Isotherm and thermodynamic studies on the removal of gelatin-stabilized silver nanoparticles from water by activated carbon

Year 2022, Volume: 9 Issue: 3, 919 - 938, 31.08.2022

Ayşenur Ceryan , Nurettin Eltuğral

https://doi.org/10.18596/jotcsa.1098891

Abstract

Gelatin-stabilized silver nanoparticles (AgNPs) with a particle size of 6.9 (±3.2) nm were synthesized and employed in nanoparticle adsorption onto activated carbon (AC). Subsequently, the synthesized AgNPs and the adsorbed nanoparticles onto the AC (AgNP@AC) were characterized by various techniques including UV–Vis spectrophotometry, transmission electron microscopy (TEM), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT–IR) and X–ray diffraction (XRD). AgNPs possessed colloidal stability at a wide pH interval ranging between 4 and 13. Adsorption was studied batch-wise as a function of initial nanoparticle concentration (4–14 mg L-1), temperature (298–323 K), pH (4–13) and adsorbent dosage (0.01–0.05 g). Adsorption isotherms were investigated by fitting the data to different isotherm models including Langmuir, Freundlich, Temkin, and Dubinin–Radushkevich (D–R). Error analysis indicated that the adsorption is well described by the Langmuir model with a monolayer adsorption capacity of 10.36 mg g-1 for 0.05 g AC at pH 7 and 323 K. Thermodynamic parameters such as enthalpy (66.77 kJ mol-1), entropy (232.92 J mol-1 K-1), and Gibbs free energy (–8.31 kJ mol-1) indicated that the process is endothermic, favorable and spontaneous through physical interactions.

Keywords

Silver nanoparticles, gelatin, activated carbon, adsorption, thermodynamic parameters

Supporting Institution

Karabük Üniversitesi

Project Number

Project 16/1-DS-245

Thanks

The authors gratefully thank Karabük University for the support by a grant from the [Project 16/1-DS-245].

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