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Yüksek Performanslı Sıvı Kromatografi ile Musluk Suyu ve Şişelenmiş Su Örneklerinde Zirkonyum ve Florürün Eser Miktarlarının Belirlenmesi

Year 2016, Volume: 6 Issue: 2, 321 - 328, 01.06.2016

Hale Seçilmiş Canbay Güleren Alsancak

Abstract

Eser miktarlardaki zirkonyum ve florürün belirlenmesi için, çeşitli matrisler musluk ve şişelenmiş su yüksek performanslı tersfaz sıvı kromatografi ile incelendi. Yüksek performanslı sıvı kromatografisi, zirkonyum ve fluorürün, 2- 5-brom-2-piridilazo -5diethylaminophenol 5-Br-PADAP ile oluşturduğu kompleks üzerinden belirlenmesi için kullanıldı. Katı faz ekstraksiyonu SPE , yüksek performanslı sıvı kromatografisi ile birlikte analiz için kullanıldı. Optimum koşullar altında, Zr IV ve florür için dedeksiyon limitleri sırasıyla 0.4 µg/L ve 0.015 µg/L olarak bulundu. Geri kazanım, Zr IV için % 99.74-104.33 ve florür için % 93.33-106.67 elde edildi. İçme suları, Isparta ve Burdur’un farklı noktalarından toplandı. Şişe suları farklı marketlerden temin edildi. Metodun, duyarlılık, yöntem kesinliği ve doğruluğu parametreleri diğer metodlarla karşılaştırıldığında yeterlidir

Keywords

Fluorür HPLC PADAP Zr

References

  • Abbaspour, A., Baramakeh, L. 2002. Simultaneous determination of zirconium and molybdenum by first-derivative spectrophotometry. Anal Sci., 18:1127–1130.
  • Afzali, D., Fathirad, F., Ghaseminezhad, S., Afzali, Z. 2014. Determination of trace amounts of zirconium in real samples after microwave digestion and ternary complex dispersive liquid–liquid microextraction. Environ Monit Assess., 186:3523–3529.
  • Alimarin, IP., Fadeeva, VI., Kudryavtsev, GV., Lokutova, IM., Tikhomirova, TI. 1987. Concentration, separation and determination of scandium, zirconium, hafnium and thorium with a silica-based sulphonic acid cation-exchanger. Talanta., 34:103–110.
  • Amin, AS. 2015. Novel approach for the determination of zirconium by solid-phase spectrophotometry. JTUSCI., 9: 227–236.
  • ASTM:D1179 B. 2010. Standard Test Methods for Fluoride Ion in Water. ASTM International, West Conshohocken, PA.
  • ASTM D4327 – 97. 1991. Standard Test Method for Anions in Water by Chemically Suppressed Ion Chromatography. ASTM International, West Conshohocken, PA.
  • Savik, E., Demer, S., Memis, U., Kumbul Doguc, D., Calıskan, T.A., Tugrul Sezer, M., Gültekin, F., Özgür, N. 2012. Isparta ve civarında tüketilen suların içerik ve sağlık açısından değerlendirilmesi. SDÜ Tip Fak Derg., 19(3):92-102.
  • Secilmiş, H., Karipcin, F., Alsancak, G. 2004. The Investigation of RP-LC of Zr(IV)(5-Br-PADAP) and Hf(IV) (5-Br- PADAP) complexes in methanol water binary mixtures. 4th Aegean Analytical Chemistry Days, pp. 95, Aydın, Turkey.
  • Shariati, S.. Yamini, Y., Zanjani M.K. 2008. Simultaneous preconcentra-tion and determination of U(VI), Th(IV), Zr[IV] and Hf(IV) ions in aqueou ssamples using micelle- mediated extraction coupled to inductively coupled plasma- optical emission spectrometry. J Hazard Mater., 156: 583–590.
  • Shariati, S.., Yamini, Y. 2006. Cloud point extraction and simultaneous determination of zirconium and hafnium using ICP-OES. J Colloid Interface Sci., 298:419–425.
  • Shervedani, R.K., Bagherzadeh, M. 2009. Electro chemical impedance spectroscopy as a trans duction method for electro chemical recognition of zirconium on gold electrode modified with hydroxamated self-assembled monolayer. Sens Actuators B., 139:657–664.
  • Sreedevi, P.D., Ahmed, S., Made, B., Ledoux, E., Gandolfi, J.M. 2006. Association of hydrogeological factors in the temporal variations of fluoride concentration in a crystalline aquifer India. Environ Geol., 50(1):1–11.
  • Standard Method 4110. 1992. Standard Methods for the Examination of Water and Wastewater. American Public Health Association, Washington, D.C.
  • Standard Methods 4500 FC. 1997. Ion-Selective Electrode Method. American Public Health Association, Washington, D.C.
  • Standard Methods 4500 FD. 1997. Test Method D. SPADNS Method. American Public Health Association, Washington, D.C.
  • Tohyama, E. 1996. Relationship between flüoride concentration in drinking water and mortality rate from uterine cancer in Okinawa prefecture, Japan. J Epidemiol., 6(4):184–191.
  • Tokalioglu, S., Sahin, U., Kartal, S. 2001. Determination of Fluoride and Some Metal Ion Levels in the Drinking Waters in Kayseri Province. Turk J Chem., 25:113-121.
  • Tsai, S.J.J., Yan, H.T. 1993. Determination of zirconium and molybdenum with 4,5-dihydroxybenze-1,3-disulfonic acid disodium salt by ion-pair reversed phase high-performance liquid chromatography. Analyst, 118:521–527.
  • USEPA, 1971. Fluoride, Total (Colorimetric, SPADNS with Bellack Distillation), Method 340.1. National Exposure Research Laboratory Office of Research and Development, Cincinnati OH. EPA.
  • Vivit, D.V., King, B.S.W. 2007. The determination of majör oxide and trace element concentrations in eighteen Chinese standard ref-erence samples by X-ray fluorescence spectrometry. Geostand Geoanal Res., 12:363–370.
  • Wang, Z.P., Qian, Y.H., Chen, G.S., Cheng, K.L. 1998. Studies on simultaneous fluorescence-spectrophotometric determination of ultra trace niobium(V), tantalum(V), and zirconium(IV) using par-tialleast-squares algorithm. Microchim J., 60:271–281.
  • Wejnerowska, G., Karczmarek A., Gaca, J. 2007. Determination of fluoride in toothpaste using headspace solid-phase microextraction and gas chromatography-flame ionization detection. J Chrom A., 1-2:173-177.
  • World Health Organization 1995. Guide line for drinking water quality. World Health Organization (WHO),CEHA, Amman, Vol. 1.
  • Yong, C. 2013. Determination of Zirconium, Niobium, Vanadium and Chromium in the Titanium Ore by Microwave Digestion – ICP-OES. Adv Mat Res., 641-642:346-350.
  • Zeiger, E., Shelby, M.D., Witt, K.L. 1993. Genetic toxicity of fluoride. Environ Mol Mutagen., 21(4):309–318.
  • Zaporozhets, Olga.A., Ye Tsyukalo, L. 2007. Determination of fluoride and oxalate using the indicator reaction of Zr(IV) with methyl thymol blue adsorbed on silica gel. Anal Chim Acta., 597:171–177.
  • Development, Cincinnati OH. EPA.

