Surface assimilation and corrosion inhibition characteristic of water soluble Polyvinyl Alcohol on mild steel surface in 0.5M HCl solution

Year 2021, Volume: 8 Issue: 1, 217 - 228, 28.02.2021

Abhishek Dwivedi , Prem Bharti Sudhish Shukla

https://doi.org/10.18596/jotcsa.794721

Cited By: 10

Abstract

Polymers lead to become emerging materials as corrosion inhibitors for mild steel in acidic media due to its larger surface area. This paper focuses on the characteristic of water solvent Polyvinyl Alcohol (PVA) at interface of Mild Steel under 0.5 M HCl, examined using electrochemical impedance spectroscopy, Tafel polarization and weight reduction techniques. These entire outcomes of the study of characteristic of inhibitor behaved as in well connection and the restraint proficiency, which shows up to 93.7% in 0.5 M hydrochloric acid for 3hrs term. An advanced form of high spatial resolution imaging of surface of mild steel at different stages was found by using scanning electron microscopy.

Keywords

Polymer inhibitor, Weight loss study, Langmuir adsorption isotherm, Polyvinyl Alcohol

Thanks

The manuscript communication number provided by the Research and Development Cell, Integral University, Lucknow is: IU/R&D/ 2020-MCN000976.

References

• 1. Abhishek Dwivedi, S.K. Shukla, P.K.Bharti, “Interaction of water soluble polyacrylic acid towards mild steel / hydrochloric acid interface” IOP CONF. SER. MATER. SCI. ENG, 404 (2018) 012044, DOI:10.1088/1757-899X/404/1/012044
• 2. Rafael Martinez Palou, Octavio Olivares-Xomelt and Natalya V. Likhanova, “Environmentally Friendly Corrosion Inhibitors”, (2014), p. 431-65, http://dx.doi.org/10.5772/57252
• 3. S.K. Shukla, Corrosion inhibitive effect of N-(6-methoxyquinolin-8-yl)-pentane-1,4-diamine on mild steel / sulphuric acid solution interface; J. Mater. Environ. Sci. 6(2015) 1779-1786.
• 4. N. A. Aljeaban, L. K. M. O. Goni, B. G. Alharbi, M. A. Jafar Mazumder, S. A. Ali, T. Chen, M. A. Quraishi, H. A. Al-Muallem, "Polymers Decorated with Functional Motifs for Mitigation of Steel Corrosion: An Overview", Int. J. Polym. Sci., vol. (2020), Article ID 9512680, 23 pages, 2020. https://doi.org/10.1155/2020/9512680M
• 5. Fatima Bouhlal, Najoua Labjar, Farah Abdoun, Aimad Mazkour, Malika Serghini-Idrissi, Mohammed El Mahi, El Mostapha Lotfi, Souad El Hajjaji, "Electrochemical and Thermodynamic Investigation on Corrosion Inhibition of C38 Steel in 1M Hydrochloric Acid Using the Hydro-Alcoholic Extract of Used Coffee Grounds", Int. J. Corros, vol. (2020), 4045802, 14 pages, 2020. https://doi.org/10.1155/2020/4045802
• 6. Adriana Samide, Claudia Merisanu, Bogdan Tutunaru, And Gabriela Eugenia Iacobescu, Poly (Vinyl Butyral-Co-Vinyl Alcohol-Co-Vinyl Acetate) Coating Performance on Copper Corrosion in Saline Environment Molecules. (2020) Feb; 25(3): 439. doi: 10.3390/molecules25030439
• 7. Roxana Grecu, Adrıana Samıde, Gabrıela Eugenıa Iacobescu, Nıcoleta Cıoateră, Alexandru Popescu, Copper Corrosıon Inhıbıtors based on Polyvınyl Alcohol and Sılver Nanopartıcles, Chem. Ind. Chem. Eng. Q., 25 (3) 267−275 (2019)
• 8. Lagrenee, B. Mernari, M. Bouanis, M. Traisnel, F. Bentiss, Studies of the mechanism and inhibiting efficiency of 3,5-bis(4-methylthiophenyl)-4H-1,2,4-triazole on mild steel corrosion in acidic media Corros. Sci. 44 (2002) 573-588.
• 9. M.A. Quraishi, R, Sardar, Aromatic triazoles as corrosion inhibitors for MS in acidic environment, Corrosion 58 (2002)747-756.
• 10. M.A. Quraishi, M. Athar, H. Ali, Corrosion inhibition of carbon steel in hydrochloric acid by organic compounds containing heteroatoms; Brit. Corros. J. 37 (2002) 155-158.
• 11. M.A. Quraishi, F.A. Ansari, Corrosion inhibition by fatty acid triazoles for mild steel in formic acid; J. Appl. Electrochem. 33 (2003) 233-238.
