Year 2015, Volume 2 , Issue 1, Pages 21 - 37 2015-01-28

FACTORS AFFECTING THE REMOVAL OF A BASIC AND AN AZO DYE FROM ARTIFICIAL SOLUTIONS BY ADSORPTION USING ACTIVATED CARBON
YAPAY ÇÖZELTİLERDEN BİR BAZİK VE BİR AZO BOYAR MADDESİNİN AKTİF KARBON KULLANILARAK ADSORPSİYONUYLA GİDERİLMESİNİ ETKİLEYEN FAKTÖRLER

H Albroomi [1] , Mohamed Elsayed [2] , A Baraka [3] , M Abdelmaged [4]


Decolourisation of wastewater, particularly from textile industries, is one of the major environmental concerns these days. Current methods for removing dyes from wastewater are costly and cannot effectively be used to treat wide range of such wastewater. This work describes the use of commercial available granular activated carbon (GAC) as an efficient adsorbent material for dyes removal. Aqueous solutions of various basic dye Methylene Blue (MB) and azo-dye Tartrazine with concentrations 5-20 mg l1 and 10-100 mg l1, respectively, were shaken with certain amount of GAC to determine the adsorption capacity and removal efficiencies. The effects of adsorbent dose, initial pH, initial dye concentration, agitation speed and contact time on dyes removal efficiencies have been studied. Maximum dye concentration was removed from the solution within 60-90 min after the beginning of every experiment. Adsorption parameters were found to fit well into Langmuir and Freundlich adsorption isotherms models with correlation coefficient (R2 > 0.99) in the concentration range of MB and TZ studied.

Özellikle tekstil endüstrisinden gelen atık suların renginin giderilmesi günümüzde büyük çevresel kaygılardan birini oluşturmaktadır. Atık sudan boyar maddelerin giderilmesini içeren şu andaki yöntemler pahalıdır ve böyle atık suların geniş ölçekte ele alınmasında etkili olarak kullanılamaz. Bu çalışma, boyar maddelerin giderilmesinde etkili bir adsorban malzeme olarak ticari olarak mevcut granül aktif karbon (GAK) kullanımını tarif etmektedir. Bazik bir boyar madde olan Metilen Mavisi (MB) ve azo boyası olan Tartrazin'in sırası ile 5-20 mg.L-1 ve 10-100 mg.L-1 olarak değişen konsantrasyonlarında sulu çözeltileri belirli miktarda GAK ile çalkalanmış ve adsorpsiyon kapasiteleri ile giderme etkinlikleri belirlenmiştir. Adsorban dozu, ilk pH, ilk boya konsantrasyonu, çalkalama hızı ve temas süresinin boyaların giderme etkinlikleri üzerine etkileri incelenmiştir. Maksimum boya derişimi, her deneyin başından itiberin 60-90 dakika içinde çözeltiden giderilmiştir. Adsorpsiyon parametreleri Langmuir ve Freundlich adsorpsiyon izoterm modellerine, çalışılan MB ve TZ derişim aralıkları içinde iyi bir şekilde uymaktadır (R2 > 0,99).

Activated carbon, Adsorption, Methylene Blue, Tartrazine.
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Primary Language tr
Journal Section Articles
Authors

