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Enrichment of Magnesite and Usage to Obtain Magnesium Fluoride

Year 2022, Volume: 9 Issue: 2, 621 - 630, 31.05.2022
https://doi.org/10.18596/jotcsa.1070017

Abstract

Magnesium is the sixth most abundant element, constituting 2% of the total mass of the earth's crust. It is a metal that exists only in chemical compounds, and generally exits in carbonate and oxide forms. The most important mineral forms are magnesite (MgCO3), dolomite (MgCO3.CaCO3) and carnallite (KCl.MgCl2-6H2O). Magnesium metal, which is obtained from different sources by various methods, has an important place in the industry. There are approximately 16 billion tons of dolomite and 110 million tons of magnesite reserves in Turkey. The aim of this study is to investigate the use of idle magnesium clay raw material (in Eskişehir) for the production of magnesium fluoride and thus to propose a chemical process for the relevant raw material to the industry. For the experiments, a 10 kg sample was taken and after the whole was ground to 75 µm size, XRF, XRD and DTA analyzes were performed. As a result of XRF analysis, it was determined that it contains 44.28% MgO. As a result of XRD analysis, it was determined that it is magnesite with MgCO3 structure, and also it has dolomite and chlorite group mineral structures. As a result of the experiments, MgF2 was obtained by using HF from the relevant raw material, and it was determined that the efficiency was higher in the experiments performed with raw magnesite.

Thanks

We kindly thank Esan Eczacıbaşı Industrial Raw Materials Ind. and Trade Inc.

References

  • 1. Gence N. Enrichment Of Magnesite Ore. Eskişehir Osmangazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi. 2001 Dec 31;14(2):1–10.
  • 2. Wilson I, Ebner F. The World of magnesite. Ind Minerals. 2006;462:54–9.
  • 3. Yucel O, Yiğit S, Derin B. Production of Magnesium Metal from Turkish Calcined Dolomite Using Vacuum Silicothermic Reduction Method. MSF. 2005 Jul;488–489:39–42.
  • 4. Gunay A, Karadag D, Tosun I, Ozturk M. Use of magnesit as a magnesium source for ammonium removal from leachate. Journal of Hazardous Materials. 2008 Aug;156(1–3):619–23.
  • 5. Demiray Y, Yücel O. Production and Refining of Magnesium Metal from Turkey Originating Dolomite. High Temperature Materials and Processes [Internet]. 2012 Jan 6 [cited 2022 Apr 18];31(3).
  • 6. Demir F, Dönmez B, Okur H, Sevim F. Calcination Kinetic of Magnesite from Thermogravimetric Data. Chemical Engineering Research and Design. 2003 Jul;81(6):618–22.
Year 2022, Volume: 9 Issue: 2, 621 - 630, 31.05.2022
https://doi.org/10.18596/jotcsa.1070017

Abstract

References

  • 1. Gence N. Enrichment Of Magnesite Ore. Eskişehir Osmangazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi. 2001 Dec 31;14(2):1–10.
  • 2. Wilson I, Ebner F. The World of magnesite. Ind Minerals. 2006;462:54–9.
  • 3. Yucel O, Yiğit S, Derin B. Production of Magnesium Metal from Turkish Calcined Dolomite Using Vacuum Silicothermic Reduction Method. MSF. 2005 Jul;488–489:39–42.
  • 4. Gunay A, Karadag D, Tosun I, Ozturk M. Use of magnesit as a magnesium source for ammonium removal from leachate. Journal of Hazardous Materials. 2008 Aug;156(1–3):619–23.
  • 5. Demiray Y, Yücel O. Production and Refining of Magnesium Metal from Turkey Originating Dolomite. High Temperature Materials and Processes [Internet]. 2012 Jan 6 [cited 2022 Apr 18];31(3).
  • 6. Demir F, Dönmez B, Okur H, Sevim F. Calcination Kinetic of Magnesite from Thermogravimetric Data. Chemical Engineering Research and Design. 2003 Jul;81(6):618–22.
There are 6 citations in total.

Details

Primary Language English
Subjects Analytical Chemistry
Journal Section Articles
Authors

Çiğdem Aras 0000-0003-4301-2004

Birsen Demirata 0000-0002-0978-0977

Kevser Sözgen Başkan 0000-0002-3486-0231

Publication Date May 31, 2022
Submission Date February 8, 2022
Acceptance Date March 28, 2022
Published in Issue Year 2022 Volume: 9 Issue: 2

Cite

Vancouver Aras Ç, Demirata B, Sözgen Başkan K. Enrichment of Magnesite and Usage to Obtain Magnesium Fluoride. JOTCSA. 2022;9(2):621-30.