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Adsorption of CI Basic Blue 3 Dye Molecules from Aqueous Media by Sulfuric Acid-Activated Montmorillonite Mineral

Year 2017, Volume 1, Issue Sp. is. 1, 1 - 16, 20.10.2017

Abstract

Many industries (especially textile, paper, plastic) which use chemicals and colorants, generate considerable amount of waste water since they use excessive amounts of water in their operations. and they These waste waters form a significant reason of worldwide water pollution, and if they are released before being treated, they bring an important harm to these waters.  Therefore, In this paper, adsorption kinetics and equilibrium of CI Basic Blue 3 (BB3) from aqueous media using sulfuric acid-activated montmorillonite mineral (SAM) was investigated. For this aim, firstly the natural montmorillonite mineral (NM) was activated by treating with a 6 M H2SO4 solution for 4 hours at 395 K. After sulfuric acid treatment the SAM samples were characterized using a BET surface analyzer and FTIR spectroscopy. The adsorption experiments in different conditions such as i.e., contact times (0-120 min), initial pH values (2-8), temperatures (298-318 K), and initial dye concentrations (100-350 mg/l) were performed in a thermostatic water bath at an agitation speed of 180 rpm. The experimental maximum adsorption capacity (qe) was determined to be 277 mg/g at 60 min, 6 ± 0.02, 298 K and 350 ppm initial dye concentration. For adsorption of CI Basic Blue 3 (BB3) molecules from aqueous media by the supfuric acid activated montmorillonite mineral (SAM) is determined that Lagergren’s kinetic model (pseudo first order) simulated the kinetic data better than the Ho’s kinetic model (pseudo second order) and the Freundlich isotherm is the best fitting isotherm model equation. Also, the thermodynamic parameters calculated using Van't Hoff equation show that the adsorption process is spontaneous and exothermic. The experimental results of the study indicated that, the acid activated mineral is suitable for adsorption of BB3 dye molecules from aqueous media.

