THE LATEST ADVANCEMENTS IN THE ACYLATION REACTIONS VIA CROSS-DEHYDROGENATIVE COUPLING AND/OR METAL CATALYSTS

Year 2018, Volume: 5 Issue: 1, 247 - 268, 01.09.2017

Soykan Ağar , Omer Tahir Gunkara

https://doi.org/10.18596/jotcsa.338292

Cited By: 1

Abstract

There are quite
many examples in the scientific literature regarding the acylation reactions, especially
the metal-catalyzed acylation reactions, metal-free acylation reactions, metal-catalyzed
acylation via cross-dehydrogenative coupling (CDC) reactions and metal-free acylation
via cross-dehydrogenative coupling (CDC) reactions. In this review paper, the
most important examples of these domains were brought together and their
mechanisms were exhibited in a clear, chronological format. Following these, the
best example study towards green chemistry with a metal-free and high-yielding
route was mentioned and discussed to demonstrate what has achieved in this
field regarding the new acylation reaction mechanisms using the advantages of
cross-dehydrogenative coupling (CDC) reactions. The most prominent studies
regarding these domains have been examined thoroughly and the latest progress
in this field was explained in detail.

Keywords

Acylation, Cross-Dehydrogenative coupling (CDC) reactions, C-C bond formation, C-H bond activation, Metal Catalysts

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