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Perovskit Tabanlı Güneş Hücresinde Vanadyum Beşoksit İnce Filmin Deşik İletim Tabakası Olarak Performansı

Year 2023, Volume: 1 Issue: 2, 67 - 75, 31.12.2023
https://doi.org/10.5281/zenodo.10445044

Abstract

Geleneksel fosil enerji kaynak rezervlerinin yakın gelecekte tükenecek olması ve ayrıca son yıllarda mevcut fosil yakıtları kullanan enerji üretim teknolojilerinin küresel ısınma ve diğer çevresel tehditlere yol açması nedeniyle, temiz, sürdürülebilir enerji kaynaklarına ilgi artmıştır. Bundan dolayı, özellikle uzun ömürlü doğal bir kaynak olan güneş, alternatif bir enerji kaynağı olarak kullanılmaktadır. Perovskitler ilk kez 2009 yılında güneş hücrelerinde kullanıldığı zaman verim %3,8 iken, son yıllarda yapılan yoğun araştırma ve geliştirme sonucunda 2023 yılına gelindiğinde bu alanda verim %25,7’e ulaşmış durumdadır. Tersine çevrilmiş yapıda deşik iletim materyali olarak çoğunlukla Poly(3,4ethylenedioxythio phene):poly(styrene-sulfonate) PEDOT:PSS kullanılmaktadır. PEDOT:PSS’in düşük kristalliği, düşük mobilitesi, asidik ve hidroskobik doğası nedeniyle kararlılığını arttırmak amacıyla farklı inorganikler deşik iletim materyali olarak kullanılmaktadır. Vanadyum oksitler (V2O3, VO2 ve V2O5) güneş hücreleri de dahil olmak üzere çok çeşitli uygulamalarda kullanılmaktadır. Vanadyum beşoksit (V2O5) ince filmleri çözeltiden dönel kaplama yöntemiyle elde edilerek yapısal ve optik özellikleri incelenmiştir. Tersine çevrilmiş (p-i-n) düzlemsel yapıda peroskit güneş hücrelerinde PEDOT:PSS ve V2O5 ince filmlerin deşik iletim tabakası olarak fotovoltaik performansı belirlendi.

Supporting Institution

Ardahan Üniversitesi

Project Number

2020/004

Thanks

Bu çalışma Ardahan Üniversitesi Bilimsel Araştırma Projeleri Koordinatörlüğü tarafından 2020/004 proje numarası ile desteklenmiştir. Prof. Dr. Serap Güneş’e bilimsel desteklerinden ve laboratuvar imkanlarını sunarak çalışmalarının yapılmasına imkân sağladığı için ve ekibine deneysel çalışmalardaki yardımlarından dolayı sonsuz teşekkürlerimi sunarım. Doç. Dr. Ali Baltakesmez ve Dr. Öğr. Üyesi Zakir Çaldıran’a desteklerinden dolayı çok teşekkür ederim.

