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DESIGN OF A NOVEL CONDUCTING COMPOSITE SUPPORTED BY PLATINUM NANOPARTICLES FOR HYDROGEN PRODUCTION FROM WATER

Year 2016, Volume: 3 Issue: 3, 417 - 426, 08.01.2017
https://doi.org/10.18596/jotcsa.42436

Abstract

Because of the decrease in fossil fuel resources and the continuous increase in energy demands, clean energy requirements become extremely important for future energy generation systems. Hydrogen is well known as an efficient and environmentally friendly energy carrier. Highly catalytic active and low-cost electrocatalysts for hydrogen production are key issues for sustainable energy technologies. Here we report an aluminium electrode modified with polypyrrole (PPy)-chitosan (Chi) composite film decorated with Pt nanoparticles for hydrogen production from water. Hydrogen evolution reaction (HER) is examined by cyclic voltammetry (CV), Tafel polarization curves and electrochemical impedance spectroscopy (EIS) in 0.5M H2SO4. The structural properties of the modified surfaces analyses were investigated by scanning electron microscopy (SEM). The stability tests also performed for aluminium electrode coted with PPy-Chi/Pt composite film.

References

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  • Varghese J.G, Kittur A.A, Rachipudi P.S, Kariduraganavar M.Y. Synthesis, characterization and pervaporation performance of chitosan-g-polyaniline membranes for the dehydration of isopropanol. J Membr Sci 2010;364:111-121.
  • Gök A, Omastova M, Yavuz A.G. Synthesis and characterization of polythiophenes prepared in the presence of surfactants. Synth Met 2007;157:23–29.
  • Kayan D.B, Koçak D, İlhan M. The activity of PAni-Chitosan composite film decorated with Pt nanoparticles for electrocatalytic hydrogen generation. Int. J. Hydrogen Energy 2016; http://dx.doi.org/10.1016/j.ijhydene.2016.05.024.
  • Zheng Y, Jiao Y, Zhu Y, Li LH, Han Y, Chen Y, Du A, Jaroniec M, Qiao SZ. Hydrogen evolution by a metal-free electrocatalyst. Nature Commun 2014; 5:3783:1-8.
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Year 2016, Volume: 3 Issue: 3, 417 - 426, 08.01.2017
https://doi.org/10.18596/jotcsa.42436

Abstract

References

  • Hassan S, Suzuki M, Abd El-Moneim A. New MnO2/carbon nanowalls composite electrode for supercapacitor application.
  • J. Power Sources 2014;246:68-73.
  • Hao P, Zhao Z. Leng Y, Tian J, Sang Y, Boughton R.I, Wong C.P, Liu H, Yang B. Graphene-based nitrogen self-doped hierarchical porous carbon aerogels derived from chitosan for high performance supercapacitors, Nano Energy 2015;15:9-23.
  • Chen J, Lim B, Lee E.P, Xia Y. Shape-controlled synthesis of platinum nanocrystals for catalytic and electrocatalytic applications. Nano Today 2009;4:81-95.
  • Navarro-Flores E, Omanovic S. Hydrogen evolution on nickel incorporated in three-dimensional conducting polymer layers. J. Mol. Catal. A: Chem. 2005;242:182-194.
  • Dalla Corte D.A, Torres C, Correa P. dos S, Rieder E.S, Malfatti C. de F. The hydrogen evolution reaction on nickel-polyaniline composite electrodes. Int. J. Hydrogen Energy 2012;37:3025-3032.
  • Alexis D, Omanovic S. Ni and Ni Mo hydrogen evolution electrocatalysts electrodeposited in a polyaniline matrix. J. Power Sources 2006;158(1):464-76.
  • Tuomi S, Guil-Lopez R, Kallio T. Molybdenum carbide nanoparticles as a catalyst for the hydrogen evolution reaction and the effect of pH. J Catal 2016;334:102-109.
  • Yuvaraj AL, Santhanaraj D. A systematic study on electrolytic production of hydrogen gas by using graphite as electrode. Materials Research 2014;17(1):83-87.
  • Flores EN, Omanovic S. Hydrogen evolution on nickel incorporated in three-dimensional conducting polymer layers. J Mol Catal A: Chem 2005;242:182-194.
  • Niu L. Li Q, Wei F, Wu S, Liu P, Cao X. Electrocatalytic behaviour of Ptmodified polyaniline electrode for methanol electrooxidation: Effect of Pt deposition modes. J. Electroanal. Chem. 2005;578:331-337.
  • Yavuz A.G, Uygun A, Bhethanabotla VR. Substituted polyaniline/chitosan composites: Synthesis and characterization. Carbohydr Polym 2009;75:448–453.
  • Marroquina J.B, Rheea K.Y, Park S.J. Chitosan nanocomposite films: Enhanced electrical conductivity, thermal stability, and mechanical properties. Carbohydr Polym 2013;92:1783-1791.
  • Silva R.C, Sarmento M.V, Nogueira A.R.F, Tonholo J, Mortimer R.J, Faez R, Ribeiro A.S. Enhancing the electrochromic response of polyaniline films by the preparation of hybrid materials based on polyaniline, chitosan and organically modified clay. RSC Adv 2014;4:14948–14955.
  • Varghese J.G, Kittur A.A, Rachipudi P.S, Kariduraganavar M.Y. Synthesis, characterization and pervaporation performance of chitosan-g-polyaniline membranes for the dehydration of isopropanol. J Membr Sci 2010;364:111-121.
  • Gök A, Omastova M, Yavuz A.G. Synthesis and characterization of polythiophenes prepared in the presence of surfactants. Synth Met 2007;157:23–29.
  • Kayan D.B, Koçak D, İlhan M. The activity of PAni-Chitosan composite film decorated with Pt nanoparticles for electrocatalytic hydrogen generation. Int. J. Hydrogen Energy 2016; http://dx.doi.org/10.1016/j.ijhydene.2016.05.024.
  • Zheng Y, Jiao Y, Zhu Y, Li LH, Han Y, Chen Y, Du A, Jaroniec M, Qiao SZ. Hydrogen evolution by a metal-free electrocatalyst. Nature Commun 2014; 5:3783:1-8.
  • Kayan D.B, Köleli F. Dinitrogen reduction on a polypyrrole coated Pt electrode under high-pressure conditions: electrochemical impedance spectroscopy studies. Turk J Chem 2015;39:648-659.
  • Winther-Jensen B.B, Fraser K, Ong C, Forsyth M, MacFarlane D.R. Conducting polymer composite materials for hydrogen generation. Adv. Mater. 2010;2:1727–1730.
There are 20 citations in total.

Details

Journal Section Articles
Authors

Didem Balun Kayan This is me

Merve İlhan This is me

Derya Koçak This is me

Publication Date January 8, 2017
Submission Date July 4, 2016
Published in Issue Year 2016 Volume: 3 Issue: 3

Cite

Vancouver Balun Kayan D, İlhan M, Koçak D. DESIGN OF A NOVEL CONDUCTING COMPOSITE SUPPORTED BY PLATINUM NANOPARTICLES FOR HYDROGEN PRODUCTION FROM WATER. JOTCSA. 2017;3(3):417-26.