Research Article
BibTex RIS Cite

Preparation and Characterization of Some Complexes of Nickel(II), Copper (II), and Zinc (II) With Decylxanthate and their Adducts with Nitrogen Base Ligands, and their Biological Activity

Year 2023, Volume: 10 Issue: 4, 975 - 984, 11.11.2023
https://doi.org/10.18596/jotcsa.1311891

Abstract

This research includes the synthesis and characterization of twelve new complexes of mono nuclear xanthate for a number of transition metal ions Ni(II), Cu(II), and Zn(II) and through the interaction with ligand (potassium decyl xanthate) and complexes of formula [M(DEXANT)2] were prepared: M= Ni(II), Cu(II), and Zn(II), and then the interaction of these complexes with Lewis bidentate bases, to give complexes with the formula [M(DEXANT)2.L], where L= 1,10-phenanthroline, 8-hydroxyquinoline, and 2,2-bipyridine. The prepared complexes were characterized by melting point, atomic absorption spectrometry, micro elemental analysis, infrared spectroscopy, proton nuclear magnetic resonance spectroscopy, molar electrical conductivity, electronic absorption spectra, and magnetic susceptibility measurements. Magnetic moment and electronic spectra indicated that the complexes of type [M(DEXANT)2] had a tetrahedral geometry, while complexes of type [M(DEXANT)2.L] had an octahedral geometry. The conductivity measurements proved the non-electrolytic behavior of all compounds. The biological evaluation against bacterial species indicated that the xanthate complexes were effective against all bacterial types.

Thanks

All the researchers thank the Deanship of the College of Education for Pure Sciences, Department of Chemistry, University of Mosul, Iraq, for completing the research requirements.

