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REMOVAL OF HEXAVALENT CHROMIUM FROM WATER BY USING NATURAL BROWN CLAY

Year 2017, Özel Sayı 2, 43 - 52, 23.11.2017

Abstract

The present study investigates the removal of chromium from aqueous solution, by natural Algerian brown clay, in batch mode, at different temperatures. Kinetic experiment showed that the adsorption process can be simulated by pseudo-second order model. In order to determine the best-fit-isotherm, the experimental data were analyzed by the Freundlich, Langmuir, Temkin and Dubinin-Radushkevich equation, at different temperatures of 20, 30, 40 and 50°C. The mean deviation obtained from the four models revealed that Freundlich is the most suitable one. The results showed that natural brown clay is effective to remove chromium (VI) about 90% at 20°C.



References

  • Alonso, A.I., Galán, B., González, M., Ortiz, I., 1999. Experimental and theoretical analysis of a nondispersive solvent extraction pilot plant for the removal of Cr(VI) from a galvanic process wastewaters, Ind. Eng. Chem. Res., 38, 1666.
  • Arfaouia, S., Frini-Srasraa, N., Srasra, E., 2008. Modelling of the adsorption of the chromium ion by modified clays, Desalination, 222, 474.
  • Barkat, M., Chegrouche, S., Mellah, A., Bensmain, B., Nibou, D., Boufatit, M., 2014. Application of algerian bentonite in the removal of cadmium (II) and chromium (VI) from aqueous solutions, J. Surf. Eng. Mater. Adv. Technol., 4, 210.
  • El-Taweel, Y.A., Nassef, E.M., Elkheriany, I., Sayed, D., 2015. Removal of Cr(VI) ions from waste water by electrocoagulation using iron electrode, Egyptian Journal of Petroleum, 24(2), 183.
  • Hafez, A., El-Manharawy, S., 2004. Design and performance of the two-stage/two-pass RO membrane system for chromium removal from tannery wastewater. Part 3, Desalination, 165, 141.
  • Ho, Y.S., McKay, G., 1999. Pseudo-scond order model for sorption process, Process Biochem, 34, 451.
  • Hsu, L.C., Wang, S.L., Lin, Y.C., Wang, M.K., Chiang, P.N., Liu, J.C., Kuan, W.H., Chen, C.C., Tzou, Y.M., 2010. Cr(VI) removal on fungal biomass of neurospora crassa: the importance of dissolved organic carbons derived from the biomass to Cr(VI) reduction, Environ. Sci. Technol. 44, 6202.
  • Kashif Uddin, M., 2017. A review on the adsorption of heavy metals by clay minerals, with special focus on the past decade, J. Chem. Eng., 308, 438.
  • Lagergren, S., 1898. Zur theorie Der sogenanntenadsorption gel ster stoffe. Kung-liga Svenska Vetenakapsakademiens Handlingar, 24, 1.
  • Rengaraj, S., Kyeong-Ho Yeon, Seung-Hyeon Moon, 2001. Removal of chromium from water and wastewater by ion exchange resins, J. Hazard.Mater., 87(1-3), 273.
  • Wanees, S. A., Ahmed, A.M., Adam, M.S., Mohamed, M.A., 2013. Adsorption Studies on the Removal of Hexavalent Chromium-Contaminated Wastewater, Asian Journal of Chemistry, 25(15), 8245.
  • Yuan, P., Liu, D., Fan., M., Yang, D., Zhu, R., Ge, F., Zhu, J., He, H., 2010. Removal of Hexavalent Chromium [Cr(VI)] from Aqueous Solutions by the Diatomite-Supported/Unsupported Magnetite Nanoparticles, J. Hazard. Mater., 173, 614.
  • Zhan, Y.B., Shukla, A., Shukls, S., Dorris, K.L., 2000.The removal of heavy metal from aqueous solutions by sawdust adsorption - removal of copper, J. Hazard. Mater., 80, 33.
Year 2017, Özel Sayı 2, 43 - 52, 23.11.2017