References

  • A. Kojima, K. Teshima, Y. Shirai and T. Miyasaka, “Organometal halide perovskites as visible-light sensitizers for photovoltaic cells”, Journal of the American Chemical Society, vol. 131, no. 17, pp. 6050–6051, 2009.
  • National Renewable Energy Laboratory (NREL), https://www.nrel.gov/pv/cell-efficiency.html, 2023.
  • M. Grätzel, “The light and shade of perovskite solar cells” Nature Materials, vol. 13, no.9, pp. 838–842, 2014.
  • A. Fakharuddin, F. De Rossi, T. M. Watson, L. Schmidt-Mende and R. Jose, “Research Update: Behind the high efficiency of hybrid perovskite solar cells”, APL Materials, vol. 4, no. 9, pp. 0–16, 2016.
  • T. A. Berhe, W. N. Su, C. H. Chen, C. J. Pan, J. H. Cheng, H. M. Chen, B. J. Hwang, “Organometal halide perovskite solar cells: degradation and stability”, Energy Environ. Sci., vol. 9, 2016.
  • Z. Song, S. C. Watthage, A. B. Phillips and M. J. Heben, “Pathways toward high-performance perovskite solar cells: review of recent advances in organo-metal halide perovskites for photovoltaic applications”, Journal of Photonics for Energy, vol. 6, no.2, pp. 22001, 2016.
  • Yang Bai, Xiangyue Meng and Shihe Yang “Interface Engineering for Highly Efficient and Stable Planar p-i-n Perovskite Solar Cells”, Adv. Energy Mater., vol. 8, pp. 1701883, 2018.
  • L. Calió, S. Kazim, M. Grätzel and S. Ahmad, “Hole-Transport Materials for Perovskite Solar Cells”, Angew. Chemie - Int. Ed., vol. 55, pp. 14522–14545, 2016.
  • S. Pitchaiya, M. Natarajan, A. Santhanam, V. Asokan, A. Yuvapragasam, V. Madurai Ramakrishnan and et al., “A review on the classification of organic/inorganic/carbonaceous hole transporting materials for perovskite solar cell application”, Arab. J. Chem., vol. 13, pp. 2526–2557, 2020.
  • P. K. Kung, M.H. Li, P. Y. Lin, Y. H. Chiang, C. R. Chan, T. F. Guo and P. Chen., “A Review of Inorganic Hole Transport Materials for Perovskite Solar Cells”, Adv. Mater. Interfaces., vol. 5, pp. 1800882 (1–35), 2018.
  • Z. Shariatinia, “Recent progress in development of diverse kinds of hole transport materials for the perovskite solar cells: A review”, Renew. Sustain. Energy Rev., vol. 119, pp. 109608, 2020.
  • M. Liu, B. Su, Y. Tang, X. Jiang and A. Yu, “Recent Advances in Nanostructured Vanadium Oxides and Composites for Energy Conversion”, Adv. Energy Mater., vol. 7, pp. 1700885, 2017.
  • A. Mauger and C. M. Julien, “V2O5 thin films for energy storage and conversion”, AIMS Materials Science, vol. 5, no. 3, pp. 349–401, 2018.
  • I. Hancox, L. A. Rochford, D. Clare, M. Walker, J. J. Mudd, P. Sullivan, S. Schumann, C. F. McConville and T. S. Jones, “Optimization of a High Work Function Solution Processed Vanadium Oxide Hole-Extracting Layer for Small Molecule and Polymer Organic Photovoltaic Cells”, J. Phys. Chem. C., vol. 117, pp. 49−57, 2013.
  • H. Peng, W. Sun, Y. Li, S. Ye, H. Rao, W. Yan and et al., “Solution processed inorganic V2Ox as interfacial function materials for inverted planar-heterojunction perovskite solar cells with enhanced efficiency”, Nano Res., vol. 9, pp. 2960–2971, 2016.
  • L. Zhang, C. Jiang, C. Wu, H. Ju, G. Jiang, W. Liu and et al., “V2O5 as Hole Transporting Material for Efficient All Inorganic Sb2S3 Solar Cells”, ACS Appl. Mater. Interfaces, vol. 10, pp. 27098–27105, 2018.
  • Z. Liu, T. He, H. Wang, X. Song, H. Liu, J. Yang and et al., “Improving the stability of the perovskite solar cells by V2O5 modified transport layer film”, RSC Adv., vol. 7, pp. 18456–18465, 2017.
  • J. Wu, Y. Zhang, P. Xu, W. Guo, L. Shen and S. Ruan, “Role of solution-processed V2O5 in P3HT:PCBM based inverted polymer solar cells”, Synth. Met., vol. 170, pp. 7–10, 2013.
  • Y. L. Chan, S.-Y. Pung and S. Sreekantan, "Synthesis of V2O5 Nanoflakes on PET Fiber as Visible-Light-Driven Photocatalysts for Degradation of RhB Dye", Journal of Catalysts, vol. Article ID 370696, 7, 2014.
  • K. Schneider, “Optical properties and electronic structure of V2O5, V2O3 and VO2”, J Mater Sci: Mater Electron, vol. 31, pp. 10478–10488, 2020.