References

  • 1. Ghoshal S, Jain VK. Gallium(III) and indium(III) dithiolate complexes: versatile precursors for metal sulfides. Journal of Chemical Sciences. 2007;119:583-91. Available from: <URL>.
  • 2. Chand VT. Synthesis of metal xanthates and their application as latent catalysts for curing of epoxy resin. PhD Thesis, 2015. Kyushu University, Japan. Available from: <URL>.
  • 3. Rumyantsev M, Korablev IA, Rumyantsev S. The reaction of potassium xanthates with five-membered cyclic carbonates: Selectivity of the underlying cascade reactions and mechanistic insights. RSC advances. 2020;10(60):36303-16. Available from: <URL>.
  • 4. Vakalopoulou E, Buchmaier C, Pein A, Saf R, Fischer RC, Torvisco A, et al. Synthesis and characterization of zinc di (O-2, 2-dimethylpentan-3-yl dithiocarbonates) bearing pyridine or tetramethylethylenediamine coligands and investigation of their thermal conversion mechanisms towards nanocrystalline zinc sulfide. Dalton Transactions. 2020;49(41):14564-75. Available from: <URL>.
  • 5. Görgülü AO, Arslan M, Çİl E. Synthesis and characterization of a new pyrrolidine containing sulfur ligand and the transition metal complexes of Co (II), Ni (II) and Cu (I). Journal of Coordination Chemistry. 2006;59(17):1913-9. Available from: <URL>.
  • 6. Perluigi M, Joshi G, Sultana R, Calabrese V, De Marco C, Coccia R, et al. In vivo protection by the xanthate tricyclodecan-9-yl-xanthogenate against amyloid β-peptide (1–42)-induced oxidative stress. Neuroscience. 2006;138(4):1161-70. Available from: <URL>.
  • 7. Larsson A-C, Öberg S. Study on potassium iso-propylxanthate and its decomposition products: experimental 13C CP/MAS NMR combined with DFT calculations. The Journal of Physical Chemistry A. 2011;115(8):1396-407. Available from: <URL>.
  • 8. Ma X, Wang S, Zhong H. Effective production of sodium isobutyl xanthate using carbon disulfide as a solvent: Reaction kinetics, calorimetry and scale-up. Journal of Cleaner Production. 2018;200:444-53. Available from: <URL>.
  • 9. A Al-Qasser I, E Al-Mukhtar S, F Hana N. Synthesis and Characterization of 2-butoxyethylxanthate complexes with iron(II), cobalt(II), nickel(II), copper(II) and zinc(II) and their adducts with nitrogen base ligands. Rafidain Journal of Science. 2014;25(3):57-64. Available from: <URL>.
  • 10. Sharma S, Sachar R, Bajju G, Sharma V. Nickel (II) complexes of m-ethylphenylxanthate with nitrogen donors and their biological screening. Indian Journal of Chemistry-Section A (IJCA). 2020;59(11):1618-26. Available from: <URL>.
  • 11. Al-Mukhtar SE, Al-Katib HF, Al-Nuaimy LA. Preparation and characterization of some transition metal complexes with crotyl xanthate ligand and their adducts with nitrogen bases. Rafidain Journal of Science. 2017;26(1):49-55. Available from: <URL>.
  • 12. Al-Jarah FK, Al-Mukhtar SE. Preparation and characterization of some transition metal complexes with oleyl xanthate and 1, 10-phenanthrolin. Rafidain Journal of Science. 2019;28(2):228-34. Available from: <URL>.
  • 13. Al-Fahdawi A, Alsalihi E. Synthesis and characterization of iron(II), cobalt(II), nickel(II), copper(II), and zinc(II) complexes using diphenylmethyl xanthate ligand. ARO-The Scientific Journal of Koya University. 2018;6(1):33-7. Available from: <URL>.
  • 14. Adel HI, AL-Mukhtar SE. Synthesis and characterization of sulfur donor ligand (Xanthate) Complexes With manganese(ll), iron(ll), cobalt(ll), nikel(ll), copper(ll), and zinc(ll) and thier adduct with nitrogen base ligande. Journal of Duhok University. 2022;25(2):244-60. Available from: <URL>.
  • 15. Al-Mukhtar S. Synthesis and characterization of 3-Methoxypropyldithiocarbamate complexes with iron(II), cobalt(II), nickel(II), copper(II) and zinc(II) and their adducts with nitrogen base ligands. Rafidain journal of science. 2013;24(7):50-9. Available from: <URL>.
  • 16. Nakamoto K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, Part A: Theory and Applications in Inorganic Chemistry, 6th Edition. New York. 2009; 165-322. ISBN: 978-0-471-74339-2
  • 17. Abed RR, Mohammed AS, Ahmed FJ. Synthesis and diagnoses of new metal ions complexes derived from trimethoprim schiff bases. Research Journal of Pharmacy and Technology, 2021; 14(9), 4963-4968.‏ Available from: <URL>.
  • 18 Numan AT, Ibraheem KR, Ibrahim MK. Synthesis, characterization and bacterial evaluation of new mixed-ligand complexes containing dithiocarbamate and 1, 10-phenanthroline with some metal ions. Journal of Education and Scientific Studies. 2018;3(12). Available from: <URL>.
Year 2023, Volume: 10 Issue: 4, 975 - 984, 11.11.2023
https://doi.org/10.18596/jotcsa.1311891