Abstract

References

  • Alonso, A.I., Galán, B., González, M., Ortiz, I., 1999. Experimental and theoretical analysis of a nondispersive solvent extraction pilot plant for the removal of Cr(VI) from a galvanic process wastewaters, Ind. Eng. Chem. Res., 38, 1666.
  • Arfaouia, S., Frini-Srasraa, N., Srasra, E., 2008. Modelling of the adsorption of the chromium ion by modified clays, Desalination, 222, 474.
  • Barkat, M., Chegrouche, S., Mellah, A., Bensmain, B., Nibou, D., Boufatit, M., 2014. Application of algerian bentonite in the removal of cadmium (II) and chromium (VI) from aqueous solutions, J. Surf. Eng. Mater. Adv. Technol., 4, 210.
  • El-Taweel, Y.A., Nassef, E.M., Elkheriany, I., Sayed, D., 2015. Removal of Cr(VI) ions from waste water by electrocoagulation using iron electrode, Egyptian Journal of Petroleum, 24(2), 183.
  • Hafez, A., El-Manharawy, S., 2004. Design and performance of the two-stage/two-pass RO membrane system for chromium removal from tannery wastewater. Part 3, Desalination, 165, 141.
  • Ho, Y.S., McKay, G., 1999. Pseudo-scond order model for sorption process, Process Biochem, 34, 451.
  • Hsu, L.C., Wang, S.L., Lin, Y.C., Wang, M.K., Chiang, P.N., Liu, J.C., Kuan, W.H., Chen, C.C., Tzou, Y.M., 2010. Cr(VI) removal on fungal biomass of neurospora crassa: the importance of dissolved organic carbons derived from the biomass to Cr(VI) reduction, Environ. Sci. Technol. 44, 6202.
  • Kashif Uddin, M., 2017. A review on the adsorption of heavy metals by clay minerals, with special focus on the past decade, J. Chem. Eng., 308, 438.
  • Lagergren, S., 1898. Zur theorie Der sogenanntenadsorption gel ster stoffe. Kung-liga Svenska Vetenakapsakademiens Handlingar, 24, 1.
  • Rengaraj, S., Kyeong-Ho Yeon, Seung-Hyeon Moon, 2001. Removal of chromium from water and wastewater by ion exchange resins, J. Hazard.Mater., 87(1-3), 273.
  • Wanees, S. A., Ahmed, A.M., Adam, M.S., Mohamed, M.A., 2013. Adsorption Studies on the Removal of Hexavalent Chromium-Contaminated Wastewater, Asian Journal of Chemistry, 25(15), 8245.
  • Yuan, P., Liu, D., Fan., M., Yang, D., Zhu, R., Ge, F., Zhu, J., He, H., 2010. Removal of Hexavalent Chromium [Cr(VI)] from Aqueous Solutions by the Diatomite-Supported/Unsupported Magnetite Nanoparticles, J. Hazard. Mater., 173, 614.
  • Zhan, Y.B., Shukla, A., Shukls, S., Dorris, K.L., 2000.The removal of heavy metal from aqueous solutions by sawdust adsorption - removal of copper, J. Hazard. Mater., 80, 33.
There are 13 citations in total.

Details

Subjects Engineering
Journal Section Full-length articles
Authors

Latifa Bentchikou This is me

Fatma-zohra Mechelouf This is me

Feyza Neggaz This is me

Abdelhamid Mellah This is me

Publication Date November 23, 2017
Submission Date December 12, 2017
Acceptance Date December 21, 2017
Published in Issue Year 2017 Özel Sayı 2

Cite

APA Bentchikou, L., Mechelouf, F.-z., Neggaz, F., Mellah, A. (2017). REMOVAL OF HEXAVALENT CHROMIUM FROM WATER BY USING NATURAL BROWN CLAY. Journal of the Turkish Chemical Society Section B: Chemical Engineering, 1(Sp. is. 2), 43-52.

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J. Turk. Chem. Soc., Sect. B: Chem. Eng. (JOTCSB)