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A Statistical Study Comparing Experimental and Theoretical Yields of Activated Carbon Prepared from Pomegranate (Punica granatum) Peels via Chemical Treatment

Year 2024, Volume: 11 Issue: 4, 1407 - 1416, 03.12.2024
https://doi.org/10.18596/jotcsa.1416075

Abstract

Due to the great importance that activated carbon has gained through its use in combating pollution, removing dyes components, and other uses, it has been prepared in different ways. In this
research, a statistical study was conducted to compare the practical and theoretical values of activated carbon yield prepared from pomegranate peels with some additives (Novolak resin and Beji asphalt) in order to improve its specifications. Since the preparation of activated carbon is controlled by a group of variables, a number of matters were tested for the possibility of finding a linear relationship based on the effect of the amount of the iodine number, density, ash content, and humidity on the yield of all prepared types of activated carbon, and considering the possibility of achieving the relationship through additional additives that can be obtained through it on carbon with a homogeneous surface and specifications. Also, finding a general mathematical relationship that brings together all the types prepared from pomegranate peels after adding new variables representing the percentages of adding asphalt to them and novolak resin used in preparation and activation. This equation makes it possible to control the proportions of the resulting yield before trying to measure, test and evaluate any of the practically calculated values such as the iodine number, density, ash content and humidity using the mathematical equation and calculating them for unknown values if the other characteristics are known. This achieves a shortening of the time
period. The success of this method is evidenced by the high experimental R2 values, the low SE, and the logical variation of the variable coefficients.

References

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  • 2. Al-Dabouni AA. Introduction to petrochemicals. University of Mosul; 1991. 307–322 p.
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  • 4. De Ridder DJ. Adsorption of organic micropollutants onto activated carbon and zeolites. Water Manag Acad Press [Internet]. 2012;7–14. Available from: <URL>.
  • 5. Lozano-Castelló D, Lillo-Ródenas MA, Cazorla-Amorós D, Linares-Solano A. Preparation of activated carbons from Spanish anthracite. Carbon N Y [Internet]. 2001 Apr 1;39(5):741–9. Available from: <URL>.
  • 6. Pradhan S. Production and characterization of Activated carbon produced from asuitable Industrial Sludge [Internet]. National Institute of Technology; 2011. Available from: <URL>.
  • 7. Shahbeik H, Bagheri N, Ghorbanian SA, Hallajisani A, Pourkarimi S. A new adsorption isotherm model of aqueous solutions on granular activated carbon. World J Model Simul [Internet]. 2013;9(4):243–54. Available from: <URL>.
  • 8. Inagaki M. New carbons - control of structure and functions [Internet]. Elsevier; 2000. Available from: <URL>.
  • 9. Gottipati R. Preparation and characterization of microporous activated carbon from biomass and its application in the removal of Chromium(VI) from aqueous phase. National Institute of Technology Rourkela; 2012.
  • 10. AL Ghannam KA, Aweed KA, Hamdoon AA. Preparation of activated from Morus nigra by chemical treatment. Natl J Chem. 2004;13:26–33.
  • 11. Aweed KA. Production of activated carbon from some agricultural wastes by chemical treatment. Natl J Chem [Internet]. 2005;17:138–42. Available from: <URL>.
