The Synthesis of New Aryl Boron-Dipyrromethene Compounds: Photophysical and pH Responsive Properties

Year 2018, Volume: 5 Issue: 2, 433 - 444, 01.01.2018

Gökhan Sevinç , Mustafa Hayvalı

https://doi.org/10.18596/jotcsa.372452

Cited By: 3

Abstract

In
this work, a convenient protocol enabled the synthesis of novel Arylated
Borondipyrromethene (BODIPY) compounds was applied that synthesis yields found
to be higher than classical alkyl substituted analogue. Arylated chromophores
exhibited the broader red-shifted absorption and fluorescence bands with higher
stokes shifts with regard to reference Borondipyrromethene compound
(4,4’-difluoro-8-phenyl-1,3,5,7-tetramethyl-4-bora-3a,4a-diaza-s-indacene,). We
interested in the electron transfer mechanism of compound BDPNH₂
which have amine subunit to alkyl substituted reference. The fluorescence
enhancement of this compound in acidic media was associated with the
inactivation of the acceptor type photoinduced electron transfer mechanism by
fluorimetric measurements. Our results are helpful for designing new
photosensitizers and for applications in the study of the molecular
photochemistry.

Keywords

Aryl Borondipyrromethene, Pentaaryldipyrrin, BODIPY, pH Sensor

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