Quinaldinium Chlorochromate(VI), (QnCC) Catalyzed Oxidation of Alcohols with Periodic Acid Under Solvent-Free Conditions and Microwave Irradition

Year 2018, Volume: 5 Issue: 2, 679 - 690, 01.01.2018

Melek Canbulat Özdemir

https://doi.org/10.18596/jotcsa.357452

Cited By: 2

Abstract

The economic synthesis of quinaldinium
chlorochromate(VI), C₁₀H₉NH[CrO₃Cl], (QnCC)
was performed by using a 1:1:1 stoichiometric amounts of CrO₃, HCl
(aq) and quinaldine. QnCC was isolated in 99% yield as an orange crystalline
solid and characterized with FT-IR, ¹H-NMR, and ¹³C-NMR. An
efficient, selective, and environmentally friendly oxidation of alcohols with
1.1 equiv. periodic acid (H₅IO₆) catalyzed by QnCC (2 mol%)
is described. The primary and secondary alcohols were oxidized to their
corresponding aldehydes and ketones under solvent-free conditions at room
temperature and MW irradiation in high to excellent yields.

Keywords

alcohols, quinaldinium chlorochromate, periodic acid, solvent-free, microwave irradiation

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