Catalytic performance of polyvinylidene fluoride (PVDF) supported TiO2 additive at microwave conditions

Year 2020, Volume: 7 Issue: 2, 361 - 374, 23.06.2020

Hüseyin Gümüş

https://doi.org/10.18596/jotcsa.610886

Cited By: 5

Abstract

TiO₂ is widely used additive material
in order to improve properties of filtration membranes. As far as its
contribution to filtration performance, TiO₂ acts as catalytic
agent.In this study, catalytic activity of TiO₂ added PVDF flat
sheets (membranes) prepared by phase inversion method, and they were performed on
benzyl alcohol oxidation at microwave radiation. Structure, thermal behaviors
and morphology of samples were investigated by FTIR, TG-DTA and SEM analysis
respectively. Hydrophilicity was determined by contact angle measurements. Interaction
between TiO₂and PVDF chain was
evidenced. TiO₂ added PVDF membranes had improved filtration and
rejection performance. 32.4% BSA rejection was obtained with composites while
it was 7.5% of pristine membrane. 93.86% conversion and 56% selectivity were
obtained with composites in microwave-assisted batch reactor. Decomposition of polymer increased when 6% additive due
to catalytic effect of TiO₂ then, it decreased with further loading.Detailed
evidences were obtained by activation energies (E_a) of decomposition
calculated by Kissinger method. Microwave-assisted catalytic effect of TiO₂inside
polymeric matrix promise to obtain fast, high yielded and disposable membrane
materials for catalytic reactors to in-situ production of fine chemicals.

