NEW SCHIFF BASES DERIVED from 3,4-DIAMINO-1H-1,2,4-TRIAZOLE-5(4H)-THIONE: SYNTHESIS and CHARACTERIZATION

Year 2022, Issue: 048, 25 - 41, 31.03.2022

Bülent Büyükkıdan , Nurgün Büyükkıdan , Aslı Atar

Abstract

A new synthetic approach has been applied to obtain a compound 3,4-diamino-1H-1,2,4-triazole-5(4H)-thione (2) by using 5-amino-1,3,4-thiadiazole-2-sulfonamide (1) and hydrazine hydrate as starting materials. New Schiff bases (3a-d) are obtained by the reaction of the compound 3,4-diamino-1H-1,2,4-triazole-5(4H)-thione (2) and varied aldehydes. The structures of the new compounds were characterized by spectral (IR, 1H and 13C NMR) and elemental analysis.

Keywords

Thione, Schiff base, Sulfonamide, Triazole, Hydrazine hydrate

Supporting Institution

Kütahya Dumlupınar Üniversitesi, Fen-edebiyat Fakültesi

Project Number

2008-1

Thanks

This study was supported by Dumlupınar University (Grant No: 2008-1)

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