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Study on Desulfurization of Light Gas Oil Using Ionic Liquids Assisted with Ultrasonication

Year 2020, Volume: 3 Issue: 1, 19 - 28, 30.05.2020

Abstract

The
present work aimed to investigate the feasibility of removing sulfur from real light
gas oil using different types of inorganic ionic liquids (ILs) assisted by
ultrasonic waves in a continuous flow setup. Experimental results showed that
within 30 min, 66% of sulfur was removed under mild conditions using 10wt%NaOH assisted
by ultrasonic waves. It was found that ultrasonic waves not only facilitate the
sulfur removal but it improves gas oil properties by decreasing density and viscosity
while cetane number (CN) showed a different trend. A correlation of solute
selectivity as a function of sulfur mole fraction was presented 

Thanks

Department of Chemical Engineering, University of Technology, PR&D center, Iraqi Ministry of Oil

References

  • 1. Song C. An overview of new approaches to deep desulfurization for ultra-clean gasoline, diesel fuel and jet fuel. Catalysis Today. 2003 Nov;86(1–4):211–63.
  • 2. Gawande P, Meghe D, Kaware J. Desulphurization Techniques for Liquid Fuel A Review. International Journal of Engineering Technology Management and Applied Sciences. 2014;2(7):121–7.
  • 3. Eßer J, Wasserscheid P, Jess A. Deep desulfurization of oil refinery streams by extraction with ionic liquids. Green Chem. 2004;6(7):316–22.
  • 4. Duarte FA, Mello P de A, Bizzi CA, Nunes MAG, Moreira EM, Alencar MS, et al. Sulfur removal from hydrotreated petroleum fractions using ultrasound-assisted oxidative desulfurization process. Fuel. 2011 Jun;90(6):2158–64.
  • 5. Shafeghat A, Ghaedian M, Mehrabi M. Desulfurization of gas oil by using ultrasonic waves. Journal of Petroleum Research. 2015;24(80):85–95.
  • 6. Mochizuki Y, Sugawara K. Removal of Organic Sulfur from Hydrocarbon Resources Using Ionic Liquids. Energy Fuels. 2008 Sep 17;22(5):3303–7.
  • 7. Li F, Liu Y, Sun Z, Chen L, Zhao D, Liu R, et al. Deep Extractive Desulfurization of Gasoline with x Et 3 NHCl·FeCl 3 Ionic Liquids. Energy Fuels. 2010 Aug 19;24(8):4285–9.
  • 8. Hansmeier AR, Meindersma GW, de Haan AB. Desulfurization and denitrogenation of gasoline and diesel fuels by means of ionic liquids. Green Chem. 2011;13(7):1907.
  • 9. Nie Y, Li C, Meng H, Wang Z. N,N-dialkylimidazolium dialkylphosphate ionic liquids: Their extractive performance for thiophene series compounds from fuel oils versus the length of alkyl group. Fuel Processing Technology. 2008 Oct;89(10):978–83.
  • 10. Jian-long W, Zhao D, Zhou E, Dong Z. Desulfurization of gasoline by extraction with N-alkyl-pyridinium-based ionic liquids. Journal of Fuel Chemistry and Technology. 2007 Jun;35(3):293–6.