References

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  • 2. Chhabra M, Mishra S, Sreekrishnan TR. Combination of chemical and enzymatic treatment for efficient decolorization/degradation of textile effluent: High operational stability of the continuous process. Biochem Eng J. 2015;Complete(93):17–24.
  • 3. Dulman V, Cucu-Man SM. Sorption of some textile dyes by beech wood sawdust. J Hazard Mater. Mart 2009;162(2–3):1457–64.
  • 4. Annadurai G, Ling LY, Lee JF. Adsorption of reactive dye from an aqueous solution by chitosan: isotherm, kinetic and thermodynamic analysis. J Hazard Mater. Mart 2008;152(1):337–46.
  • 5. Mahmoodi NM, Salehi R, Arami M, Bahrami H. Dye Removal from Colored Textile Wastewater Using Chitosan in Binary Systems. Desalination. 01 Şubat 2011;267:64–72.
  • 6. Çakmak M, Taşar Ş, Selen V, Özer D, Özer A. Removal of astrazon golden yellow 7GL from colored wastewater using chemically modified clay. J Cent South Univ. 01 Nisan 2017;24(4):743–53. 7. Selen V, Güler Ö, Özer D, Evin E. Synthesized multi-walled carbon nanotubes as a potential adsorbent for the removal of methylene blue dye: kinetics, isotherms, and thermodynamics. Desalination Water Treat. 20 Nisan 2016;57(19):8826–38.
  • 8. Angin D. Utilization of activated carbon produced from fruit juice industry solid waste for the adsorption of Yellow 18 from aqueous solutions. Bioresour Technol. Eylül 2014;168:259–66.
  • 9. Zou W, Li K, Bai H, Shi X, Han R. Enhanced Cationic Dyes Removal from Aqueous Solution by Oxalic Acid Modified Rice Husk. J Chem Eng Data. 12 Mayıs 2011;56(5):1882–91.
  • 10. Song J, Zou W, Bian Y, Su F, Han R. Adsorption characteristics of methylene blue by peanut husk in batch and column modes. Desalination. 15 Ocak 2011;265(1):119–25.
  • 11. Kim T-H, Park C, Kim S. Water recycling from desalination and purification process of reactive dye manufacturing industry by combined membrane filtration. J Clean Prod. 01 Haziran 2005;13(8):779–86.
  • 12. Türgay O, Ersöz G, Atalay S, Forss J, Welander U. The treatment of azo dyes found in textile industry wastewater by anaerobic biological method and chemical oxidation. Sep Purif Technol. 19 Mayıs 2011;79(1):26–33.
  • 13. Nanofiltration and reverse osmosis thin film composite membrane module for the removal of dye and salts from the simulated mixtures [Internet]. [kaynak 24 Eylül 2017]. Available at: https://www.researchgate.net/publication/244144789_Nanofiltration_and_reverse_osmosis_thin_film_composite_membrane_module_for_the_removal_of_dye_and_salts_from_the_simulated_mixtures
  • 14. Coagulation/flocculation process for dye removal using water treatment residuals: modelling through artificial neural networks: Desalination and Water Treatment: Vol 57, No 55 [Internet]. [kaynak 24 Eylül 2017]. Available at: http://www.tandfonline.com/doi/abs/10.1080/19443994.2016.1165150?src=recsys&journalCode=tdwt20
  • 15. Bohli T, Ouederni A, Fiol N, Villaescusa I. Uptake of Cd2+ and Ni2+ Metal Ions from Aqueous solutions By Activated Carbons Derived from Waste Olive Stones. C. 3. 2012. 232 s.
  • 16. Rozada F, Otero M, Morán A, García AI. Adsorption of heavy metals onto sewage sludge-derived materials. Bioresour Technol. Eylül 2008;99(14):6332–8.
