Synthesis and characterization of molecularly imprinted composite as a novel adsorbent and competition with non-imprinting composite for removal of dye

Year 2021, Volume: 8 Issue: 2, 609 - 622, 31.05.2021

Ayfer Yıldırım Hilal Acay Ayşe Baran

https://doi.org/10.18596/jotcsa.868054

Cited By: 3

Abstract

Due to its high visibility, high resistance, and toxic effects, colored substances in the textile and other dyeing industries waste-water cause great damage to biological organisms and ecology. Therefore, current research efforts to develop high selectivity, specificity, and efficient water treatment technologies are very intense, and molecularly imprinting methods (MIM) constitute a category of functional materials to meet these criteria. Polymethylmethacrylate-chitosan molecularly imprinted composite (PMMAC-MIC) and non-imprinted composite (PMMAC-NIC) were successfully prepared by MIM. Dye adsorption performance of MIC and NIC composites was investigated by comparison. The obtained adsorbents were characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and zeta potential techniques. The kinetics of adsorption followed a pseudo-first-order model while the Langmuir adsorption isotherm provided the best fit. The maximum adsorption capacity of dye was found as 93.78 mg/g for PMMAC-MIC and 17.70 mg/g for PMMAC-NIC at 298 K temperature, the initial dye concentration was 100 mg/L. Thermodynamic parameters indicated that the removal of dye from PMMAC-MIC was endothermic and spontaneous. Besides, the regeneration of composite was recycled four times.

