Yeni Mono-Lutesyum Iıı Ftalosiyaninlerin Sentezi, Karakterizasyonu ve Spektroskopik Özellikleri

Year 2016, Volume: 6 Issue: 2, 307 - 314, 01.06.2016

Mehmet Pişkin , Zafer Odabaş

Abstract

Bu çalışmada çeşitli teknolojik uygulamalarda kullanılması amacıyla yeni, oldukça çözünür ve agregasyon yapmayan ftalosiyanin halkasına periferal ve non-periferal pozisyonlardan 2,6-dimetoksifenoksi gruplarıyla tetrasübstitüe lutesyum III asetat metalli ftalosiyanin bileşikleri sentezlenmiş ve yapıları elemental analiz, FT-IR, 1H NMR, UV–vis spektroskopisi ve MALDI-TOF Kütle analiz metotları kullanılarak karakterize edilip aydınlatılmıştır. Ayrıca bu bileşiklerin periferal ve non-periferal pozisyonlardan 2,6-dimetoksifenoksi gruplarıyla sübstitüe edilmesiyle spektroskopik özelliklerindeki değişiklikler rapor edilmiştir

Keywords

Lutesyum III asetat, Mono-lutesyum ftalosiyanin, Agregasyon yapmayan, Non-periferal, Periferal, Çözünür

Synthesis, characterization and spectroscopic properties of novel mono-lutetium III phthalocyanines

Abstract

In this study, the novel, highly soluble and non-aggregated peripherally /non-peripherally tetrakis-2,6-dimethoxyphenoxy substituted lutetium III acetate mono-phthalocyanine complexes have been synthesized for use in different technological applications in this study. The new phthalocyanine complexes have been characterized by elemental analysis, IR, 1H NMR, UV–vis spectroscopy and MALDI-TOF Mass spectra. The effects of the positions peripheral or non-peripheral of the substituents on the spectroscopic properties of 2,6-dimethoxyphenoxy substituted mono-lutetium III phthalocyanines have been also reported.

Keywords

Mono-phthalocyanine, lutetium III acetate, soluble, non-aggregated, peripheral, non-peripheral.

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