Abstract

References

  • 1. Ghoshal S, Jain VK. Gallium(III) and indium(III) dithiolate complexes: versatile precursors for metal sulfides. Journal of Chemical Sciences. 2007;119:583-91. Available from: <URL>.
  • 2. Chand VT. Synthesis of metal xanthates and their application as latent catalysts for curing of epoxy resin. PhD Thesis, 2015. Kyushu University, Japan. Available from: <URL>.
  • 3. Rumyantsev M, Korablev IA, Rumyantsev S. The reaction of potassium xanthates with five-membered cyclic carbonates: Selectivity of the underlying cascade reactions and mechanistic insights. RSC advances. 2020;10(60):36303-16. Available from: <URL>.
  • 4. Vakalopoulou E, Buchmaier C, Pein A, Saf R, Fischer RC, Torvisco A, et al. Synthesis and characterization of zinc di (O-2, 2-dimethylpentan-3-yl dithiocarbonates) bearing pyridine or tetramethylethylenediamine coligands and investigation of their thermal conversion mechanisms towards nanocrystalline zinc sulfide. Dalton Transactions. 2020;49(41):14564-75. Available from: <URL>.
  • 5. Görgülü AO, Arslan M, Çİl E. Synthesis and characterization of a new pyrrolidine containing sulfur ligand and the transition metal complexes of Co (II), Ni (II) and Cu (I). Journal of Coordination Chemistry. 2006;59(17):1913-9. Available from: <URL>.
  • 6. Perluigi M, Joshi G, Sultana R, Calabrese V, De Marco C, Coccia R, et al. In vivo protection by the xanthate tricyclodecan-9-yl-xanthogenate against amyloid β-peptide (1–42)-induced oxidative stress. Neuroscience. 2006;138(4):1161-70. Available from: <URL>.
  • 7. Larsson A-C, Öberg S. Study on potassium iso-propylxanthate and its decomposition products: experimental 13C CP/MAS NMR combined with DFT calculations. The Journal of Physical Chemistry A. 2011;115(8):1396-407. Available from: <URL>.
  • 8. Ma X, Wang S, Zhong H. Effective production of sodium isobutyl xanthate using carbon disulfide as a solvent: Reaction kinetics, calorimetry and scale-up. Journal of Cleaner Production. 2018;200:444-53. Available from: <URL>.
  • 9. A Al-Qasser I, E Al-Mukhtar S, F Hana N. Synthesis and Characterization of 2-butoxyethylxanthate complexes with iron(II), cobalt(II), nickel(II), copper(II) and zinc(II) and their adducts with nitrogen base ligands. Rafidain Journal of Science. 2014;25(3):57-64. Available from: <URL>.
  • 10. Sharma S, Sachar R, Bajju G, Sharma V. Nickel (II) complexes of m-ethylphenylxanthate with nitrogen donors and their biological screening. Indian Journal of Chemistry-Section A (IJCA). 2020;59(11):1618-26. Available from: <URL>.
  • 11. Al-Mukhtar SE, Al-Katib HF, Al-Nuaimy LA. Preparation and characterization of some transition metal complexes with crotyl xanthate ligand and their adducts with nitrogen bases. Rafidain Journal of Science. 2017;26(1):49-55. Available from: <URL>.
  • 12. Al-Jarah FK, Al-Mukhtar SE. Preparation and characterization of some transition metal complexes with oleyl xanthate and 1, 10-phenanthrolin. Rafidain Journal of Science. 2019;28(2):228-34. Available from: <URL>.
  • 13. Al-Fahdawi A, Alsalihi E. Synthesis and characterization of iron(II), cobalt(II), nickel(II), copper(II), and zinc(II) complexes using diphenylmethyl xanthate ligand. ARO-The Scientific Journal of Koya University. 2018;6(1):33-7. Available from: <URL>.
  • 14. Adel HI, AL-Mukhtar SE. Synthesis and characterization of sulfur donor ligand (Xanthate) Complexes With manganese(ll), iron(ll), cobalt(ll), nikel(ll), copper(ll), and zinc(ll) and thier adduct with nitrogen base ligande. Journal of Duhok University. 2022;25(2):244-60. Available from: <URL>.
  • 15. Al-Mukhtar S. Synthesis and characterization of 3-Methoxypropyldithiocarbamate complexes with iron(II), cobalt(II), nickel(II), copper(II) and zinc(II) and their adducts with nitrogen base ligands. Rafidain journal of science. 2013;24(7):50-9. Available from: <URL>.
  • 16. Nakamoto K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, Part A: Theory and Applications in Inorganic Chemistry, 6th Edition. New York. 2009; 165-322. ISBN: 978-0-471-74339-2
  • 17. Abed RR, Mohammed AS, Ahmed FJ. Synthesis and diagnoses of new metal ions complexes derived from trimethoprim schiff bases. Research Journal of Pharmacy and Technology, 2021; 14(9), 4963-4968.‏ Available from: <URL>.
  • 18 Numan AT, Ibraheem KR, Ibrahim MK. Synthesis, characterization and bacterial evaluation of new mixed-ligand complexes containing dithiocarbamate and 1, 10-phenanthroline with some metal ions. Journal of Education and Scientific Studies. 2018;3(12). Available from: <URL>.
There are 18 citations in total.

Details

Primary Language English
Subjects Biochemistry and Cell Biology (Other), Transition Metal Chemistry
Journal Section RESEARCH ARTICLES
Authors

Mahameed Ameen 0009-0002-5932-0108

Fadia Ahmed 0000-0001-7275-2584

Publication Date November 11, 2023
Submission Date June 8, 2023
Acceptance Date August 14, 2023
Published in Issue Year 2023 Volume: 10 Issue: 4

Cite

Vancouver Ameen M, Ahmed F. Preparation and Characterization of Some Complexes of Nickel(II), Copper (II), and Zinc (II) With Decylxanthate and their Adducts with Nitrogen Base Ligands, and their Biological Activity. JOTCSA. 2023;10(4):975-84.