Research Article

Synthesis, Characterization, and Adsorption Properties of Highly Microporous Structured Activated Carbon

Volume: 8 Number: 3 August 31, 2021
EN

Synthesis, Characterization, and Adsorption Properties of Highly Microporous Structured Activated Carbon

Abstract

The aim of this study is to synthesize activated carbon with high surface area from peach kernel shells which is an agricultural waste. In this study, activated carbon synthesis was carried out by using CO2 at 2 different temperatures (800 and 900 °C) with physical activation from products carbonized at 4 different temperatures (300, 400, 500, and 600 °C) and 2 different N2 gas flow rates (100 and 500 mL/min). After carbonization, solid, liquid, and gas yields of the materials were calculated. The surface area of activated carbons synthesized was calculated by BET analysis and the differences in the surface area were shown by changing the synthesis conditions. Surface areas vary between 340.15 and 686.74 m2/g. In samples pores formed were examined by DFT plus. It was found that most of these pores consist of micropores. Also, the structures of the samples were examined with SEM and XRD analyses. Methylene blue removal of the synthesized samples was studied and the results were compared.

Keywords

Supporting Institution

İnönü Üniversitesi Bap birimi

Project Number

FDI-2017-680

References

  1. 1. Ayinla RT, Dennis J, Zaid H, Sanusi Y, Usman F, Adebayo L. A review of technical advances of recent palm bio-waste conversion to activated carbon for energy storage. Journal of cleaner production. 2019;229:1427-42.
  2. 2. Mayyas M, Sahajwalla V. Carbon nano-sponge with enhanced electrochemical properties: A new understanding of carbon activation. Chemical Engineering Journal. 2019;358:980-91.
  3. 3. Khan JH, Marpaung F, Young C, Lin J, İslam MT, Alsheri SM, Ahamad T, Alhokbany N, Ariga K, Shrestha LK, Yamauchi Y, W. Wu KC, Hossain MSA, Kim J. Jute-derived microporous/mesoporous carbon with ultra-high surface area using a chemical activation process. Microporous Mesoporous Materials. 2019;274:251-6.
  4. 4. Zhang Y, Song X, Xu Y, Shen H, Kong X, Xu H. Utilization of wheat bran for producing activated carbon with high specific surface area via NaOH activation using industrial furnace. Journal of cleaner production. 2019;210:366-75.
  5. 5. Sharma M, Joshi M, Nigam S, Shree S, Avasthi DK, Adelung R, Srivastava SK, Mishra YK. ZnO tetrapods and activated carbon based hybrid composite: Adsorbents for enhanced decontamination of hexavalent chromium from aqueous solution. Chemical Engineering Journal. 2019;358:540-51.
  6. 6. Abdullah MO, Tan IW, Lim LS. Automobile adsorption air-conditioning system using oil palm biomass-based activated carbon: a review. Renewable Sustainable Energy Reviews. 2011; 15:2061-72.
  7. 7. Hu Z, Srinivasan M. Mesoporous high-surface-area activated carbon. Microporous Mesoporous Materials. 2001;43:267-75. 8. Sinha P, Banerjee S, Kar K.K. Characteristics of activated carbon. Springer Series in Materials Science. 2020. ISBN: 978-3-030-43009-2
  8. 9. Oliveira L, Pereira E, Guimaraes R, Vallone A, Pereira M, Mesquita JP, Sapag K. Preparation of activated carbons from coffee husks utilizing FeCl3 and ZnCl2 as activating agents. Journal of Hazardous Materials. 2009;165;87-94.

Details

Primary Language

English

Subjects

Physical Chemistry

Journal Section

Research Article

Publication Date

August 31, 2021

Submission Date

June 16, 2020

Acceptance Date

July 12, 2021

Published in Issue

Year 2021 Volume: 8 Number: 3

APA
Küçük, İ., & Önal, Y. (2021). Synthesis, Characterization, and Adsorption Properties of Highly Microporous Structured Activated Carbon. Journal of the Turkish Chemical Society Section A: Chemistry, 8(3), 821-834. https://doi.org/10.18596/jotcsa.753579
AMA
1.Küçük İ, Önal Y. Synthesis, Characterization, and Adsorption Properties of Highly Microporous Structured Activated Carbon. JOTCSA. 2021;8(3):821-834. doi:10.18596/jotcsa.753579
Chicago
Küçük, İlhan, and Yunus Önal. 2021. “Synthesis, Characterization, and Adsorption Properties of Highly Microporous Structured Activated Carbon”. Journal of the Turkish Chemical Society Section A: Chemistry 8 (3): 821-34. https://doi.org/10.18596/jotcsa.753579.
EndNote
Küçük İ, Önal Y (August 1, 2021) Synthesis, Characterization, and Adsorption Properties of Highly Microporous Structured Activated Carbon. Journal of the Turkish Chemical Society Section A: Chemistry 8 3 821–834.
IEEE
[1]İ. Küçük and Y. Önal, “Synthesis, Characterization, and Adsorption Properties of Highly Microporous Structured Activated Carbon”, JOTCSA, vol. 8, no. 3, pp. 821–834, Aug. 2021, doi: 10.18596/jotcsa.753579.
ISNAD
Küçük, İlhan - Önal, Yunus. “Synthesis, Characterization, and Adsorption Properties of Highly Microporous Structured Activated Carbon”. Journal of the Turkish Chemical Society Section A: Chemistry 8/3 (August 1, 2021): 821-834. https://doi.org/10.18596/jotcsa.753579.
JAMA
1.Küçük İ, Önal Y. Synthesis, Characterization, and Adsorption Properties of Highly Microporous Structured Activated Carbon. JOTCSA. 2021;8:821–834.
MLA
Küçük, İlhan, and Yunus Önal. “Synthesis, Characterization, and Adsorption Properties of Highly Microporous Structured Activated Carbon”. Journal of the Turkish Chemical Society Section A: Chemistry, vol. 8, no. 3, Aug. 2021, pp. 821-34, doi:10.18596/jotcsa.753579.
Vancouver
1.İlhan Küçük, Yunus Önal. Synthesis, Characterization, and Adsorption Properties of Highly Microporous Structured Activated Carbon. JOTCSA. 2021 Aug. 1;8(3):821-34. doi:10.18596/jotcsa.753579

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