in cylindrical nanoscape of mesoporous silica and carbon. Adsorption 2018;24:345-55.
  • 7. Ding H, Li J, Gao Y, Zhao D, Shi D, Mao G, Liu S, Tan X. Preparation of silica nanoparticles from waste silicon sludge. Powder Technology 2015;284;231-6.
  • 8. Li J, Xu L, Zheng N, Wang H, Lu F, Li S. Biomimetic synthesized bimodal nanoporous silica: Bimodal mesostructure formation and application for ibuprofen delivery. Materials Science and Engineering C 2016;58:1105-11.
  • 9. Temuujin J, Okada K, MacKenzie KJD. Preparation of porous silica from vermiculite by selective leaching. Applied Clay Science 2003;22:187-95.
  • 10. Hu X, Yan X, Zhou M, Komarneni S. One-step synthesis of nanostructured mesoporous ZIF-8/silica composites. Microporous and Mesoporous Materials 2016;219:311-6.
  • 11. Krasucka P, Stefaniak W, Kierys A, Goworek J. One-pot synthesis of two different highly porous silica materials. Microporous and Mesoporous Materials 2016;221:14-22.
  • 12. Lee BI, Quesnel E. Low density silica gels and solvent permeability. Journal of the European Ceramic Society 1998;18:123-9.
  • 13. Klotz M, Ayral A, Guizard C, Cot L. Synthesis and characterization of silica membranes exhibiting an ordered mesoporosity. Control of the porous texture and effect on the membrane permeability. Separation and Purification Technology 2001;25:71-8.
  • 14. Azzouz I, Essoussi A, Fleury J, Haudebourg R., Thiebaut D, Vial J. Feasibility of the preparation of silica monoliths for gas chromatography: Fast separation of light hydrocarbons. Journal of Chromatography A 2015;1383:127-33.
  • 15. Beygi H, Karimi EZ, Farazi R, Ebrahimi F. A statistical approach to synthesis of functionally modified silica nanoparticles. Journal of Alloys and Compounds 2016;654:308-14.
  • 16. Kato N, Kato N. High-yield hydrothermal synthesis of mesoporous silica hollow capsules. Microporous and Mesoporous Materials 2016;219:230-9.
  • 17. Scherer GW. Effect of drying on properties of silica gel. Journal of Non-Crystalline Solids 1997;215:155-68.
  • 18. Gunawan S, Ismadji S, Ju Y-H. Design and operation of a modified silica gel column chromatography. Journal of the Chinese Institute of Chemical Engineers 2008;39;625-33.
  • 19. Mignot M, Sebban M, Tchapla A, Mercier O, Cardinael P, PeulonAgasse V. Thermal pretreatments of superficially porous silica particles for high-performance liquid chromatography: Surface control, structural characterization and chromatographic evaluation. Journal of Chromatography A 2015;1419:45-57.
  • 20. Sarıkaya Y, Ceylan H, Önal M, Pekdemir AD. Thermal deactivation kinetics and thermodynamics of a silica gel using surface area data. Journal of Thermal Analysis and Calorimetry 2021;doi.org/10.1007/s10973-020-10132-z.
  • 21. Cherrak DE, Al-Bokari M, Drumm EC, Guiochon G. Behavior of packing materials in axially compressed chromatographic columns. Journal of Chromatography A 2001;943:15-31.
  • 22. Núñez O, Nakanishi K, Tanaka N, Preparation of monolithic silica columns for high-performance liquid chromatography. Journal of Chromatography A 2008;1191:231-52.
  • 23. Hara T, Makino S, Watanabe Y, Ikegami T, Cabrera K, Smarsly B, Tanaka N. The performance of hybrid monolithic capillary columns prepared by changing feed ratios of tetramethoxysilane and methyltrimethoxysilane. Journal of Chromatography A2010;1217:89-98.
  • 24. Anisah S, KanezashiM, Nagasawa H, Tsuru T. Hydrothermal stability and properties of TiO2-ZrO2 (5/5) nanofiltration membranes at high temperatures. Separation and Purification Technology 2019; 212:1001-12.
Year 2021, , 477 - 482, 31.05.2021
https://doi.org/10.18596/jotcsa.753130