Performance of Vanadium Pentoxide Thin Film as Hole Conduction Layer in Perovskite Based Solar Cell

Year 2023, Volume: 1 Issue: 2, 67 - 75, 31.12.2023
https://doi.org/10.5281/zenodo.10445044

Abstract

Interest in clean, sustainable energy sources has increased due to the fact that traditional fossil energy resource reserves will be depleted in the near future and that energy production technologies that use existing fossil fuels cause global warming and other environmental threats. As a result, the sun, a long-lasting natural resource, is being explored as an alternative energy source. Solar cells are devices that convert sunlight directly into electrical energy. When perovskites were first introduced in solar cells in 2009, the efficiency was 3.8%. However, intensive research and development efforts in recent years have pushed the efficiency in this field to 25.7% by 2023. Poly(3,4-ethylenedioxythiophene):poly(styrene-sulfonate) (PEDOT:PSS) is commonly used as the hole transport material in the inverted structure. Due to PEDOT:PSS's low crystallinity, low mobility, and its acidic and hygroscopic nature, various inorganic materials are employed as hole transport materials to enhance stability. Vanadium oxides (V2O3, VO2 and V2O5) are used in a wide variety of applications, including solar cells. Vanadium pentoxide (V2O5) thin films were obtained from solution by spin coating method and their structural and optical properties were examined. The photovoltaic performance of PEDOT:PSS and V2O5 thin films as hole conduction layer in inverted (p-i-n) planar structure perovskite solar cells was determined.

