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Year 2016, Volume: 1 Issue: 1, 13 - 24, 23.02.2017

Abstract

References

  • James H. Gary, Glenn H. Handwerk, Mark J. Kaiser. Catalytic Hydrocracking. In: James H. Gary, Glenn H. Handwerk, Mark J. Kaiser. editors. Petroleum Refining: Technology and Economics. 5 ed. Boca Raton: CRC Press; 2007. p. 161-79.
  • Alain Billon, Pierre-Henri Bigeard. Hydrocracking. In: Pierre Leprince. editor. Petroleum Refining. Vol. 3 Conversion Processes. : Institut Français Du Petrole Publication; 2001. p. 288.
  • Adrian Gruia. Distillate Hydrocracking. In: David S. J. “Stan” Jones, Peter R. Pujadó, editors. Handbook of Petroleum Processing. Dordrecht: Springer Netherlands; 2006. p. 287-320.
  • Patricia Rayo Mayoral, Juarez Jorge Ancheyta , Marroquin Sanchez Gustavo Jesus, Centeno Nolasco Guillermo, Jorge Fernando Ramirez Solis, Mesoporous Composite Of Molecular Sieves for Hydrocracking of Heavy Crude Oils and Residues, US20140124410, filed in December 19, 2012, issued in January 26, 2014.
  • Marchand Karin, Chaumonnot Alexandra, Bonduelle Audrey, Dufaud Veronique, Lefebvre Frederic, Bader Manuela, Lopes Silva Susana, Process for the Hydrocrackıng of Hydrocarbon Cuts Using A Catalyst Based on Heteropolyanıons Trapped in A Mesostructured Oxide Support, US20130334099, filed in December 15, 2011, issued in December 19, 2013.
  • Omer Refa Koseoglu, Adnan Al-Hajji, Ali Mahmood Al-Somali, Ali H. Al-Abdul’Al, Mishaal Al-Thukair, Masaru Ushio, Ryuzo Kuroda, Takashi Kameoka, Koji Nakano, Yuichi Takamori, Hydrocracking Catalyst for Hydrocarbon Oil, Method for Producing Hydrocracking Catalyst, and Method for Hydrocracking Hydrocarbon Oil with Hydrocracking Catalyst, filed August 02, 2011, and issued July 11, 2013.
  • Qi Bangfeng, Gan Weğmin, Meng Fanmei, Silicon-Aluminum Carrier Containing Two Modified Molecular Sieves, Preparation Method and Application Thereof, filed July 22, 2013, and issued December 31, 2014.
  • Zhang Zhihua, Yan Zifeng, Dai Baoqin, Liu Xinmei, Tian Ran, Li Haiyan, Sun Famin,
  • Qin Lihong, Zhang Wencheng, Lyu Qian, Xie Bin, Wang Dongqing, Wang Fucun, Guo Shuzhi, Zhang Qingwu, Wang Yan, Yu Xiujuan, Bing Shuqiu, Usy Molecular Sieve Modification Method, filed April 03, 2013, and issued October 15, 2014.
  • Kwan Young Lee, Hee Jun Eom, Seong Min Kim, Young Gul Hur, Method for Preparing Light Distillate from Extra-Middle Distillate by Using Heteropolyacid Catalyst Substituted with Cesium, and Method for Regenerating Catalyst, filed August 14, 2013, and issued October 09, 2014.
  • Lu Yinhua, Fan Lichuang, Liu Feipeng, Hao Kun, Tao Zhichao, Yang Yong, Li Yongwang, Non-Sulfur Catalyst as well as Preparation Method and Application Thereof, filed July 11, 2013, and issued September 18, 2013.
  • Dong Songtao, Dong Jianwei, Nie Hong, Shi Yahua, Li Dadong, Hydrocracking Catalyst, Preparation and Application Thereof, filed March 15, 2013, and issued September 17, 2014.
  • Melek Bardakcı Türkmen. Recent Developments in Hydrocracking Catalysts – Patent and Open Literature Survey. In: Deniz Üner. editor. Advances in Refining Catalysis. :CRC Press; in press.

EFFECTS OF MATERIAL CHARACTERISTICS ON PERFORMANCE OF HYDROCRACKING CATALYSTS

Year 2016, Volume: 1 Issue: 1, 13 - 24, 23.02.2017

Abstract

Hydrocracking is a refinery process used to convert heavy hydrocarbon fractions to lighter cuts with high added value. The products that usually range from heavy diesel to light naphtha involving middle distillate as targeted cut are obtained as a result of hydrocracking process of feed with higher molecular weights and lower hydrogen/carbon ratios. Hydrocracking reactions occur under high hydrogen partial pressures and temperatures in the presence of catalyst in order to remove impurities such as sulfur compounds and crack heavy hydrocarbon molecules to high added value lighter cuts. Hydrocracking catalysts are bifunctional in which metal function with hydrogenation consisting group VIB or group VIIIB is for removal of impurities and acidic support consisting amorphous oxides and/or crystalline zeolites to realize cracking function.