  • 17. Ma Y, Gao N, Chu W, Li C. Removal of phenol by powdered activated carbon adsorption. Front Environ Sci Eng. 01 Nisan 2013;7(2):158–65. 18. Banerjee S, Chattopadhyaya M. Adsorption characteristics for the removal of a toxic dye, tartrazine from aqueous solutions by a low cost agricultural by-product. C. 170. 2013.
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  • 20. Vijayakumar G, TAMILARASAN R, Dharmendirakumar M. Adsorption, Kinetic, Equilibrium and Thermodynamic studies on the removal of basic dye Rhodamine-B from aqueous solution by the use of natural adsorbent perlite. J Mater Environ Sci. 01 Ocak 2012;3.
  • 21. Liu H, Yuan P, Qin Z, Liu D, Tan D, Zhu J, vd. Thermal degradation of organic matter in the interlayer clay–organic complex: A TG-FTIR study on a montmorillonite/12-aminolauric acid system. C. 80–81. 2013. 398 s.
  • 22. Öztürk N, Tabak A, Akgöl S, Denizli A. Newly synthesized bentonite–histidine (Bent–His) micro-composite affinity sorbents for IgG adsorption. Colloids Surf Physicochem Eng Asp. 05 Temmuz 2007;301(1):490–7.
  • 23. Lee J-W, Choi S-P, Thiruvenkatachari R, Shim W-G, Moon H. Evaluation of the performance of adsorption and coagulation processes for the maximum removal of reactive dyes. Dyes Pigments. 01 Ocak 2006;69(3):196–203.
  • 24. Yao Y, Bing H, Feifei X, Xiaofeng C. Equilibrium and kinetic studies of methyl orange adsorption on multiwalled carbon nanotubes. Chem Eng J. 15 Mayıs 2011;170(1):82–9.
  • 25. Wang P, Cao M, Wang C, Ao Y, Hou J, Qian J. Kinetics and thermodynamics of adsorption of methylene blue by a magnetic graphene-carbon nanotube composite. Appl Surf Sci. 01 Ocak 2014;290:116–24.
  • 26. Özer A, Akkaya G, Turabik M. Biosorption of Acid Blue 290 (AB 290) and Acid Blue 324 (AB 324) Dyes on Spirogyra rhizopus. J Hazard Mater. 01 Ağustos 2006;135:355–64.
  • 27. Vijayaraghavan K, Yun Y-S. Bacterial biosorbents and biosorption. Biotechnol Adv. Haziran 2008;26(3):266–91.
  • 28. S L. ABOUT THE THEORY OF SO-CALLED ADSORPTION OF SOLUBLE SUBSTANCES. 01 Ocak 1898;24(4):1–39.
  • 29. Ho YS, McKay G. Pseudo-second order model for sorption processes. Process Biochem. 01 Temmuz 1999;34(5):451–65.
  • 30. Ozer D, Dursun G, Ozer A. Methylene blue adsorption from aqueous solution by dehydrated peanut hull. J Hazard Mater. Haziran 2007;144(1–2):171–9.
  • 31. Vimonses V, Lei S, Jin B, Chow CWK, Saint C. Kinetic study and equilibrium isotherm analysis of Congo Red adsorption by clay materials. Chem Eng J. 15 Mayıs 2009;148(2):354–64.
  • 32. Toor M, Jin B. Adsorption characteristics, isotherm, kinetics, and diffusion of modified natural bentonite for removing diazo dye. Chem Eng J. 01 Nisan 2012;187(Supplement C):79–88.
  • 33. Langmuir I. THE CONSTITUTION AND FUNDAMENTAL PROPERTIES OF SOLIDS AND LIQUIDS. II. LIQUIDS.1. J Am Chem Soc. 01 Eylül 1917;39(9):1848–906.
  • 34. Freundlich H. Über die Adsorption in Lösungen. Leipzig: Wilhelm Engelmann; 1906. 98 s.
  • 35. Yu Y, Zhuang Y-Y, Wang Z-H. Adsorption of Water-Soluble Dye onto Functionalized Resin. J Colloid Interface Sci. 15 Ekim 2001;242(2):288–93.
  • 36. Chatterjee S, Chatterjee S, Chatterjee BP, Guha AK. Adsorptive removal of congo red, a carcinogenic textile dye by chitosan hydrobeads: Binding mechanism, equilibrium and kinetics. Colloids Surf Physicochem Eng Asp. 15 Mayıs 2007;299(1):146–52.