• 12. M.A. Quraishi, S. Khan, Inhibition of mild steel corrosion in sulfuric acid solution by thiadiazoles; J. Appl. Electrochem. 36 (2006) 539-544.
• 13. M. Abdeli, N.P. Ahmadi, R.A. Khosroshahi, Nile Blue and Indigo Carmine organic dyes as corrosion inhibitor of mild steel in hydrochloric acid; J. Solid State Electrochem. 14 (2010) 1317-1324
• 14. A.S. Fouda, Ali H. El-Azaly, R.S. Awad, A.M. Ahmed, New benzonitrile azo dyes as corrosion inhibitors for carbon steel in hydrochloric acid solutions; Int.J. Electrochem. Sci. 9 (2014) 1117-1131
• 15. S.K. Shukla, A.K. Singh, L.C. Murulana, M.M. Kabanda, E.E. Ebenso Inhibitive effect of Azorubine dye on the corrosion of mild steel in hydrochloric acid medium and synergistic iodide additive; Int.J. Electrochem. Sci. 7, (2012) 5057-5068
• 16. C. Jayaprabha, S. Sathyanarayanan, G. Venkatachari, Polyaniline as corrosion inhibitor for iron in acid solutions, J. Appl. Poly. Sci. 101 (2006) 2144–2153.
• 17. N.M. Martyak, P. McAndrew, Corrosion performance of steel coated with co-polyamides and polyaniline, Corros. Sci. 49 (2007) 3826–3837.
• 18. G.A. Moraga, G.G. Silva, T. Matencio, R.M. Paniago, Poly(2,5-dimethoxy aniline)/ fluoropolymer blend coatings to corrosion inhibition on stainless steel, Synthetic Met. 156 (2006) 1036–1042.
• 19. M. Rohwerder, A. Michalik, Conducting polymers for corrosion protection: What makes the difference between failure and success?, Electrochim Acta 53 (2007) 1300–1313.
• 20. U. Riaz, S.M. Ashraf, S. Ahmad, High performance corrosion protective DGEBA/polypyrrole composite coatings, Prog. Org. Coat. 59 (2007) 138–145.
• 21. C. Jeyaprabha, S. Sathiyanarayanan, G. Venkatachari, Effect of cerium ions on corrosion inhibition of PANI for iron in 0.5M H2SO4, Appl. Surf. Sci. 253 (2006) 432–438.
• 22. S. de Souza, Smart coating based on polyaniline acrylic blend for corrosion protection of different metals, Surf. Coat. Technol. 201 (2007) 7574–7581.
• 23. E. Armelin, R. Oliver, F. Liesa, J.I. Iribarren, F. Estrany, C. Alemán, Marine paint formulations: Conducting polymers as anticorrosive additives, Prog. Org. Coat. 59 (2007) 46–52.
• 24. J.E.P. da Silva, S.I.C. de Torresi, R.M. Torresi, Polyaniline / poly(methylmethacrylate) blends for corrosion protection: The effect of passivating dopants on different metals, Prog. Org. Coat. 58 (2007) 33–39.
• 25. R.C. Patil, S. Radhakrishnan, Conducting polymer based hybrid nano-composite for enhanced corrosion protective coatings, Prog. Org. Coat. 57 (2006) 332–336.
• 26. S. Sathiyanarayanan, S. Syed Azim, G. Venkatachari, Preparation of polyaniline-TiO2 composite and its comparative corrosion protection performance with polyaniline, Synthetic Met. 157 (2007) 205–213.
• 27. M.G.Tsoeunyane, M.E.Makhatha, O.A.Arotiba, “Corrosion Inhibition of Mild Steel by Poly(butylene succinate)-L-histidine Extended with 1,6-diisocynatohexane Polymer Composite in 1 M HCl” Int. J. Corros., Volume (2019), Article ID 7406409, 12 pages https://doi.org/10.1155/2019/7406409
• 28. K.Deshmukh, M.Basheer Ahamed, R.R.Deshmukh, S.K.Khadheer, Pasha P., R.Bhagat, Biopolymer Composites With High Dielectric Performance: Interface Engineering, Biopolymer Composites in Electronics, (2017), Pages 27-128, https://doi.org/10.1016/B978-0-12-809261-3.00003-6
• 29. S.K. Shukla, M.A. Quraishi, R. Prakash, A self-doped conducting polymer “polyanthranilic acid”: An efficient corrosion inhibitor for mild steel in acidic solution, Corros. Sci. 50 (2008) 2867-2872.
• 30. G. Ji, S.K. Shukla, P. Dwivedi, S. Sundaram, R. Prakash, Inhibitive effect of Argemone mexicana plant extract on acid corrosion of mild steel, Ind. Engg. Chem Res. 50 (2011) 11954-11959