Author: H Albroomi

Author: Mohamed Elsayed

Author: A Baraka

Author: M Abdelmaged

Dates

Publication Date : January 28, 2015

Bibtex @ { jotcsa201776, journal = {Journal of the Turkish Chemical Society Section A: Chemistry}, issn = {}, eissn = {2149-0120}, address = {}, publisher = {Turkish Chemical Society}, year = {2015}, volume = {2}, pages = {21 - 37}, doi = {10.18596/jotcsa.201776}, title = {YAPAY ÇÖZELTİLERDEN BİR BAZİK VE BİR AZO BOYAR MADDESİNİN AKTİF KARBON KULLANILARAK ADSORPSİYONUYLA GİDERİLMESİNİ ETKİLEYEN FAKTÖRLER}, key = {cite}, author = {Albroomi, H and Elsayed, Mohamed and Baraka, A and Abdelmaged, M} }
APA Albroomi, H , Elsayed, M , Baraka, A , Abdelmaged, M . (2015). YAPAY ÇÖZELTİLERDEN BİR BAZİK VE BİR AZO BOYAR MADDESİNİN AKTİF KARBON KULLANILARAK ADSORPSİYONUYLA GİDERİLMESİNİ ETKİLEYEN FAKTÖRLER. Journal of the Turkish Chemical Society Section A: Chemistry , 2 (1) , 21-37 . DOI: 10.18596/jotcsa.201776
MLA Albroomi, H , Elsayed, M , Baraka, A , Abdelmaged, M . "YAPAY ÇÖZELTİLERDEN BİR BAZİK VE BİR AZO BOYAR MADDESİNİN AKTİF KARBON KULLANILARAK ADSORPSİYONUYLA GİDERİLMESİNİ ETKİLEYEN FAKTÖRLER". Journal of the Turkish Chemical Society Section A: Chemistry 2 (2015 ): 21-37 <https://dergipark.org.tr/en/pub/jotcsa/issue/19065/201776>
Chicago Albroomi, H , Elsayed, M , Baraka, A , Abdelmaged, M . "YAPAY ÇÖZELTİLERDEN BİR BAZİK VE BİR AZO BOYAR MADDESİNİN AKTİF KARBON KULLANILARAK ADSORPSİYONUYLA GİDERİLMESİNİ ETKİLEYEN FAKTÖRLER". Journal of the Turkish Chemical Society Section A: Chemistry 2 (2015 ): 21-37
RIS TY - JOUR T1 - YAPAY ÇÖZELTİLERDEN BİR BAZİK VE BİR AZO BOYAR MADDESİNİN AKTİF KARBON KULLANILARAK ADSORPSİYONUYLA GİDERİLMESİNİ ETKİLEYEN FAKTÖRLER AU - H Albroomi , Mohamed Elsayed , A Baraka , M Abdelmaged Y1 - 2015 PY - 2015 N1 - doi: 10.18596/jotcsa.201776 DO - 10.18596/jotcsa.201776 T2 - Journal of the Turkish Chemical Society Section A: Chemistry JF - Journal JO - JOR SP - 21 EP - 37 VL - 2 IS - 1 SN - -2149-0120 M3 - doi: 10.18596/jotcsa.201776 UR - https://doi.org/10.18596/jotcsa.201776 Y2 - 2019 ER -
EndNote %0 Journal of the Turkish Chemical Society Section A: Chemistry YAPAY ÇÖZELTİLERDEN BİR BAZİK VE BİR AZO BOYAR MADDESİNİN AKTİF KARBON KULLANILARAK ADSORPSİYONUYLA GİDERİLMESİNİ ETKİLEYEN FAKTÖRLER %A H Albroomi , Mohamed Elsayed , A Baraka , M Abdelmaged %T YAPAY ÇÖZELTİLERDEN BİR BAZİK VE BİR AZO BOYAR MADDESİNİN AKTİF KARBON KULLANILARAK ADSORPSİYONUYLA GİDERİLMESİNİ ETKİLEYEN FAKTÖRLER %D 2015 %J Journal of the Turkish Chemical Society Section A: Chemistry %P -2149-0120 %V 2 %N 1 %R doi: 10.18596/jotcsa.201776 %U 10.18596/jotcsa.201776
ISNAD Albroomi, H , Elsayed, Mohamed , Baraka, A , Abdelmaged, M . "YAPAY ÇÖZELTİLERDEN BİR BAZİK VE BİR AZO BOYAR MADDESİNİN AKTİF KARBON KULLANILARAK ADSORPSİYONUYLA GİDERİLMESİNİ ETKİLEYEN FAKTÖRLER". Journal of the Turkish Chemical Society Section A: Chemistry 2 / 1 (January 2015): 21-37 . https://doi.org/10.18596/jotcsa.201776
AMA Albroomi H , Elsayed M , Baraka A , Abdelmaged M . YAPAY ÇÖZELTİLERDEN BİR BAZİK VE BİR AZO BOYAR MADDESİNİN AKTİF KARBON KULLANILARAK ADSORPSİYONUYLA GİDERİLMESİNİ ETKİLEYEN FAKTÖRLER. JOTCSA. 2015; 2(1): 21-37.
Vancouver Albroomi H , Elsayed M , Baraka A , Abdelmaged M . YAPAY ÇÖZELTİLERDEN BİR BAZİK VE BİR AZO BOYAR MADDESİNİN AKTİF KARBON KULLANILARAK ADSORPSİYONUYLA GİDERİLMESİNİ ETKİLEYEN FAKTÖRLER. Journal of the Turkish Chemical Society Section A: Chemistry. 2015; 2(1): 37-21.