Research Article
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Kinetic and thermodynamic study on adsorption of cadmium from aqueous solutions using natural clay

Year 2021, Volume: 8 Issue: 2, 677 - 692, 31.05.2021
https://doi.org/10.18596/jotcsa.882016

Abstract

Heavy metal pollution poses a great risk for the environment and the human health. Cadmium is among the most common pollutants found in wastewater, known for its great toxicity even in small doses. This work aims to study the removal of cadmium using natural Moroccan clay (MC). The clay was characterized using X-ray diffraction, X-ray fluorescence, Fourier transform infrared spectroscopy, BET, and SEM. The effects of several experimental parameters on the clay adsorption capacity towards cadmium ions, such as MC dose, initial concentration and contact time, initial pH, and temperature were studied. The kinetic models Pseudo-first order, Pseudo-second order, and Elovich are evaluated to identify the adsorption process. The adsorption mechanism was determined by the use of the adsorption isotherms: Langmuir, Freundlich, and Temkin model. The results show that the heavy metal retention obeys the Pseudo-second order (R²≥0.99). The Langmuir isotherm model provided the best fit (R²≥0.99) to the experimental data for the adsorption of Cd(II) by MC as compared to the Freundlich and Temkin model. The maximum monolayer adsorption capacity of Cd(II), using the Langmuir model equation, is equal to 5.25 mg/g. The adsorption is a spontaneous and an endothermic process characterized by a disorder of the medium.

Thanks

The authors are pleased to acknowledge Centre National de la Recherche Scientifique et Technique (CNRST) Morocco.

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Year 2021, Volume: 8 Issue: 2, 677 - 692, 31.05.2021
https://doi.org/10.18596/jotcsa.882016