Keywords

Molecular imprinting, Adsorption, Composite, Regeneration, Selectivity

References

• 1. Yildirim A, Acay H. Biosorption Studies of Mushrooms for Two Typical Dyes. JOTCSA. 2020; 7(1): 295-306.
• 2. Zhang Y, Huang Y, Zhai F, Du R, Liu Y, Lai K. Analyses of enrofloxacin, furazolidone and malachite green in fish products with surface-enhanced Raman spectroscopy. Food Chemistry. 2012; 13: 845–50.
• 3. Li Q, Su H, Li J, Tan T. Application of surface molecular imprinting adsorbent in expanded bedfor the adsorption of Ni2+ and adsorption model. Journal of Environmental Management. 2007; 85: 900–7.
• 4. Hui Y, Yan-Fei C, Hui-Qin G, Wen-Tian M, Jing L, Shui-Gen Z, Sen L, Liu-Shui Y, Ke-Xin L. Preparation of Molecularly Imprinted Carbon Microspheres by One-Pot Hydrothermal Method and Their Adsorption Properties to Perfluorooctane Sulfonate. Chinese Journal of Analytical Chemistry. 2019; 47: 1776–84.
• 5. He Q, Liang JJ, Chen LX, Chen SL, Zheng HL, Liu HX, Zhang HJ. Removal of the environmental pollutant carbamazepine using molecular imprinted adsorbents: Molecular simulation, adsorption properties, and mechanisms. Water Research. 2000; 168: 1151642, 1-13.
• 6. Yi Z, Huajie L, Mingchun L, Meihua X. Adsorption of aniline on aminated chitosan/graphene oxide composite material. Journal of Molecular Structure. 2020; 1209: 127973, 1-6.
• 7. Wang R, Zhang X, Zhu J, Bai J, Gao L, Liu S, Ji T. Facile preparation of self-assembled chitosan-based composite hydrogels with enhanced adsorption performances. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2020; 598: 124860, 1-9.
• 8. Deng H, Wei Z, Wang XN. Enhanced adsorption of active brilliant red X-3B dye on chitosan molecularly imprinted polymer functionalized with Ti(IV) as Lewis acid. Carbohydrate Polymers. 2017; 157: 1190-7.
• 9. Kyzas GZ, Lazaridis NK, Bikiaris DN. Optimization of chitosan and β-cyclodextrin molecularly imprinted polymer synthesis for dye adsorption. Carbohydrate Polymers. 2013; 91: 198-208.
• 10. MR Fat'hi, S.J.H. Nasab. Synthesis of calcon-imprinted magnetic chitosan nanoparticles as a novel adsorbent and its application in selective removal of calcon dye from aqueous solutions. International Journal of Biological Macromolecules. 2018; 114: 1151-60.
• 11. Ahmed MA, Abdelbar NM, Mohamed AA. Molecular imprinted chitosan-TiO2 nanocomposite for the selective removal of Rose Bengal from wastewater, International Journal of Biological Macromolecules. 2018; 107: 1046-53.
• 12. da Silva RC, de Aguiar SB, da Cunha PLR, de Paula RCM, Feitosa JPA. Effect of microwave on the synthesis of polyacrylamide-g-chitosan gel for azo dye removal. Reactive and Functional Polymers. 2020; 148: 104491, 1-10.
• 13. Khajavian M, Salehi E, Vatanpour V. Chitosan/polyvinyl alcohol thin membrane adsorbents modified with zeolitic imidazolate framework (ZIF-8) nanostructures: Batch adsorption and optimization. Separation and Purification Technology. 2020; 241: 116759, 1-16.
• 14. Fan L, Zhang Y, Li X, Luoa C, Lu F, Qiu H. Removal of alizarin red from water environment using magnetic chitosan with Alizarin Red as imprinted molecules. Colloids and Surfaces B: Biointerfaces. 2012; 91: 250-7.
• 15. Baran, MF Acay H, C Keskin. Determination of antimicrobial and toxic metal removal activities of plant-based synthesized (Capsicum annuum L. Leaves), Ecofriendly, Gold Nanomaterials. Global challenges. 2020; 1900104: 1-7.
• 16. Bhomick CP, Supong A, Baruah MC, Sinha D. Pine Cone biomass as an efficient precursor for the synthesis of activated biocarbon for adsorption of anionic dye from aqueous solution: Isotherm, kinetic, thermodynamic and regeneration studies. Sustainable Chemistry and Pharmacy. 2018; 10. 41-9.
• 17. Acay H, Baran MF. Biosynthesis and characterization of silver nanoparticles using king oyster (Pleurotus eryngii) extract: effect on some microorganisms. Applied Ecology And Environmental Research. 2019; 17: 9205-14.
• 18. Baran MF, Acay H. Antimicrobial Activity of Silver Nanoparticles Synthesized with Extract of Tomato plant Against Bacterial and Fungal Pathogens. Middle Black Sea Journal of Health Science. 2019; 5: 67-73.
• 19 Yildirim A, Acay H, Baran F. Synthesis and characterisation of mushroom-based nanocomposite and its efficiency on dye biosorption via antimicrobial activity. International Journal of Environmental Analytical Chemistry. 2020; 1739664, 1-18.
• 20. Baran MF, Yildirim A, Acay H, Keskin C, Aygun H. Adsorption performance of Bacillus licheniformis sp. bacteria isolated from the soil of the Tigris River on mercury in aqueous solutions. International Journal of Environmental Analytical Chemistry. 2020; 1746779, 1-16.
• 21. Yildirim A, Bulut Y. Adsorption behaviors of malachite green by using crosslinked chitosan/polyacrylic acid/bentonite composites with different ratios. Environmental Technology & Innovation. 2020; 7: 100560, 1-13.