  • 12. Hamdon AA, Abdul Aziz AN, Ali MH. Study the effect of the structural modifications on the properties of the activated carbon prepared from coconut-shell by chemical treatment. Tikrit J Pure Sci [Internet]. 2008;13(3):278–82. Available from: <URL>.
  • 13. Saleh NJ, Ismaeel MI, Ibrahim RI, Zablouk MA, Amer A. Preparation activated carbon of from Iraqi reed. Eng Technol J [Internet]. 2008 Mar 28 [cited 2024 Aug 28];26(3):291–304. Available from: <URL>.
  • 14. Ramakrishnan K, Namasivayam C. Development and characteristic of activated carbons from Jatropha husk, an agro industrial solid waste, by chemical activation methods. J Environ Eng Manag [Internet]. 2009;19(3):173–8. Available from: <URL>.
  • 15. Ragan S, Megonnell N. Activated carbon from renewable resources-lignin. Cellul Chem Technol [Internet]. 2011;45(8):527–31. Available from: <URL>.
  • 16. Zengin A, Akalin MK, Tekin K, Erdem M, Tay T, Karagoz S. Preparation and characterization of activated carbons from waste melamine coated chipboard by NaOH activation. Ekoloji [Internet]. 2012 Dec 31;21(85):123–8. Available from: <URL>.
  • 17. Al-Badran SFJ. Preparation of activated carbon by chemical activation with phosphoric acid using Cordia myxa fruits nuclei as raw material. J Basrah Res [Internet]. 2013;39(4B):98–106. Available from: <URL>.
  • 18. Abechi SE, Gimba CE, Uzairu A, Dallatu YA. Preparation and characterization of activated carbon from palm kernel shell by chemical activation. Res J Chem Sci [Internet]. 2013;3(7):54–61. Available from: <URL>.
  • 19. Salman JM. Preparation of mesoporous‐activated carbon from branches of pomegranate trees: optimization on removal of methylene blue using response surface methodology. Giuliani A, editor. J Chem [Internet]. 2013 Jan 12;2013(1):489670. Available from: <URL>.
  • 20. Njewa JB, Vunain E, Biswick T. Synthesis and characterization of activated carbons prepared from agro-wastes by chemical activation. Guo W, editor. J Chem [Internet]. 2022 Mar 22;2022(1):975444. Available from: <URL>.
  • 21. Islam MN, Khatton A, Sarker ahid, Sikder HA, Chowdhury AMS. Preparation and characterization of activated carbon from jute stick by chemical activation: Comparison of different activating agents. Saudi J Eng Technol [Internet]. 2022 Feb 28;7(2):112–7. Available from: <URL>.
  • 22. Al-Hyali EAS, Al-Khazraji AAH, Al-Taey SIK. A Thermodynamic and kinetic study for adsorption of a number of dyes from their aqueous solutions on a new kind of activated carbon prepared by pomegranate (Punica granatum) peels via chemical treatment. Int J Enhanc Res Sci [Internet]. 2016;5(3):82–116. Available from: <URL>.
  • 23. AL-Taey SIK. Preparation of new types of activated carbon and testing their efficiency by the adsorption of some dyes, thermodynamic and kinetic studies. 2017.
  • 24. Ma R, Qin X, Liu Z, Fu Y. Adsorption property, kinetic and equilibrium studies of activated carbon fiber prepared from liquefied wood by ZnCl2 activation. Materials (Basel) [Internet]. 2019 Apr 28;12(9):1377. Available from: <URL>.
  • 25. ASTMD2854-70. Standard test method for apparent density activated carbon. 2000.
  • 26. Test method for activated carbon. Roster bau int. Engineering GMBH. W. Germany Devtschos Arzneibuch 6th Edition. 1999.
  • 27. Sunanda, Tiwari DP, Sharma DN, Thakur S, Kumar RTS. Sapindus based activated carbon by chemical activation. Res J Mater Sci [Internet]. 2013;1(7):9–15. Available from: <URL>.
Year 2024, Volume: 11 Issue: 4, 1407 - 1416, 03.12.2024
https://doi.org/10.18596/jotcsa.1416075