Year 2017, Volume 1, Issue Sp. is. 1, 1 - 16, 20.10.2017

Abstract

References

  • 1. Gong R, Li M, Yang C, Sun Y, Chen J. Removal of cationic dyes from aqueous solution by adsorption on peanut hull. J Hazard Mater. 20 Mayıs 2005;121(1–3):247–50.
  • 2. Chhabra M, Mishra S, Sreekrishnan TR. Combination of chemical and enzymatic treatment for efficient decolorization/degradation of textile effluent: High operational stability of the continuous process. Biochem Eng J. 2015;Complete(93):17–24.
  • 3. Dulman V, Cucu-Man SM. Sorption of some textile dyes by beech wood sawdust. J Hazard Mater. Mart 2009;162(2–3):1457–64.
  • 4. Annadurai G, Ling LY, Lee JF. Adsorption of reactive dye from an aqueous solution by chitosan: isotherm, kinetic and thermodynamic analysis. J Hazard Mater. Mart 2008;152(1):337–46.
  • 5. Mahmoodi NM, Salehi R, Arami M, Bahrami H. Dye Removal from Colored Textile Wastewater Using Chitosan in Binary Systems. Desalination. 01 Şubat 2011;267:64–72.
  • 6. Çakmak M, Taşar Ş, Selen V, Özer D, Özer A. Removal of astrazon golden yellow 7GL from colored wastewater using chemically modified clay. J Cent South Univ. 01 Nisan 2017;24(4):743–53. 7. Selen V, Güler Ö, Özer D, Evin E. Synthesized multi-walled carbon nanotubes as a potential adsorbent for the removal of methylene blue dye: kinetics, isotherms, and thermodynamics. Desalination Water Treat. 20 Nisan 2016;57(19):8826–38.
  • 8. Angin D. Utilization of activated carbon produced from fruit juice industry solid waste for the adsorption of Yellow 18 from aqueous solutions. Bioresour Technol. Eylül 2014;168:259–66.
  • 9. Zou W, Li K, Bai H, Shi X, Han R. Enhanced Cationic Dyes Removal from Aqueous Solution by Oxalic Acid Modified Rice Husk. J Chem Eng Data. 12 Mayıs 2011;56(5):1882–91.
  • 10. Song J, Zou W, Bian Y, Su F, Han R. Adsorption characteristics of methylene blue by peanut husk in batch and column modes. Desalination. 15 Ocak 2011;265(1):119–25.
  • 11. Kim T-H, Park C, Kim S. Water recycling from desalination and purification process of reactive dye manufacturing industry by combined membrane filtration. J Clean Prod. 01 Haziran 2005;13(8):779–86.
  • 12. Türgay O, Ersöz G, Atalay S, Forss J, Welander U. The treatment of azo dyes found in textile industry wastewater by anaerobic biological method and chemical oxidation. Sep Purif Technol. 19 Mayıs 2011;79(1):26–33.
  • 13. Nanofiltration and reverse osmosis thin film composite membrane module for the removal of dye and salts from the simulated mixtures [Internet]. [kaynak 24 Eylül 2017]. Available at: https://www.researchgate.net/publication/244144789_Nanofiltration_and_reverse_osmosis_thin_film_composite_membrane_module_for_the_removal_of_dye_and_salts_from_the_simulated_mixtures
  • 14. Coagulation/flocculation process for dye removal using water treatment residuals: modelling through artificial neural networks: Desalination and Water Treatment: Vol 57, No 55 [Internet]. [kaynak 24 Eylül 2017]. Available at: http://www.tandfonline.com/doi/abs/10.1080/19443994.2016.1165150?src=recsys&journalCode=tdwt20
  • 15. Bohli T, Ouederni A, Fiol N, Villaescusa I. Uptake of Cd2+ and Ni2+ Metal Ions from Aqueous solutions By Activated Carbons Derived from Waste Olive Stones. C. 3. 2012. 232 s.
  • 16. Rozada F, Otero M, Morán A, García AI. Adsorption of heavy metals onto sewage sludge-derived materials. Bioresour Technol. Eylül 2008;99(14):6332–8.
  • 17. Ma Y, Gao N, Chu W, Li C. Removal of phenol by powdered activated carbon adsorption. Front Environ Sci Eng. 01 Nisan 2013;7(2):158–65. 18. Banerjee S, Chattopadhyaya M. Adsorption characteristics for the removal of a toxic dye, tartrazine from aqueous solutions by a low cost agricultural by-product. C. 170. 2013.
  • 19. Baseline Studies of Source Clays [Internet]. [kaynak 24 Eylül 2017]. Available at: http://www.clays.org/sourceclays_baseline_studies.html