In this study, the association between the performance test results obtained from laboratory scale reactor system and the material characteristics of the catalysts are viewed. Selectivity, hydrocracking and hydrogenation activities within the performance parameters of the catalysts are calculated based on the fraction ratios and feed-product properties. Furthermore, the effect of hydrotreating activity on hydrocracking activity is also highlighted. The surface area and pore size, crystallinity, chemical composition of the material and acidic properties are investigated within the scope of material characteristics of the catalysts by using BET, XRD, XRF, NH3-TPD techniques, respectively.

References

  • James H. Gary, Glenn H. Handwerk, Mark J. Kaiser. Catalytic Hydrocracking. In: James H. Gary, Glenn H. Handwerk, Mark J. Kaiser. editors. Petroleum Refining: Technology and Economics. 5 ed. Boca Raton: CRC Press; 2007. p. 161-79.
  • Alain Billon, Pierre-Henri Bigeard. Hydrocracking. In: Pierre Leprince. editor. Petroleum Refining. Vol. 3 Conversion Processes. : Institut Français Du Petrole Publication; 2001. p. 288.
  • Adrian Gruia. Distillate Hydrocracking. In: David S. J. “Stan” Jones, Peter R. Pujadó, editors. Handbook of Petroleum Processing. Dordrecht: Springer Netherlands; 2006. p. 287-320.
  • Patricia Rayo Mayoral, Juarez Jorge Ancheyta , Marroquin Sanchez Gustavo Jesus, Centeno Nolasco Guillermo, Jorge Fernando Ramirez Solis, Mesoporous Composite Of Molecular Sieves for Hydrocracking of Heavy Crude Oils and Residues, US20140124410, filed in December 19, 2012, issued in January 26, 2014.
  • Marchand Karin, Chaumonnot Alexandra, Bonduelle Audrey, Dufaud Veronique, Lefebvre Frederic, Bader Manuela, Lopes Silva Susana, Process for the Hydrocrackıng of Hydrocarbon Cuts Using A Catalyst Based on Heteropolyanıons Trapped in A Mesostructured Oxide Support, US20130334099, filed in December 15, 2011, issued in December 19, 2013.
  • Omer Refa Koseoglu, Adnan Al-Hajji, Ali Mahmood Al-Somali, Ali H. Al-Abdul’Al, Mishaal Al-Thukair, Masaru Ushio, Ryuzo Kuroda, Takashi Kameoka, Koji Nakano, Yuichi Takamori, Hydrocracking Catalyst for Hydrocarbon Oil, Method for Producing Hydrocracking Catalyst, and Method for Hydrocracking Hydrocarbon Oil with Hydrocracking Catalyst, filed August 02, 2011, and issued July 11, 2013.
  • Qi Bangfeng, Gan Weğmin, Meng Fanmei, Silicon-Aluminum Carrier Containing Two Modified Molecular Sieves, Preparation Method and Application Thereof, filed July 22, 2013, and issued December 31, 2014.
  • Zhang Zhihua, Yan Zifeng, Dai Baoqin, Liu Xinmei, Tian Ran, Li Haiyan, Sun Famin,
  • Qin Lihong, Zhang Wencheng, Lyu Qian, Xie Bin, Wang Dongqing, Wang Fucun, Guo Shuzhi, Zhang Qingwu, Wang Yan, Yu Xiujuan, Bing Shuqiu, Usy Molecular Sieve Modification Method, filed April 03, 2013, and issued October 15, 2014.
  • Kwan Young Lee, Hee Jun Eom, Seong Min Kim, Young Gul Hur, Method for Preparing Light Distillate from Extra-Middle Distillate by Using Heteropolyacid Catalyst Substituted with Cesium, and Method for Regenerating Catalyst, filed August 14, 2013, and issued October 09, 2014.
  • Lu Yinhua, Fan Lichuang, Liu Feipeng, Hao Kun, Tao Zhichao, Yang Yong, Li Yongwang, Non-Sulfur Catalyst as well as Preparation Method and Application Thereof, filed July 11, 2013, and issued September 18, 2013.
  • Dong Songtao, Dong Jianwei, Nie Hong, Shi Yahua, Li Dadong, Hydrocracking Catalyst, Preparation and Application Thereof, filed March 15, 2013, and issued September 17, 2014.
  • Melek Bardakcı Türkmen. Recent Developments in Hydrocracking Catalysts – Patent and Open Literature Survey. In: Deniz Üner. editor. Advances in Refining Catalysis. :CRC Press; in press.
There are 13 citations in total.

Details

Journal Section Full-length articles
Authors

Melek Bardakcı Türkmen This is me

Burcu Yüzüak This is me

Ayşegül Bayat This is me

Deniz Onay Atmaca This is me

Volkan Balci This is me

Seçil Ünsal This is me

Can Erkey This is me

Ersen Ertaş This is me

Publication Date February 23, 2017
Submission Date September 2, 2016
Published in Issue Year 2016 Volume: 1 Issue: 1

Cite

APA Bardakcı Türkmen, M., Yüzüak, B., Bayat, A., Onay Atmaca, D., et al. (2017). EFFECTS OF MATERIAL CHARACTERISTICS ON PERFORMANCE OF HYDROCRACKING CATALYSTS. Journal of the Turkish Chemical Society Section B: Chemical Engineering, 1(1), 13-24.

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J. Turk. Chem. Soc., Sect. B: Chem. Eng. (JOTCSB)