A green and efficient process for the synthesis of Benzothiazinones using Phosphate fertilizers MAP, DAP and TSP as heterogeneous catalysts

Year 2019, Volume: 6 Issue: 3, 349 - 354, 20.10.2019

İmane Bahammou Badr Malek Tourya Ghaılane Rachida Ghaılane Said Boukhrıs , Abdelaziz Souızı

https://doi.org/10.18596/jotcsa.563093

Cited By: 1

Abstract

The aim of this work is
to prove the efficiency of the Phosphate fertilizers mono-ammonium phosphate
(MAP), di-ammonium phosphate (DAP) and triple-super phosphate (TSP) as a
“green” heterogeneous catalysts for the synthesis of 2-aryl-2H-benzo[b][1,4]thiazin-3(4H)-ones
via the C-S and C-N coupling process of gem-dicyano epoxide with
α-aminothiophenol. To optimize the reaction conditions, the synthesis was
conducted with a range of solvents, catalyst amounts and catalyst particle
sizes. Also, the potential recyclability of the catalysts was confirmed by
running the reaction using the recycled catalyst.

Keywords

Heterogeneous catalyst, phosphate fertilizer, MAP, DAP, TSP

Supporting Institution

University of Ibn Tofail

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