  • 20. Vijayakumar G, TAMILARASAN R, Dharmendirakumar M. Adsorption, Kinetic, Equilibrium and Thermodynamic studies on the removal of basic dye Rhodamine-B from aqueous solution by the use of natural adsorbent perlite. J Mater Environ Sci. 01 Ocak 2012;3.
  • 21. Liu H, Yuan P, Qin Z, Liu D, Tan D, Zhu J, vd. Thermal degradation of organic matter in the interlayer clay–organic complex: A TG-FTIR study on a montmorillonite/12-aminolauric acid system. C. 80–81. 2013. 398 s.
  • 22. Öztürk N, Tabak A, Akgöl S, Denizli A. Newly synthesized bentonite–histidine (Bent–His) micro-composite affinity sorbents for IgG adsorption. Colloids Surf Physicochem Eng Asp. 05 Temmuz 2007;301(1):490–7.
  • 23. Lee J-W, Choi S-P, Thiruvenkatachari R, Shim W-G, Moon H. Evaluation of the performance of adsorption and coagulation processes for the maximum removal of reactive dyes. Dyes Pigments. 01 Ocak 2006;69(3):196–203.
  • 24. Yao Y, Bing H, Feifei X, Xiaofeng C. Equilibrium and kinetic studies of methyl orange adsorption on multiwalled carbon nanotubes. Chem Eng J. 15 Mayıs 2011;170(1):82–9.
  • 25. Wang P, Cao M, Wang C, Ao Y, Hou J, Qian J. Kinetics and thermodynamics of adsorption of methylene blue by a magnetic graphene-carbon nanotube composite. Appl Surf Sci. 01 Ocak 2014;290:116–24.
  • 26. Özer A, Akkaya G, Turabik M. Biosorption of Acid Blue 290 (AB 290) and Acid Blue 324 (AB 324) Dyes on Spirogyra rhizopus. J Hazard Mater. 01 Ağustos 2006;135:355–64.
  • 27. Vijayaraghavan K, Yun Y-S. Bacterial biosorbents and biosorption. Biotechnol Adv. Haziran 2008;26(3):266–91.
  • 28. S L. ABOUT THE THEORY OF SO-CALLED ADSORPTION OF SOLUBLE SUBSTANCES. 01 Ocak 1898;24(4):1–39.
  • 29. Ho YS, McKay G. Pseudo-second order model for sorption processes. Process Biochem. 01 Temmuz 1999;34(5):451–65.
  • 30. Ozer D, Dursun G, Ozer A. Methylene blue adsorption from aqueous solution by dehydrated peanut hull. J Hazard Mater. Haziran 2007;144(1–2):171–9.
  • 31. Vimonses V, Lei S, Jin B, Chow CWK, Saint C. Kinetic study and equilibrium isotherm analysis of Congo Red adsorption by clay materials. Chem Eng J. 15 Mayıs 2009;148(2):354–64.
  • 32. Toor M, Jin B. Adsorption characteristics, isotherm, kinetics, and diffusion of modified natural bentonite for removing diazo dye. Chem Eng J. 01 Nisan 2012;187(Supplement C):79–88.
  • 33. Langmuir I. THE CONSTITUTION AND FUNDAMENTAL PROPERTIES OF SOLIDS AND LIQUIDS. II. LIQUIDS.1. J Am Chem Soc. 01 Eylül 1917;39(9):1848–906.
  • 34. Freundlich H. Über die Adsorption in Lösungen. Leipzig: Wilhelm Engelmann; 1906. 98 s.
  • 35. Yu Y, Zhuang Y-Y, Wang Z-H. Adsorption of Water-Soluble Dye onto Functionalized Resin. J Colloid Interface Sci. 15 Ekim 2001;242(2):288–93.
  • 36. Chatterjee S, Chatterjee S, Chatterjee BP, Guha AK. Adsorptive removal of congo red, a carcinogenic textile dye by chitosan hydrobeads: Binding mechanism, equilibrium and kinetics. Colloids Surf Physicochem Eng Asp. 15 Mayıs 2007;299(1):146–52.

Details

Subjects Engineering
Journal Section Full-length articles
Authors

Şeyda TAŞAR
Firat University
0000-0003-3184-1542
Türkiye


Fatih KAYA
FATİH ÜNİVERSİTESİ
0000-0003-3184-1542
Türkiye


Ahmet ÖZER
FATİH ÜNİVERSİTESİ
0000-0003-3184-1542
Türkiye

Publication Date October 20, 2017
Application Date October 20, 2017
Acceptance Date October 19, 2017
Published in Issue Year 2017, Volume 1, Issue Sp. is. 1

Cite

Vancouver Taşar Ş. , Kaya F. , Özer A. Adsorption of CI Basic Blue 3 Dye Molecules from Aqueous Media by Sulfuric Acid-Activated Montmorillonite Mineral. Journal of the Turkish Chemical Society Section B: Chemical Engineering. 2017; 1(Sp. is. 1): 1-16.

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J. Turk. Chem. Soc., Sect. B: Chem. Eng. (JOTCSB)