  • 11. Kȩdra-Królik K, Fabrice M, Jaubert J-N. Extraction of Thiophene or Pyridine from n-Heptane Using Ionic Liquids. Gasoline and Diesel Desulfurization. Ind Eng Chem Res. 2011 Feb 16;50(4):2296–306.
  • 12. Liu X, Zhou G, Zhang S, Yu G. Molecular simulations of phosphonium-based ionic liquid. Molecular Simulation. 2010 Jan;36(1):79–86.
  • 13. Varma NR, Ramalingam A, Banerjee T. Experiments, correlations and COSMO-RS predictions for the extraction of benzothiophene from n-hexane using imidazolium-based ionic liquids. Chemical Engineering Journal. 2011 Jan;166(1):30–9.
  • 14. Chen X, Yuan S, Abdeltawab AA, Al-Deyab SS, Zhang J, Yu L, et al. Extractive desulfurization and denitrogenation of fuels using functional acidic ionic liquids. Separation and Purification Technology. 2014 Sep;133:187–93.
  • 15. Afshar A, Hashemi S. Role and effect of temperature on LPG sweetening process. International Journal of Chemical and Molecular Engineering. 2011;5(7):628–30.
  • 16. Mello P de A, Duarte FA, Nunes MAG, Alencar MS, Moreira EM, Korn M, et al. Ultrasound-assisted oxidative process for sulfur removal from petroleum product feedstock. Ultrasonics Sonochemistry. 2009 Aug;16(6):732–6.
  • 17. Shakirullah M, Ahmad I, Ahmad W, Ishaq M. DESULPHURIZATION STUDY OF PETROLEUM PRODUCTS THROUGH EXTRACTION WITH AQUEOUS IONIC LIQUIDS. J Chil Chem Soc [Internet]. 2010 Jun [cited 2020 Apr 13];55(2). Available from: http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072010000200007&lng=en&nrm=iso&tlng=en
  • 18. Heinrich G, Kasztelan S. Hydrotreating, in Petroleum Refining. Leprince P, editor. Paris: Institut Français Du Pétrole Publications; 2001.
  • 19. Cabo B. Desulfurization of fuels with ionic liquids by extraction and oxidative extraction processes [PhD Thesis]. [Compostela]: University of Santiago de Compostela; 2013.
  • 20. Robbins L, Cusack R. Liquid-Liquid Extraction Operations and Equipment. In: Green D, Maloney J, editors. Perry’s Chemical Engineering Handbook. New York: McGraw-Hill Company; 1997.
  • 21. Leerdam RC van. Anaerobic degradation of methanethiol in a process for Liquefied Petroleum Gas (LPG) biodesulfurization. 198 p.
  • 22. Supriyadi S, Purwanto P, Dwi anggoro D, Hermawan. Enhancing Biodiesel from Kemiri Sunan Oil Manufacturing using Ultrasonics. Hadiyanto, Sudarno, Maryono, editors. E3S Web Conf. 2018;31:02014.
  • 23. Stavarache C, Vinatoru M, Maeda Y. Ultrasonic versus silent methylation of vegetable oils. Ultrasonics Sonochemistry. 2006 Jul;13(5):401–7.
  • 24. Chen D, Sharma SK, Mudhoo A. Handbook on applications of ultrasound sonochemistry for sustainability [Internet]. Boca Raton, Fla.: CRC Press; 2012 [cited 2020 Apr 13]. Available from: https://www.taylorfrancis.com/books/9781439842072
Year 2020, Volume: 3 Issue: 1, 19 - 28, 30.05.2020