• 22 Rajabi M, Mahanpoor K, Moradi O. Preparation of PMMA/GO and PMMA/GO-Fe3O4 nanocomposites for malachite green dye adsorption: Kinetic and thermodynamic studies. Composites Part B. 2019; 167: 544–55.
• 23 Labidi A, Salaberria AM, Labidi J, Abderrabba M. Preparation of novel carboxymethyl chitosan-graft-poly(methylmethacrylate) under microwave irradiation as a chitosan-based material for Hg2+ removal. Microchemical Journal. 2019; 148: 531–40.
• 24. Kumari S, Khan AA, Chowdhury A, Bhakta AK, Hussain ZMS. Efficient and highly selective adsorption of cationic dyes and removal of ciprofloxacin antibiotic by surface modified nickel sulfide nanomaterials: Kinetics, isotherm, and adsorption mechanism. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2020; 586: 124264, 1-15.
• 25. Bhatti HN, Safa Y, Yakout SM, Shair OH, Iqbalf M, Nazir A. Efficient removal of dyes using carboxymethyl cellulose/alginate/polyvinyl alcohol/rice husk composite: Adsorption/desorption, kinetics and recycling studies. International Journal of Biological Macromolecules. 2020; 150: 861-70.
• 26. Yang K., Dang H, Liu L, Hu X, Li X, Ma Z, Wang X, Ren T. Effect of syringic acid incorporation on the physical, mechanical, structural and antibacterial properties of chitosan film for quail eggs preservation, International Journal of Biological Macromolecules. 2019; 141: 876–84.
• 27. Habiba U, Siddique TA, Lee JJL, Joo TC, Afifi AM. Adsorption study of methyl orange by chitosan/polyvinyl alcohol/zeolite electrospun composite nanofibrous membrane. Carbohydrate Polymers. 2018; 191: 79–85.
• 28. Boggione MJ, Mahl CRA, Beppu MM, Farruggia B. Synthesis and characterization of chitosan membranes functionalized with amino acids and copper for adsorption of endoglucanase, Powder Technology. 2017; 315: 250–7.
• 29. Zhang H, Omer AM, Hu Z, Yang LY, Ji C, Ouyang XK. Fabrication of magnetic bentonite/carboxymethyl chitosan/sodium alginate hydrogel beads for Cu (II) adsorption. International Journal of Biological Macromolecules. 2019; 135: 490–500.
• 30. Lewandowska K, Furtos G. Study of apatite layer formation on SBF-treated chitosan composite thin films. Polymer Testing. 2018; 71: 173–81.
• 31. Yekeen N, Padmanabhan E, Idris AK, Ibad SM. Surfactant adsorption behaviors onto shale from Malaysian formations: Influence of silicon dioxide nanoparticles, surfactant type, temperature, salinity and shale lithology. Applied Clay Science. 2016; 123: 64–75.
• 32. Awokoya KN, Oninla VO, Babalola JO, Mbaeyi NN, Folorunso FT. Adsorption of malachite green onto styrene-methacrylate based molecularly imprinted polymer. Ife Journal of Science. 2019; 21: 67-80.
• 33. Farhadia K, Matin AA, Hashemia P. Removal of malachite green from aqueous solutions using molecularly imprinted polymer. Desalination and Water Treatment. 2010; 24: 20–7.
• 34. Yildirim A. Kinetic, equilibrium and thermodynamic investigations for the bio-sorption of dyes onto crosslinked Pleurotus ostreatus-based bio-composite. International Journal of Environmental Analytical Chemistry. 2020; 1802441, 1-16. 35. Banerjee D, Bhowmick P, Pahari D, Santra S, Sarkar S, Chattopadhyay BDKK. Pseudo-first ordered adsorption of noxious textile dyes by low-temperature synthesized amorphous carbon nanotubes. Physica E. 2017; 87: 68–76.
• 36. Robati D, Rajabi M, Moradi O, Najafi F, Tyagi I, Agarwal S, Gupta VK. Kinetics and thermodynamics of malachite green dye adsorption from aqueous solutions on graphene oxide and reduced graphene oxide. Journal of Molecular Liquids. 2016; 214: 259–63.
• 37. Shang Y, Shi YCR, Yang P, Wang J, Wang Y. Regenerated WO2.72 nanowires with superb fast and selective adsorption forcationic dye: Kinetics, isotherm, thermodynamics, mechanism. Journal of Hazardous Materials. 2019; 379: 120834, 1-10.
• 38. Bonetto LR, Ferrarini F, Marco CD, Crespo JS, Ruégan R, Giovanela M. Removal of methyl violet 2B dye from aqueous solution using a magnetic composite as an adsorbent. J. Water Process Eng. 2015; 6: 11-20.
• 39. De Castro MLFA, Abad MLB, Sumalinog DAG, Abarca RRM, Paoprasert P, de Luna MDG. Adsorption of Methylene Blue dye and Cu(II) ions on EDTA-modified bentonite: Isotherm, kinetic and thermodynamic studies. Sustainable Environment Research. 2018; 28: 197-205.
• 40. Dastgerdi ZH, Abkhiz V, Meshkat SS, Ghorbana N. Preparation of novel magnetic grafted raft agent nanocomposite: Application in carmine dye adsorptive removal from waste water. Journal of Environmental Chemical Engineering. 2019; 7: 103109, 1-9.
• 41. Wang L, Zhang J, Wang A. Fast removal of methylene blue from aqueous solution by adsorption onto chitosan-g-poly (acrylic acid)/attapulgite composite. Desalination. 2011; 266: 33–9.