Abstract

Project Number

16L043013

References

  • 1. Scott RPW, Kucera P. Some aspect of the chromatographic properties of thermally modified silica gel. Journal of Chromatographic Science 1975;13:337-43.
  • 2. Du Fresne von Hohenesche C, Ehwald V, Unger KK. Development of standardoperation procedures for the manufacture of n-octadecyl bonded silicas as packing material in certified reference columns for reserved-phase liquid chromatography. Journal of Chromatography A 2004;1025:177-87.
  • 3. Skudas R, Grimes BA, Thommes M, Unger KK. Flow-through pore characteristics of monolithic silicas and their impact on column performance in high-performance liquid chromatography. Journal of Chromatography A 2009;1216:2625-36.
  • 4. Shirasaka H, Shimonosono T, Hirata Y, Sameshima S. Analysis of gas permeability of porous alumina powder compacts. Journal of Asian Ceramic Societies 2013;1:368-73.
  • 5. Rouquerol F, Rouquerol J, Sing KSW, Llewellyn P, Maurin G. Adsorption by powders and porous solids. Elsevier; 2014.
  • 6. Choi J, Fujita H, Ogura M, Sakoda A. Confinement effect on enthalpy of fusion and melting point of organic phase change materials in cylindrical nanoscape of mesoporous silica and carbon. Adsorption 2018;24:345-55.
  • 7. Ding H, Li J, Gao Y, Zhao D, Shi D, Mao G, Liu S, Tan X. Preparation of silica nanoparticles from waste silicon sludge. Powder Technology 2015;284;231-6.
  • 8. Li J, Xu L, Zheng N, Wang H, Lu F, Li S. Biomimetic synthesized bimodal nanoporous silica: Bimodal mesostructure formation and application for ibuprofen delivery. Materials Science and Engineering C 2016;58:1105-11.
  • 9. Temuujin J, Okada K, MacKenzie KJD. Preparation of porous silica from vermiculite by selective leaching. Applied Clay Science 2003;22:187-95.
  • 10. Hu X, Yan X, Zhou M, Komarneni S. One-step synthesis of nanostructured mesoporous ZIF-8/silica composites. Microporous and Mesoporous Materials 2016;219:311-6.
  • 11. Krasucka P, Stefaniak W, Kierys A, Goworek J. One-pot synthesis of two different highly porous silica materials. Microporous and Mesoporous Materials 2016;221:14-22.
  • 12. Lee BI, Quesnel E. Low density silica gels and solvent permeability. Journal of the European Ceramic Society 1998;18:123-9.
  • 13. Klotz M, Ayral A, Guizard C, Cot L. Synthesis and characterization of silica membranes exhibiting an ordered mesoporosity. Control of the porous texture and effect on the membrane permeability. Separation and Purification Technology 2001;25:71-8.
  • 14. Azzouz I, Essoussi A, Fleury J, Haudebourg R., Thiebaut D, Vial J. Feasibility of the preparation of silica monoliths for gas chromatography: Fast separation of light hydrocarbons. Journal of Chromatography A 2015;1383:127-33.
  • 15. Beygi H, Karimi EZ, Farazi R, Ebrahimi F. A statistical approach to synthesis of functionally modified silica nanoparticles. Journal of Alloys and Compounds 2016;654:308-14.
  • 16. Kato N, Kato N. High-yield hydrothermal synthesis of mesoporous silica hollow capsules. Microporous and Mesoporous Materials 2016;219:230-9.
  • 17. Scherer GW. Effect of drying on properties of silica gel. Journal of Non-Crystalline Solids 1997;215:155-68.
  • 18. Gunawan S, Ismadji S, Ju Y-H. Design and operation of a modified silica gel column chromatography. Journal of the Chinese Institute of Chemical Engineers 2008;39;625-33.
  • 19. Mignot M, Sebban M, Tchapla A, Mercier O, Cardinael P, PeulonAgasse V. Thermal pretreatments of superficially porous silica particles for high-performance liquid chromatography: Surface control, structural characterization and chromatographic evaluation. Journal of Chromatography A 2015;1419:45-57.
  • 20. Sarıkaya Y, Ceylan H, Önal M, Pekdemir AD. Thermal deactivation kinetics and thermodynamics of a silica gel using surface area data. Journal of Thermal Analysis and Calorimetry 2021;doi.org/10.1007/s10973-020-10132-z.
  • 21. Cherrak DE, Al-Bokari M, Drumm EC, Guiochon G. Behavior of packing materials in axially compressed chromatographic columns. Journal of Chromatography A 2001;943:15-31.
  • 22. Núñez O, Nakanishi K, Tanaka N, Preparation of monolithic silica columns for high-performance liquid chromatography. Journal of Chromatography A 2008;1191:231-52.
  • 23. Hara T, Makino S, Watanabe Y, Ikegami T, Cabrera K, Smarsly B, Tanaka N. The performance of hybrid monolithic capillary columns prepared by changing feed ratios of tetramethoxysilane and methyltrimethoxysilane. Journal of Chromatography A2010;1217:89-98.
  • 24. Anisah S, KanezashiM, Nagasawa H, Tsuru T. Hydrothermal stability and properties of TiO2-ZrO2 (5/5) nanofiltration membranes at high temperatures. Separation and Purification Technology 2019; 212:1001-12.
There are 24 citations in total.

Details

Primary Language English
Subjects Physical Chemistry
Journal Section Articles
Authors

Hasan Ceylan This is me 0000-0003-2101-1334

Abdullah Devrim Pekdemir This is me 0000-0002-3347-0469

Müşerref Önal 0000-0002-1540-8389

Yüksel Sarıkaya This is me 0000-0002-2556-078X

Project Number 16L043013
Publication Date May 31, 2021
Submission Date June 15, 2020
Acceptance Date March 1, 2021
Published in Issue Year 2021

Cite

Vancouver Ceylan H, Pekdemir AD, Önal M, Sarıkaya Y. The Effect of the Hydrothermal and Thermal Deactivations on the Adsorptive Properties and Liquid Permeability of a Silica Gel. JOTCSA. 2021;8(2):477-82.