Project Number

2020/004

References

  • A. Kojima, K. Teshima, Y. Shirai and T. Miyasaka, “Organometal halide perovskites as visible-light sensitizers for photovoltaic cells”, Journal of the American Chemical Society, vol. 131, no. 17, pp. 6050–6051, 2009.
  • National Renewable Energy Laboratory (NREL), https://www.nrel.gov/pv/cell-efficiency.html, 2023.
  • M. Grätzel, “The light and shade of perovskite solar cells” Nature Materials, vol. 13, no.9, pp. 838–842, 2014.
  • A. Fakharuddin, F. De Rossi, T. M. Watson, L. Schmidt-Mende and R. Jose, “Research Update: Behind the high efficiency of hybrid perovskite solar cells”, APL Materials, vol. 4, no. 9, pp. 0–16, 2016.
  • T. A. Berhe, W. N. Su, C. H. Chen, C. J. Pan, J. H. Cheng, H. M. Chen, B. J. Hwang, “Organometal halide perovskite solar cells: degradation and stability”, Energy Environ. Sci., vol. 9, 2016.
  • Z. Song, S. C. Watthage, A. B. Phillips and M. J. Heben, “Pathways toward high-performance perovskite solar cells: review of recent advances in organo-metal halide perovskites for photovoltaic applications”, Journal of Photonics for Energy, vol. 6, no.2, pp. 22001, 2016.
  • Yang Bai, Xiangyue Meng and Shihe Yang “Interface Engineering for Highly Efficient and Stable Planar p-i-n Perovskite Solar Cells”, Adv. Energy Mater., vol. 8, pp. 1701883, 2018.
  • L. Calió, S. Kazim, M. Grätzel and S. Ahmad, “Hole-Transport Materials for Perovskite Solar Cells”, Angew. Chemie - Int. Ed., vol. 55, pp. 14522–14545, 2016.
  • S. Pitchaiya, M. Natarajan, A. Santhanam, V. Asokan, A. Yuvapragasam, V. Madurai Ramakrishnan and et al., “A review on the classification of organic/inorganic/carbonaceous hole transporting materials for perovskite solar cell application”, Arab. J. Chem., vol. 13, pp. 2526–2557, 2020.
  • P. K. Kung, M.H. Li, P. Y. Lin, Y. H. Chiang, C. R. Chan, T. F. Guo and P. Chen., “A Review of Inorganic Hole Transport Materials for Perovskite Solar Cells”, Adv. Mater. Interfaces., vol. 5, pp. 1800882 (1–35), 2018.
  • Z. Shariatinia, “Recent progress in development of diverse kinds of hole transport materials for the perovskite solar cells: A review”, Renew. Sustain. Energy Rev., vol. 119, pp. 109608, 2020.
  • M. Liu, B. Su, Y. Tang, X. Jiang and A. Yu, “Recent Advances in Nanostructured Vanadium Oxides and Composites for Energy Conversion”, Adv. Energy Mater., vol. 7, pp. 1700885, 2017.
  • A. Mauger and C. M. Julien, “V2O5 thin films for energy storage and conversion”, AIMS Materials Science, vol. 5, no. 3, pp. 349–401, 2018.
  • I. Hancox, L. A. Rochford, D. Clare, M. Walker, J. J. Mudd, P. Sullivan, S. Schumann, C. F. McConville and T. S. Jones, “Optimization of a High Work Function Solution Processed Vanadium Oxide Hole-Extracting Layer for Small Molecule and Polymer Organic Photovoltaic Cells”, J. Phys. Chem. C., vol. 117, pp. 49−57, 2013.
  • H. Peng, W. Sun, Y. Li, S. Ye, H. Rao, W. Yan and et al., “Solution processed inorganic V2Ox as interfacial function materials for inverted planar-heterojunction perovskite solar cells with enhanced efficiency”, Nano Res., vol. 9, pp. 2960–2971, 2016.
  • L. Zhang, C. Jiang, C. Wu, H. Ju, G. Jiang, W. Liu and et al., “V2O5 as Hole Transporting Material for Efficient All Inorganic Sb2S3 Solar Cells”, ACS Appl. Mater. Interfaces, vol. 10, pp. 27098–27105, 2018.
  • Z. Liu, T. He, H. Wang, X. Song, H. Liu, J. Yang and et al., “Improving the stability of the perovskite solar cells by V2O5 modified transport layer film”, RSC Adv., vol. 7, pp. 18456–18465, 2017.
  • J. Wu, Y. Zhang, P. Xu, W. Guo, L. Shen and S. Ruan, “Role of solution-processed V2O5 in P3HT:PCBM based inverted polymer solar cells”, Synth. Met., vol. 170, pp. 7–10, 2013.
  • Y. L. Chan, S.-Y. Pung and S. Sreekantan, "Synthesis of V2O5 Nanoflakes on PET Fiber as Visible-Light-Driven Photocatalysts for Degradation of RhB Dye", Journal of Catalysts, vol. Article ID 370696, 7, 2014.
  • K. Schneider, “Optical properties and electronic structure of V2O5, V2O3 and VO2”, J Mater Sci: Mater Electron, vol. 31, pp. 10478–10488, 2020.
There are 20 citations in total.

Details

Primary Language Turkish
Subjects Atomic, Molecular and Optical Physics (Other)
Journal Section Research Articles
Authors

Fatih Ongül 0000-0001-5123-1325

Project Number 2020/004
Early Pub Date December 30, 2023
Publication Date December 31, 2023
Submission Date November 13, 2023
Acceptance Date December 4, 2023
Published in Issue Year 2023 Volume: 1 Issue: 2

Cite

IEEE F. Ongül, “Perovskit Tabanlı Güneş Hücresinde Vanadyum Beşoksit İnce Filmin Deşik İletim Tabakası Olarak Performansı”, JSAT, vol. 1, no. 2, pp. 67–75, 2023, doi: 10.5281/zenodo.10445044.

https://jsat.ardahan.edu.tr