Abstract

References

  • 1. Jabit NB. The production and characterization of activated carbon using local agricultural waste through chemical activation process [Internet]. 2007. Available from: <URL>.
  • 2. Al-Dabouni AA. Introduction to petrochemicals. University of Mosul; 1991. 307–322 p.
  • 3. Alhamed Y. Activated carbon from dates’ stone by ZnCl2 activation. J King Abdulaziz Univ Sci [Internet]. 2006;17(2):75–98. Available from: <URL>.
  • 4. De Ridder DJ. Adsorption of organic micropollutants onto activated carbon and zeolites. Water Manag Acad Press [Internet]. 2012;7–14. Available from: <URL>.
  • 5. Lozano-Castelló D, Lillo-Ródenas MA, Cazorla-Amorós D, Linares-Solano A. Preparation of activated carbons from Spanish anthracite. Carbon N Y [Internet]. 2001 Apr 1;39(5):741–9. Available from: <URL>.
  • 6. Pradhan S. Production and characterization of Activated carbon produced from asuitable Industrial Sludge [Internet]. National Institute of Technology; 2011. Available from: <URL>.
  • 7. Shahbeik H, Bagheri N, Ghorbanian SA, Hallajisani A, Pourkarimi S. A new adsorption isotherm model of aqueous solutions on granular activated carbon. World J Model Simul [Internet]. 2013;9(4):243–54. Available from: <URL>.
  • 8. Inagaki M. New carbons - control of structure and functions [Internet]. Elsevier; 2000. Available from: <URL>.
  • 9. Gottipati R. Preparation and characterization of microporous activated carbon from biomass and its application in the removal of Chromium(VI) from aqueous phase. National Institute of Technology Rourkela; 2012.
  • 10. AL Ghannam KA, Aweed KA, Hamdoon AA. Preparation of activated from Morus nigra by chemical treatment. Natl J Chem. 2004;13:26–33.
  • 11. Aweed KA. Production of activated carbon from some agricultural wastes by chemical treatment. Natl J Chem [Internet]. 2005;17:138–42. Available from: <URL>.
  • 12. Hamdon AA, Abdul Aziz AN, Ali MH. Study the effect of the structural modifications on the properties of the activated carbon prepared from coconut-shell by chemical treatment. Tikrit J Pure Sci [Internet]. 2008;13(3):278–82. Available from: <URL>.
  • 13. Saleh NJ, Ismaeel MI, Ibrahim RI, Zablouk MA, Amer A. Preparation activated carbon of from Iraqi reed. Eng Technol J [Internet]. 2008 Mar 28 [cited 2024 Aug 28];26(3):291–304. Available from: <URL>.
  • 14. Ramakrishnan K, Namasivayam C. Development and characteristic of activated carbons from Jatropha husk, an agro industrial solid waste, by chemical activation methods. J Environ Eng Manag [Internet]. 2009;19(3):173–8. Available from: <URL>.
  • 15. Ragan S, Megonnell N. Activated carbon from renewable resources-lignin. Cellul Chem Technol [Internet]. 2011;45(8):527–31. Available from: <URL>.
  • 16. Zengin A, Akalin MK, Tekin K, Erdem M, Tay T, Karagoz S. Preparation and characterization of activated carbons from waste melamine coated chipboard by NaOH activation. Ekoloji [Internet]. 2012 Dec 31;21(85):123–8. Available from: <URL>.
  • 17. Al-Badran SFJ. Preparation of activated carbon by chemical activation with phosphoric acid using Cordia myxa fruits nuclei as raw material. J Basrah Res [Internet]. 2013;39(4B):98–106. Available from: <URL>.
  • 18. Abechi SE, Gimba CE, Uzairu A, Dallatu YA. Preparation and characterization of activated carbon from palm kernel shell by chemical activation. Res J Chem Sci [Internet]. 2013;3(7):54–61. Available from: <URL>.
  • 19. Salman JM. Preparation of mesoporous‐activated carbon from branches of pomegranate trees: optimization on removal of methylene blue using response surface methodology. Giuliani A, editor. J Chem [Internet]. 2013 Jan 12;2013(1):489670. Available from: <URL>.
  • 20. Njewa JB, Vunain E, Biswick T. Synthesis and characterization of activated carbons prepared from agro-wastes by chemical activation. Guo W, editor. J Chem [Internet]. 2022 Mar 22;2022(1):975444. Available from: <URL>.
  • 21. Islam MN, Khatton A, Sarker ahid, Sikder HA, Chowdhury AMS. Preparation and characterization of activated carbon from jute stick by chemical activation: Comparison of different activating agents. Saudi J Eng Technol [Internet]. 2022 Feb 28;7(2):112–7. Available from: <URL>.
  • 22. Al-Hyali EAS, Al-Khazraji AAH, Al-Taey SIK. A Thermodynamic and kinetic study for adsorption of a number of dyes from their aqueous solutions on a new kind of activated carbon prepared by pomegranate (Punica granatum) peels via chemical treatment. Int J Enhanc Res Sci [Internet]. 2016;5(3):82–116. Available from: <URL>.
  • 23. AL-Taey SIK. Preparation of new types of activated carbon and testing their efficiency by the adsorption of some dyes, thermodynamic and kinetic studies. 2017.
  • 24. Ma R, Qin X, Liu Z, Fu Y. Adsorption property, kinetic and equilibrium studies of activated carbon fiber prepared from liquefied wood by ZnCl2 activation. Materials (Basel) [Internet]. 2019 Apr 28;12(9):1377. Available from: <URL>.
  • 25. ASTMD2854-70. Standard test method for apparent density activated carbon. 2000.
  • 26. Test method for activated carbon. Roster bau int. Engineering GMBH. W. Germany Devtschos Arzneibuch 6th Edition. 1999.
  • 27. Sunanda, Tiwari DP, Sharma DN, Thakur S, Kumar RTS. Sapindus based activated carbon by chemical activation. Res J Mater Sci [Internet]. 2013;1(7):9–15. Available from: <URL>.
There are 27 citations in total.

Details

Primary Language English
Subjects Physical Chemistry (Other)
Journal Section RESEARCH ARTICLES
Authors

Semaa Khaleel 0009-0005-8687-3164

Ammar A.h. Al-khazraji This is me

Emad A.s. Al-hyali This is me

Publication Date December 3, 2024
Submission Date January 7, 2024
Acceptance Date August 5, 2024
Published in Issue Year 2024 Volume: 11 Issue: 4

Cite

Vancouver Khaleel S, Al-khazraji AA, Al-hyali EA. A Statistical Study Comparing Experimental and Theoretical Yields of Activated Carbon Prepared from Pomegranate (Punica granatum) Peels via Chemical Treatment. JOTCSA. 2024;11(4):1407-16.