Keywords

Alcohol oxidation, degradation, filtration membranes, pvdf, TiO2

References

• 1. Xu Z, Wu T, Shi J, Teng K, Wang W, Ma M, et al. Photo catalytic antifouling PVDF ultra filtration membranes based on synergy of graphene oxide and TiO2 for water treatment. Journal of Membrane Science. 2016;520:281–93.
• 2. Nor NAM, Jaafar J, Ismail AF, Mohamed MA, Rahman MA, Othman MHD, et al. Preparation and performance of PVDF-based nanocomposite membrane consisting of TiO2 nanofibers for organic pollutant decomposition in wastewater under UV irradiation. Desalination. 2016;391:89–97.
• 3. Laohaprapanon S, Vanderlipe AD, Doma BT, You SJ. Self-cleaning and antifouling properties of plasma-grafted poly(vinylidene fluoride) membrane coated with ZnO for water treatment. Journal of the Taiwan Institute of Chemical Engineers. 2017;70:15–22.
• 4. Munoz-Bonilla A, Kubacka A, Fernandez-Garcia M, Ferrer M, Fernandez-Garcia M, Cerrada ML. Visible and ultraviolet antibacterial behavior in PVDF-TiO nanocomposite films. European Polymer Journal. 2015;71:412–22.
• 5. You SJ, Semblante GU, Lu SC, Damodar RA, Wei TC. Evaluation of the antifouling and photo catalytic properties of poly(vinylidene fluoride) plasma-grafted poly(acrylic acid) membrane with self-assembled TiO2. Journal of Hazardous Materials. 2012;237–238:10–9.
• 6. Kim BS, Lee J. Macroporous PVDF/TiO2 membranes with three-dimensionally interconnected pore structures produced by directional melt crystallization. Chemical Engineering Journal. 2016;301:158–65.
• 7. Wang Q, Wang X, Wang Z, Huang J, Wang Y. PVDF membranes with simultaneously enhanced permeability and selectivity by breaking the tradeoff effect via atomic layer deposition of TiO2. Journal of Membrane Science. 2013;442:57–64.
• 8. Zhang X, Wang Y, You Y, Meng H, Zhang J, Xu X. Preparation, performance and adsorption activity of TiO2 nanoparticles entrapped PVDF hybrid membranes. Applied Surface Science. 2012;263:660–5.
• 9. Shi F, Ma Y, Ma J, Wang P, Sun W. Preparation and characterization of PVDF / TiO 2 hybrid membranes with different dosage of nano-TiO 2. Journal of Membrane Science. 2012;389:522–31.
• 10. Duranoğlu D. Preparation of TiO2/perlite composites by using 23-1 Fractional Factorial Design. Journal Of The Turkish Chemical Society, Section A: Chemistry. 2016; 3(3):299-312.
• 11. Cao X, Ma J, Shi X, Ren Z. Effect of TiO2 nanoparticle size on the performance of PVDF membrane. Applied Surface Science. 2006;253(4):2003–10.
• 12. Oh SJ, Kim N, Lee YT. Preparation and characterization of PVDF/TiO2 organic-inorganic composite membranes for fouling resistance improvement. Journal of Membrane Science. 2009;345(1–2):13–20.
• 13. Méricq J-P, Mendret J, Brosillon S, Faur C. High performance PVDF-TiO2 membranes for water treatment. Chemical Engineering Science. 2015;123:283–91.
• 14. Wei Y, Chu HQ, Dong BZ, Li X, Xia SJ, Qiang ZM. Effect of TiO2 nanowire addition on PVDF ultra filtration membrane performance. Desalination. 2011;272(1–3):90–7.
• 15. Wang Q, Wang Z, Zhang J, Wang J, Wu Z. Antifouling behaviors of PVDF/nano-TiO2 composite membranes revealed by surface energetics and quartz crystal microbalance monitoring. RSC Adv. 2014;4(82):43590–8.
• 16. Torlak Y. Polyoxotungstate/oxy-graphene nanocomposite multilayer films for electro catalytic hydrogen evolution. Journal of the Turkish Chemical Society, Section A: Chemistry. 2018;
• 17. Ou X, Pilitsis F, Jiao Y, Zhang Y, Xu S, Jennings M, et al. Hierarchical Fe-ZSM-5/SiC foam catalyst as the foam bed catalytic reactor (FBCR) for catalytic wet peroxide oxidation (CWPO). Chemical Engineering Journal. 2019;362(July 2018):53–62.
• 18. Fadaei A, Salimi A, Mirzataheri M. Structural elucidation of morphology and performance of the PVDF/PEG membrane. Journal of Polymer Research. 2014;21(9).
• 19. Liang W, Luo Y, Song S, Dong X, Yu X. High photo catalytic degradation activity of polyethylene containing polyacrylamide grafted TiO2. Polymer Degradation and Stability. 2013;98(9):1754–61.
• 20. Patra N, Salerno M, Malerba M, Cozzoli PD, Athanassiou A. Improvement of thermal stability of poly(methyl methacrylate) by incorporation of colloidal TiO2 nanorods. Polymer Degradation and Stability. 2011;96(7):1377–81.
