A Simultaneous Determination Method for the Analysis of Chloride and Nitrate Ions in Air Samples by PLS1

Year 2023, Volume: 10 Issue: 1, 89 - 96, 28.02.2023

Çiğdem Kuş , Havva Ataş , Adnan Kenar , Mustafa Taştekin

https://doi.org/10.18596/jotcsa.1124772

Abstract

This study describes a multi-ion-selective electrode system for the simultaneous determination of nitrate and chloride ions in air samples by using multivariate calibration methods. The measurement system was constituted of two ion-selective electrodes, an Ag/AgCl double-junction reference electrode and a multi-potentiometer. The measurements were performed at pH 5.0 acetic acid/sodium acetate buffer. The obtained data were evaluated by using Partial Least Squares (PLS1). The system was used to analyze the synthetic samples and fume-hood samples in terms of the amount of chloride and nitrate. The percentage recovery values obtained from fume-hood samples were 93.8% ± 3.8 and 102.4% ± 2.5 for chloride and nitrate, respectively. The presented system could be an easy-to-use approach for monitoring the amount of chloride and nitrate species in the scope of occupational health and safety analysis.

Keywords

Multiple ion-selective electrode array, nitrate analysis, chloride analysis, multivariate calibration techniques, chemometrics, air samples

Supporting Institution

Ankara University Research Fund

Project Number

BAP No. 12B4240008

Thanks

The authors gratefully acknowledge the financial support of Ankara University Research Fund (BAP No. 12B4240008).

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