Abstract

References

  • 1. Song C. An overview of new approaches to deep desulfurization for ultra-clean gasoline, diesel fuel and jet fuel. Catalysis Today. 2003 Nov;86(1–4):211–63.
  • 2. Gawande P, Meghe D, Kaware J. Desulphurization Techniques for Liquid Fuel A Review. International Journal of Engineering Technology Management and Applied Sciences. 2014;2(7):121–7.
  • 3. Eßer J, Wasserscheid P, Jess A. Deep desulfurization of oil refinery streams by extraction with ionic liquids. Green Chem. 2004;6(7):316–22.
  • 4. Duarte FA, Mello P de A, Bizzi CA, Nunes MAG, Moreira EM, Alencar MS, et al. Sulfur removal from hydrotreated petroleum fractions using ultrasound-assisted oxidative desulfurization process. Fuel. 2011 Jun;90(6):2158–64.
  • 5. Shafeghat A, Ghaedian M, Mehrabi M. Desulfurization of gas oil by using ultrasonic waves. Journal of Petroleum Research. 2015;24(80):85–95.
  • 6. Mochizuki Y, Sugawara K. Removal of Organic Sulfur from Hydrocarbon Resources Using Ionic Liquids. Energy Fuels. 2008 Sep 17;22(5):3303–7.
  • 7. Li F, Liu Y, Sun Z, Chen L, Zhao D, Liu R, et al. Deep Extractive Desulfurization of Gasoline with x Et 3 NHCl·FeCl 3 Ionic Liquids. Energy Fuels. 2010 Aug 19;24(8):4285–9.
  • 8. Hansmeier AR, Meindersma GW, de Haan AB. Desulfurization and denitrogenation of gasoline and diesel fuels by means of ionic liquids. Green Chem. 2011;13(7):1907.
  • 9. Nie Y, Li C, Meng H, Wang Z. N,N-dialkylimidazolium dialkylphosphate ionic liquids: Their extractive performance for thiophene series compounds from fuel oils versus the length of alkyl group. Fuel Processing Technology. 2008 Oct;89(10):978–83.
  • 10. Jian-long W, Zhao D, Zhou E, Dong Z. Desulfurization of gasoline by extraction with N-alkyl-pyridinium-based ionic liquids. Journal of Fuel Chemistry and Technology. 2007 Jun;35(3):293–6.
  • 11. Kȩdra-Królik K, Fabrice M, Jaubert J-N. Extraction of Thiophene or Pyridine from n-Heptane Using Ionic Liquids. Gasoline and Diesel Desulfurization. Ind Eng Chem Res. 2011 Feb 16;50(4):2296–306.
  • 12. Liu X, Zhou G, Zhang S, Yu G. Molecular simulations of phosphonium-based ionic liquid. Molecular Simulation. 2010 Jan;36(1):79–86.
  • 13. Varma NR, Ramalingam A, Banerjee T. Experiments, correlations and COSMO-RS predictions for the extraction of benzothiophene from n-hexane using imidazolium-based ionic liquids. Chemical Engineering Journal. 2011 Jan;166(1):30–9.
  • 14. Chen X, Yuan S, Abdeltawab AA, Al-Deyab SS, Zhang J, Yu L, et al. Extractive desulfurization and denitrogenation of fuels using functional acidic ionic liquids. Separation and Purification Technology. 2014 Sep;133:187–93.
  • 15. Afshar A, Hashemi S. Role and effect of temperature on LPG sweetening process. International Journal of Chemical and Molecular Engineering. 2011;5(7):628–30.
  • 16. Mello P de A, Duarte FA, Nunes MAG, Alencar MS, Moreira EM, Korn M, et al. Ultrasound-assisted oxidative process for sulfur removal from petroleum product feedstock. Ultrasonics Sonochemistry. 2009 Aug;16(6):732–6.
  • 17. Shakirullah M, Ahmad I, Ahmad W, Ishaq M. DESULPHURIZATION STUDY OF PETROLEUM PRODUCTS THROUGH EXTRACTION WITH AQUEOUS IONIC LIQUIDS. J Chil Chem Soc [Internet]. 2010 Jun [cited 2020 Apr 13];55(2). Available from: http://www.scielo.cl/scielo.php?script=sci_arttext&pid=S0717-97072010000200007&lng=en&nrm=iso&tlng=en
  • 18. Heinrich G, Kasztelan S. Hydrotreating, in Petroleum Refining. Leprince P, editor. Paris: Institut Français Du Pétrole Publications; 2001.
  • 19. Cabo B. Desulfurization of fuels with ionic liquids by extraction and oxidative extraction processes [PhD Thesis]. [Compostela]: University of Santiago de Compostela; 2013.
  • 20. Robbins L, Cusack R. Liquid-Liquid Extraction Operations and Equipment. In: Green D, Maloney J, editors. Perry’s Chemical Engineering Handbook. New York: McGraw-Hill Company; 1997.
  • 21. Leerdam RC van. Anaerobic degradation of methanethiol in a process for Liquefied Petroleum Gas (LPG) biodesulfurization. 198 p.
  • 22. Supriyadi S, Purwanto P, Dwi anggoro D, Hermawan. Enhancing Biodiesel from Kemiri Sunan Oil Manufacturing using Ultrasonics. Hadiyanto, Sudarno, Maryono, editors. E3S Web Conf. 2018;31:02014.
  • 23. Stavarache C, Vinatoru M, Maeda Y. Ultrasonic versus silent methylation of vegetable oils. Ultrasonics Sonochemistry. 2006 Jul;13(5):401–7.
  • 24. Chen D, Sharma SK, Mudhoo A. Handbook on applications of ultrasound sonochemistry for sustainability [Internet]. Boca Raton, Fla.: CRC Press; 2012 [cited 2020 Apr 13]. Available from: https://www.taylorfrancis.com/books/9781439842072
There are 24 citations in total.

Details

Primary Language English
Subjects Chemical Engineering
Journal Section Full-length articles
Authors

Mohammad Abıd 0000-0001-5690-8577

Luma Mahmood This is me

Publication Date May 30, 2020
Submission Date September 30, 2018
Acceptance Date April 12, 2020
Published in Issue Year 2020 Volume: 3 Issue: 1

Cite

APA Abıd, M., & Mahmood, L. (2020). Study on Desulfurization of Light Gas Oil Using Ionic Liquids Assisted with Ultrasonication. Journal of the Turkish Chemical Society Section B: Chemical Engineering, 3(1), 19-28.

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J. Turk. Chem. Soc., Sect. B: Chem. Eng. (JOTCSB)