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Chromium Coating of Wollastonite Filled Polyamide 6 and Evaluation of Thermal Cycle Strength

Year 2023, , 107 - 122, 01.10.2023
https://doi.org/10.58692/jotcsb.1345824

Abstract

The chromium coating of plastic/polymer materials through electrolysis method has attracted attention for improving material properties. The most common material used to be coated is the Acrylonitrile Butadiene Styrene (ABS), but has disadvantages compared to polyamides (PA), such as low thermal resistance. PA’s high water retention disadvantage can be substituted by using fillers such as clay, etc; so in this study, 40% Wollastonite filled PA has been used for chromium plating to increase the thermal resistance of the PA. The plates used were produced by injection molding method. The research is focused on the effect of time and concentration on coating performance in etching, activation (by palladium) and accelerator processes. SEM and EDX were used to characterize samples for surface morphologies and the microstructures of etching, activation and accelerator in the PA sub-plates. Additionally, cross-cut adhesion test has been applied to analyze the adhesion power of the interfaces. It was found that the thermal resistance of the metal plate on the polymer surface decreased as the time increased, in relation with the increasing wearing time of the metal plate mentioned above. The thermal resistance decreased as the polymer deformed in relation with the increase in etching solution’s concentration. It is also seen that the thermal resistance improved as the activation time increased. The adhesion and the thermal resistance did not improve as the time in accelerator process increased. Furthermore, the cross – cut adhesion tests on the same samples concluded that the results are in agreement with the other thermal resistance results.

References

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Year 2023, , 107 - 122, 01.10.2023
https://doi.org/10.58692/jotcsb.1345824

Abstract

References

  • Baglin, J. E. E. (1988). Thin film adhesion: New possibilities for interface engineering. Materials Science and Engineering: B, 1(1), 1–7. https://doi.org/10.1016/0921-5107(88)90024-4
  • Bucknall, C. (1977). . Toughened Plastics. .
  • Charbonnier, M., & Romand, M. (2003). Polymer pretreatments for enhanced adhesion of metals deposited by the electroless process. International Journal of Adhesion and Adhesives, 23(4), 277–285. https://doi.org/10.1016/S0143-7496(03)00045-9
  • Ciullo P.A. (1996). Industrial Minerals and Their Uses: A handbook & Formulary. Noyes Publication.
  • Davies, D., & Whittaker, J. A. (1967). Methods of testing the adhesion of metal coatings to metals. International Materials Reviews, 12(1), 15–26. https://doi.org/10.1179/imr.1967.12.1.15
  • Eksi O. (2007). Plastik Esaslı Malzemelerin Isıl Sekil Verme Özelliklerinin İncelenmesi. https://tez.yok.gov.tr/UlusalTezMerkezi
  • Kato, K. (1968). Electron Microscope Studies on the Etching of ABS Moldings for Electroplating. Journal of Electron Microscopy. https://doi.org/10.1093/oxfordjournals.jmicro.a049589
  • Kogel, J. E. , T. N. C. , B. J. M. , K. S. T. (2006). Industrial Minerals & Rocks : Vol. 7th Edition. Society for Mining, Metallurgy, and Exploration, Inc.
  • Kuzmik JJ. (1974). Preparation of plastic surbstrates for electroless plating and solutions therefor. (Patent 3,790,400). United States Patent. .
  • Melentiev, R., Yudhanto, A., Tao, R., Vuchkov, T., & Lubineau, G. (2022). Metallization of polymers and composites: State-of-the-art approaches. Materials & Design, 221, 110958. https://doi.org/10.1016/j.matdes.2022.110958
  • Mittal, K. L. (1990). Metallized plastics 2, Fundamental and Applied Aspects. .
  • Murdan, S., Kerai, L., & Hossin, B. (2015). To what extent do in vitro tests correctly predict the in vivo residence of nail lacquers on the nail plate? Journal of Drug Delivery Science and Technology, 25, 23–28. https://doi.org/10.1016/j.jddst.2014.11.002
  • Shigemitsu H. (1986). Method For Plating Polyamide Resin Molded Article (Patent U.S. Patent No:4,563,242.). Patent Ohtake. Japan.
  • Springer, J. S. (1994). Ontario Wollastonite: Uses, Markets and Ontario’s Potential as a Future Producer. Ministry of Northern Development, Mines, Natural Resources and Forestry.
  • Stevenson M. R. (1985). Metal Plating Of Polyamide Thermoplastics (Patent U.S. Patent No:4,552,626.). United States Patent Grosse Pointe woods. Mich. .
There are 15 citations in total.

Details

Primary Language English
Subjects Electrochemical Technologies
Journal Section Full-length articles
Authors

Ramiz Akay 0000-0001-6625-4044

Hakan Yazıcı 0000-0001-7284-6599

Publication Date October 1, 2023
Submission Date August 18, 2023
Acceptance Date September 29, 2023
Published in Issue Year 2023

Cite

APA Akay, R., & Yazıcı, H. (2023). Chromium Coating of Wollastonite Filled Polyamide 6 and Evaluation of Thermal Cycle Strength. Journal of the Turkish Chemical Society Section B: Chemical Engineering, 6(2), 107-122. https://doi.org/10.58692/jotcsb.1345824

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This piece of scholarly information is licensed under Creative Commons Atıf-GayriTicari-AynıLisanslaPaylaş 4.0 Uluslararası Lisansı.

J. Turk. Chem. Soc., Sect. B: Chem. Eng. (JOTCSB)