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Year 2018, Volume: 5 Issue: 1, 37 - 44, 15.12.2017
https://doi.org/10.18596/jotcsa.370758

Abstract

References

  • Akpan, U.G. and Hammed, B.H., 2009. Parameters affecting the photocatalytic degradation of dyes using TiO2-based photocatalyst, J. Hazard. Mater., 170, 520.
  • Gan, P.P., Li and S.F.Y., 2013. Efficient removal of Rhodamine B using a rice hull-based silica supported iron catalyst by Fenton-like process, Chem. Eng. J., 229, 351.
  • Kasiri, M.B., Aleboyeh, H. and Aleboyeh, A., 2008. Degradation of Acid Blue 74 using Fe-ZSM5 zeolite as a heterogeneous photo-Fenton catalyst, Appl. Catal. B: Environ., 84(1–2), 9.
  • Labhasetwar, N., Saravanan, G., Megarajan, S.K., Manwar, N., Khobragade, R., Doggal, P. and Grasset. F., 2015. Perovskite-type catalytic materials for environmental applications, Sci. Technol. Adv. Mater., 16, p. 036002, 13 pp.
  • Panda, N., Sahoo, H. and Mohapatra S., 2011. Decolourization of Methyl Orange using Fenton-like mesoporous Fe2O3–SiO2 composite, J. Hazard. Mater., 185, 359.
  • Sun, J.H., Sun, S.P., Wang, G.L. and Qiao, L.P., 2007, Degradation of azo dye Amido black 10B in aqueous solution by Fenton oxidation process, Dyes Pigm., 74, 647.
  • Taran, O.P., Ayusheev, A.B., Ogorodnikova, O.L., Prosvirin, I.P., Isupova, L.A. and Parmon, V.N., 2016. Perovskite-like catalysts LaBO3 (B = Cu, Fe, Mn, Co, Ni) for wet peroxide oxidation of phenol, Appl. Catal. B: Environ., 180, 86.
  • Wu, C.-H., Kuo, C.-Y. and Chang, C.-L., 2008. Decolorization of C.I. Reactive Red 2 by catalytic ozonation processes, J. Hazard. Mater., 153 1052

FENTON-LIKE OXIDATION OF REACTIVE BLACK 5 IN THE PRESENCE OF LABO3 (B: Fe, Co, Mn, Ni) PEROVSKITE CATALYSTS

Year 2018, Volume: 5 Issue: 1, 37 - 44, 15.12.2017
https://doi.org/10.18596/jotcsa.370758

Abstract

The catalytic performances of LaBO3 (B: Fe,
Co, Mn, Ni) perovskite catalysts in Fenton-like oxidation of the textile dye,
Reactive Black 5 were compared, and, the optimum reaction conditions were
investigated in the presence of the most efficient catalyst. Reactive Black 5
was selected as the model dye due to its complex chemical structure, high water
solubility and common usage in the textile industry. The performances of the
catalysts in Reactive Black 5 degradation and decolorization were compared by
testing different catalyst loadings. According to the catalyst screening
experiments, LaFeO
3 showed the highest catalytic performance whereas
LaCoO
3, LaMnO3, and, LaNiO3 were not effective
in the degradation and decolorization of Reactive Black 5. A parametric study
was carried out in the presence of LaFeO
3 catalyst in order to
determine the most suitable reaction conditions. In the parametric study, the
effect of catalyst loading, pH and the initial H
2O2
concentration were investigated. The initial dye concentration and the reaction
temperature were kept constant at 100 ppm and 50
, respectively. The most suitable reaction conditions
were determined as 0.1 g/L of catalyst loading, 3 and 1 mM of H
2O2,
and, 96.9% degradation, and complete decolorization were achieved under these
conditions.

References

  • Akpan, U.G. and Hammed, B.H., 2009. Parameters affecting the photocatalytic degradation of dyes using TiO2-based photocatalyst, J. Hazard. Mater., 170, 520.
  • Gan, P.P., Li and S.F.Y., 2013. Efficient removal of Rhodamine B using a rice hull-based silica supported iron catalyst by Fenton-like process, Chem. Eng. J., 229, 351.
  • Kasiri, M.B., Aleboyeh, H. and Aleboyeh, A., 2008. Degradation of Acid Blue 74 using Fe-ZSM5 zeolite as a heterogeneous photo-Fenton catalyst, Appl. Catal. B: Environ., 84(1–2), 9.
  • Labhasetwar, N., Saravanan, G., Megarajan, S.K., Manwar, N., Khobragade, R., Doggal, P. and Grasset. F., 2015. Perovskite-type catalytic materials for environmental applications, Sci. Technol. Adv. Mater., 16, p. 036002, 13 pp.
  • Panda, N., Sahoo, H. and Mohapatra S., 2011. Decolourization of Methyl Orange using Fenton-like mesoporous Fe2O3–SiO2 composite, J. Hazard. Mater., 185, 359.
  • Sun, J.H., Sun, S.P., Wang, G.L. and Qiao, L.P., 2007, Degradation of azo dye Amido black 10B in aqueous solution by Fenton oxidation process, Dyes Pigm., 74, 647.
  • Taran, O.P., Ayusheev, A.B., Ogorodnikova, O.L., Prosvirin, I.P., Isupova, L.A. and Parmon, V.N., 2016. Perovskite-like catalysts LaBO3 (B = Cu, Fe, Mn, Co, Ni) for wet peroxide oxidation of phenol, Appl. Catal. B: Environ., 180, 86.
  • Wu, C.-H., Kuo, C.-Y. and Chang, C.-L., 2008. Decolorization of C.I. Reactive Red 2 by catalytic ozonation processes, J. Hazard. Mater., 153 1052
There are 8 citations in total.

Details

Primary Language English
Subjects Electrochemistry
Journal Section Articles
Authors

Burcu Palas This is me

Gülin Ersöz This is me

Süheyda Atalay This is me

Publication Date December 15, 2017
Submission Date December 11, 2017
Acceptance Date December 23, 2017
Published in Issue Year 2018 Volume: 5 Issue: 1

Cite

Vancouver Palas B, Ersöz G, Atalay S. FENTON-LIKE OXIDATION OF REACTIVE BLACK 5 IN THE PRESENCE OF LABO3 (B: Fe, Co, Mn, Ni) PEROVSKITE CATALYSTS. JOTCSA. 2017;5(1):37-44.