• 21. Yang W, Wang H, Zhu X, Lin L. Development and Application of Oxygen Permeable Membrane in Selective Oxidation of Light Alkanes. Topics in Catalysis. 2005;35(1–2):155–67.
• 22. Songur Z, Acar M. Chloromethylation of Polysulfone. Journal of the Turkish Chemical Society, Section A: Chemistry. ; 1(1):5.
• 23. Shi F, Ma J, Wang P, Ma Y. Effect of quenching temperatures on the morphological and crystalline properties of PVDF and PVDF-TiO2 hybrid membranes. Journal of the Taiwan Institute of Chemical Engineers. 2012;43(6):980–8.
• 24. Li W, Li H, Zhang YM. Preparation and investigation of PVDF/PMMA/TiO2 composite film. Journal of Materials Science. 2009;44(11):2977–84.
• 25. Dehestaniathar S, Khajelakzay M, Ramezani-Farani M, Ijadpanah-Saravi H. Modified diatomite-supported CuO-TiO2 composite: Preparation, characterization and catalytic CO oxidation. Journal of the Taiwan Institute of Chemical Engineers. Elsevier Ltd.; 2016;58:252–8.
• 26. Hashino M, Hirami K, Ishigami T, Ohmukai Y, Maruyama T, Kubota N, et al. Effect of kinds of membrane materials on membrane fouling with BSA. Journal of Membrane Science. 2011;384(1–2):157–65.
• 27. Abdelrasoul A, Doan H, Lohi A. Fouling in Membrane Filtration and Remediation Methods. In: Mass Transfer - Advances in Sustainable Energy and Environment Oriented Numerical Modeling. 2013.
• 28. Anvari A, Yancheshme AA, Rekaabdar F, Hemmati M, Tavakolmoghadam M, Safekordi A. Erratum to: PVDF/PAN Blend Membrane: Preparation, Characterization and Fouling Analysis (J Polym Environ, (2017), 25, 1348, 10.1007/s10924-016-0889-x). Journal of Polymers and the Environment. 2017;25(4):1359–60.
• 29. Gumus H. Performance investigation of Fe 3 O 4 blended poly (vinylidene fluoride) membrane on filtration and benzyl alcohol oxidation: Evaluation of sufficiency for catalytic reactors. Chinese Journal of Chemical Engineering. Elsevier B.V.; 2019;27(2):314–21.
• 30. Mokhtari-Shourijeh Z, Montazerghaem L, Olya ME. Preparation of Porous Nanofibers from Electrospun Polyacrylonitrile/Polyvinylidene Fluoride Composite Nanofibers by Inexpensive Salt Using for Dye Adsorption. Journal of Polymers and the Environment. 2018;26(9):3550–63.
• 31. Shi F, Ma Y, Ma J, Wang P, Sun W. Preparation and characterization of PVDF/TiO 2 hybrid membranes with different dosage of nano-TiO 2. Journal of Membrane Science. 2012;389:522–31.
• 32. Kubacka A, Ferrer M, Cerrada ML, Serrano C, Sanchez-Chaves M, Fernandez-Garcia M, et al. Boosting TiO2-anatase antimicrobial activity: Polymer-oxide thin films. Applied Catalysis B: Environmental. 2009;89(3–4):441–7.
• 33. Attarchi N, Montazer M, Toliyat T. Ag/TiO2/-CD nano composite: Preparation and photo catalytic properties for methylene blue degradation. Applied Catalysis A: General. 2013;467:107–16.
• 34. He X, Sanders S, Aker WG, Lin Y, Douglas J, Hwang H. Assessing the effects of surface-bound humic acid on the phototoxicity of anatase and rutile TiO2 nanoparticles in vitro. Journal of Environmental Sciences. 2015;2:50–60.
• 35. García-Fernández L, García-Payo MC, Khayet M. Effects of mixed solvents on the structural morphology and membrane distillation performance of PVDF-HFP hollow fiber membranes. Journal of Membrane Science. 2014;
• 36. J. L. Falconer, K. A. Magrini-Bair. Photo catalytic and Thermal Catalytic Oxidation of Acetaldehyde on Pt/TiO2. Journal of Catalysis. 1998;179:171–8.
• 37. Figoli A, Simone S, Criscuoli A, Al-Jlil SA, Al Shabouna FS, Al-Romaih HS, et al. Hollow fibers for seawater desalination from blends of PVDF with different molecular weights: Morphology, properties and VMD performance. Polymer. Elsevier Ltd; 2014;55(6):1296–306.
• 38. Sánchez-Jiménez PE, Criado JM, Pérez-Maqueda LA. Kissinger kinetic analysis of data obtained under different heating schedules. Journal of Thermal Analysis and Calorimetry. 2008;
• 39. Saleh TA, Gupta VK. Synthesis and characterization of alumina nano-particles polyamide membrane with enhanced flux rejection performance. Separation and Purification Technology. 2012;
• 40. Molinari R, Poerio T. Preparation, characterisation and testing of catalytic polymeric membranes in the oxidation of benzene to phenol. Applied Catalysis A: General. 2009;358(2):119–128.
• 41. Zhu Y, Wang B, Wang H, Liu X, Licht S. Towards efficient solar STEP synthesis of benzoic acid: Role of graphite electrode. Solar Energy. Elsevier Ltd; 2015;113:303–12.