• 31. S. K. Shukla,M. A. Quraishi, Eno E. Ebenso, “Adsorption and Corrosion Inhibition Properties of Cefadroxil on Mild Steel in Hydrochloric Acid”, Int. J. Electrochem. Sci., 6 (2011) 2912 – 2931
• 32. P.C. Pandey, R. Prakash, Characterization of Electropolymerized Polyindole; Application in the construction of a solid-state, ion-selective electrode. J. Electrochem. Soc. 145 (1998) 4301–4307.
• 33. J. Mohan, S. Joshi, R. Prakash, R.C. Srivastava, Novel Ni(II) Mixed Ligand Complex Modified Electrode: Catalytic Effect on Anodic Oxidation of Phenol, Electroanalysis 16 (2004) 572–576.
• 34. R.Karthikaiselvi, S.Subhashini, R.Rajalakshmi, Poly (vinyl alcohol – aniline) water soluble composite as corrosion inhibitor for mild steel in 1 M HCl, Arabian J. Chem., Volume 5, Issue 4, (2012), Pages 517-52. https://doi.org/10.1016/j.arabjc.2010.09.020
• 35. Sudhish Kumar Shukla, Ashish K. Singh, Eno E. Ebenso, Pharmaceutically Active Compound as Corrosion Inhibitor for Mild Steel in Acidic Medium, Int. J. Electrochem. Sci., 6 (2011) 4276 – 4285
• 36. S.K. Shukla, E.E. Ebenso, Corrosion inhibition, adsorption behaviour and thermodynamic properties of streptomycin on mild steel in hydrochloric acid medium Int. J. Electrochem. Sci., 6 (2011) 3277.
• 37. S.K. Shukla, M.A. Quraishi, Effect of some substituted aniline-formaldehyde polymers on mild steel corrosion in hydrochloric acid medium, J. Appl. Poly. Sci. 124 (2012) 5130-5137.
• 38. E.S. Ferreira, C. Giancomelli, F.C. Giacomelli, A. Spinelli, Evaluation of the inhibitor effect of l-ascorbic acid on the corrosion of mild steel, Mater. Chem. Phys. 83 (2004) 129-134.
• 39. W.H. Li, Q. He, C.L. Pei, B.R. Hou, Some new triazole derivatives as inhibitors for mild steel corrosion in acidic medium, J. Appl. Electrochem. 38 (2008) 289-295.
• 40. W.R. Fawcett, Z. Kovacova, A.J. Motheo, C.A. Foss Jr, Application of the ac admittance technique to double-layer studies on polycrystalline gold electrodes, J. Electroanal. Chem. 326 (1992) 91-103.
• 41. K. Juttner, Electrochemical impedance spectroscopy (EIS) of corrosion processes on inhomogeneous surfaces, Electrochim. Acta. 35 (1990) 1501-1508.
• 42. A.K. Singh, S.K. Shukla, E.E. Ebenso, Cefacetrile as corrosion inhibitor for mild steel in acidic media, Int. J. Electrochem. Sci. 6 (2011) 5689-5700.
• 43. F. Mansfeld, Recording and Analysis of AC Impedance Data for Corrosion Studies, Corrosion. 37 (1981) 301-307.
• 44. A. K. Singh, S.K. Shukla, M. Singh, M.A. Quraishi, Inhibitive effect of ceftazidime on the corrosion of mild steel in hydrochloric acid solution, Mater. Chem. Phys. 129 (2011) 68.
• 45. M. Lebrini, M. Lagrenee, H. Vezin, M. Traisnel, F. Bentiss, Experimental and theoretical study for corrosion inhibition of mild steel in normal hydrochloric acid solution by some new macrocyclic polyether compounds, Corros. Sci. 49 (2007) 2254-2269.
• 46. H.H. Hassan, Perchlorate and oxygen reduction during Zn corrosion in a neutral medium, Electrochim. Acta. 51 (2006) 5966-5972.
• 47. S.A. Umoren, “Polymers as Corrosion Inhibitors for Metals in Different Media - A Review”, Open Corros. J., ( 2009) DOI: 10.2174/1876503300902010175
• 48. F.B. Growcok, W.W. Frenier, P.A. Andrezzi, Inhibition of Steel Corrosion in HCl by Derivatives of Cinnamaldehyde: Part II. Structure–Activity Correlations, Corrosion 45 (1989) 1007
• 49. S. K. Shukla, A. K. Singh, M. A. Quraishi, “Triazines: Efficient Corrosion Inhibitors for Mild Steel in Hydrochloric Acid Solution” , Int. J. Electrochem. Sci., 7 (2012) 3371 – 3389
• 50. Sabirneeza, A.A.F., Subhashini, S. Poly(vinyl alcohol–proline) as corrosion inhibitor for mild steel in 1M hydrochloric acid. Int J Ind Chem 5, 111–120 (2014). https://doi.org/10.1007/s40090-014-0022-8