EFFECTS OF Zn-DOPING ON THE PHOTOCATALYTIC ACTIVITY AND MICROSTRUCTURES OF NANOCRYSTALLINE SnO2 POWDERS

Year 2018, Volume: 5 Issue: 1, 9 - 14, 15.12.2017

Metin Yurddaskal , Serdar Yıldırım Tuncay Dikici Melis Yurddaskal Mustafa Erol İdil Aritman Hilmiye Deniz Ertuğrul Uygun Erdal Çelik

https://doi.org/10.18596/jotcsa.370744

Cited By: 5

Abstract

In this study, undoped and Zn-doped SnO₂ nanoparticles in different concentrations were synthesized by flame spray pyrolysis (FSP) technique. The produced particles were post-annealed after FSP process at 600 °C in order to obtain a crystalline structure. The structural analysis of the produced powders was performed by X-Ray Diffraction (XRD) methods. The surface morphology of the nanoparticles was identified using scanning electron microscopy (SEM). In addition, photocatalytic degradation of aqueous methylene blue (MB) solutions were evaluated using undoped and Zn-doped SnO₂ nanoparticles under UV light illumination. Photocatalytic degradation of the MB solutions followed the pseudo-first-order-kinetics and the effect of the Zn doping amount on the photocatalytic reaction was investigated.    

Keywords

SnO2; Zn-doped, nanoparticles, photocatalysis, flame spray pyrolysis

References

• Ang GT, Toh GH, Bakar MZA, Abdullah AZ, Othman MR. High sensitivity and fast response SnO2 and La-SnO2 catalytic pellet sensors in detecting volatile organic compounds. Process Saf Environ Prot. Institution of Chemical Engineers; 2011;89(3):186–92.
• Dave N, Pautler BG, Farvid SS, Radovanovic P V. Synthesis and surface control of colloidal Cr3+-doped SnO2 transparent magnetic semiconductor nanocrystals. Nanotechnology. 2010;21(13):134023.
• Huang H, Tian S, Xu J, Xie Z, Zeng D. Needle-like Zn-doped SnO 2 nanorods with enhanced photocatalytic and gas sensing properties.
• Jia T, Wang W, Long F, Fu Z, Wang H, Zhang Q. Synthesis , Characterization , and Photocatalytic Activity of Zn-Doped SnO2 Hierarchical Architectures Assembled by Nanocones. 2009;9071–7.
• Liu J, Gu F, Hu Y, Li C. Flame Synthesis of Tin Oxide Nanorods: A Continuous and Scalable Approach. J Phys Chem C. 2010;114(13):5867–70.
• Paulauskas IE, Modeshia DR, Obaid Y, Basahel SN, Al-ghamdi AA, Sartain FK. Photocatalytic Activity of Doped and Undoped Titanium Dioxide Nanoparticles Synthesised by Flame Spray Pyrolysis. 2013;(1):32–43.
• Rahman MM, Jamal A, Khan SB, Faisal M. Highly sensitive ethanol chemical sensor based on Ni-doped SnO2 nanostructure materials. Biosens Bioelectron. Elsevier B.V.; 2011;28(1):127–34.
• Shanmugam N, Sathya T, Viruthagiri G, Kalyanasundaram C, Gobi R, Ragupathy S. Photocatalytic degradation of brilliant green using undoped and Zn doped SnO2 nanoparticles under sunlight irradiation. Appl Surf Sci. Elsevier B.V.; 2016;360:283–90.
• Yildirim S, Yurddaskal M, Dikici T, Aritman I. Structural and luminescence properties of undoped, Nd 3 þ and Er 3 þ doped TiO 2 nanoparticles synthesized by fl ame spray pyrolysis method. Ceram Int. Elsevier; 2016;42(9):10579–86.