Abstract

References

  • 1. Jiménez-Castañeda M, Medina D. Use of Surfactant-Modified Zeolites and Clays for the Removal of Heavy Metals from Water. Water. 2017 Mar 24;9(4):235. Doi: https://doi.org/10.3390/w9040235.
  • 2. Bouazza D, Miloudi H, Adjdir M, Tayeb A, Boos A. Competitive adsorption of Cu (II) and Zn (II) on impregnate raw Algerian bentonite and efficiency of extraction. Applied Clay Science. 2018 Jan;151:118–23. Doi: https://doi.org/10.1016/j.clay.2017.10.026.
  • 3. Ezzeddine Z, Batonneau-Gener I, Pouilloux Y, Hamad H, Saad Z. Synthetic Nax Zeolite as a Very Efficient Heavy Metals Sorbent in Batch and Dynamic Conditions. Colloids and Interfaces. 2018 May 24;2(2):22. Doi: https://doi.org/10.3390/colloids2020022.
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  • 17. Uddin MK. A review on the adsorption of heavy metals by clay minerals, with special focus on the past decade. Chemical Engineering Journal. 2017 Jan;308:438–62. Doi: https://doi.org/10.1016/j.cej.2016.09.029.
  • 18. Abbou B, Lebkiri I, Ouaddari H, Kadiri L, Ouass A, Habsaoui A, et al. Removal of Cd(II), Cu(II), and Pb(II) by adsorption onto natural clay: a kinetic and thermodynamic study. Turk J Chem. 2021;45:362–76. Doi: https://doi.org/10.3906/kim-2004-82.
  • 19. Arbaoui F, Boucherit MN. Comparison of two Algerian bentonites: Physico-chemical and retention capacity study. Applied Clay Science. 2014 Apr;91–92:6–11. Doi: https://doi.org/10.1016/j.clay.2014.02.001.
  • 20. Besq A, Malfoy C, Pantet A, Monnet P, Righi D. Physicochemical characterisation and flow properties of some bentonite muds. Applied Clay Science. 2003 Oct;23(5–6):275–86. Doi: https://doi.org/10.1016/S0169-1317(03)00127-3.
  • 21. Sadki H, Ziat K, Saidi M. Adsorption of dyes on activated local clay in aqueous solution. J Mater Environ Sci. 2014;5(1):2060-5.
  • 22. Ouaddari H, Karim A, Achiou B, Saja S, Aaddane A, Bennazha J, et al. New low-cost ultrafiltration membrane made from purified natural clays for direct Red 80 dye removal. Journal of Environmental Chemical Engineering. 2019 Aug;7(4):103268. Doi: https://doi.org/10.1016/j.jece.2019.103268.
  • 23. Essaadaoui Y, Lebkiri A, Rifi EH, Kadiri L, Ouass A. Adsorption of cobalt from aqueous solutions onto Bark of Eucalyptus. Mediterr J Chem. 2018 Sep 15;7(2):145–55. Doi: https://doi.org/10.13171/mjc72/01808150945-essaadaoui.
  • 24. Ouaddari H, Beqqour D, Bennazha J, El Amrani I-E, Albizane A, Solhy A, et al. Natural Moroccan clays: Comparative study of their application as recyclable catalysts in Knoevenagel condensation. Sustainable Chemistry and Pharmacy. 2018 Dec;10:1–8. Doi: https://doi.org/10.1016/j.scp.2018.07.003.
  • 25. Bedelean H, Măicăneanu A, Burcă S, Stanca M. Removal of heavy metal ions from wastewaters using natural clays. Clay miner. 2009 Dec;44(4):487–95. Doi: https://doi.org/10.1180/claymin.2009.044.4.487.
  • 26. Mobarak M, Selim AQ, Mohamed EA, Seliem MK. A superior adsorbent of CTAB/H2O2 solution−modified organic carbon rich-clay for hexavalent chromium and methyl orange uptake from solutions. Journal of Molecular Liquids. 2018 Jun;259:384–97. Doi: https://doi.org/10.1016/j.molliq.2018.02.014.
  • 27. Adebowale KO, Olu-Owolabi BI, Chigbundu EC. Removal of Safranin-O from Aqueous Solution by Adsorption onto Kaolinite Clay. JEAS. 2014;04(03):89–104. Doi: https://doi.org/10.4236/jeas.2014.43010.
  • 28. Bentahar Y, Hurel C, Draoui K, Khairoun S, Marmier N. Adsorptive properties of Moroccan clays for the removal of arsenic(V) from aqueous solution. Applied Clay Science. 2016 Jan;119:385–92. Doi: https://doi.org/10.1016/j.clay.2015.11.008.
  • 29. Chinoune K, Bentaleb K, Bouberka Z, Nadim A, Maschke U. Adsorption of reactive dyes from aqueous solution by dirty bentonite. Applied Clay Science. 2016 Apr;123:64–75. Doi: https://doi.org/10.1016/j.clay.2016.01.006.
  • 30. Eloussaief M, Kallel N, Yaacoubi A, Benzina M. Mineralogical identification, spectroscopic characterization, and potential environmental use of natural clay materials on chromate removal from aqueous solutions. Chemical Engineering Journal. 2011 Apr;168(3):1024–31. Doi: https://doi.org/10.1016/j.cej.2011.01.077.
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There are 56 citations in total.

Details

Primary Language English
Subjects Analytical Chemistry
Journal Section Articles
Authors

Brahim Abbou 0000-0002-2056-9187

İmane Lebkiri This is me 0000-0001-5668-1392

Hanae Ouaddarı This is me 0000-0001-6716-2985

Omar Elkhattabi This is me 0000-0001-9125-3844

Amar Habsaouı This is me 0000-0001-9641-8046

Ahmed Lebkırı This is me 0000-0003-0593-0074

El Housseine Rıfı This is me 0000-0002-6436-4554

Publication Date May 31, 2021
Submission Date February 17, 2021
Acceptance Date May 11, 2021
Published in Issue Year 2021 Volume: 8 Issue: 2

Cite

Vancouver Abbou B, Lebkiri İ, Ouaddarı H, Elkhattabi O, Habsaouı A, Lebkırı A, Rıfı EH. Kinetic and thermodynamic study on adsorption of cadmium from aqueous solutions using natural clay. JOTCSA. 2021;8(2):677-92.

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