Determination of Trace Amounts of Zirconium and Fluoride in Tap Water and BottledWater Samples Using High Performance Liquid Chromatography

Year 2016, Volume: 6 Issue: 2, 321 - 328, 01.06.2016

Hale Seçilmiş Canbay Güleren Alsancak

Abstract

The determination of trace amountsof zirconium and fluoride in various matrixes tap and bottled water were investigated by high performance reversed phase liquid chromatography. High performance liquid chromatography HPLC was used for determinationof zirconium and fluoride based on their formed complex with 2- 5-bromo-2-pyridylazo -5-diethylaminophenol 5-Br-PADAP . Solid-phase extraction SPE along with high performance liquid chromatographywas used for the analysis. Under optimum conditions, the detection limits for Zr IV and flouride were 0.4 ug/L, and 0.015 ug/L, respectively. Recoveries, 99.74–104.33% for Zr IV and 93.33-106.67% for fluoride were obtained. The sensitivity; precision and accuracy of the method are all satisfactory.

Keywords

HPLC PADAP Zr Fluoride

References

  • Abbaspour, A., Baramakeh, L. 2002. Simultaneous determination of zirconium and molybdenum by first-derivative spectrophotometry. Anal Sci., 18:1127–1130.
  • Afzali, D., Fathirad, F., Ghaseminezhad, S., Afzali, Z. 2014. Determination of trace amounts of zirconium in real samples after microwave digestion and ternary complex dispersive liquid–liquid microextraction. Environ Monit Assess., 186:3523–3529.
  • Alimarin, IP., Fadeeva, VI., Kudryavtsev, GV., Lokutova, IM., Tikhomirova, TI. 1987. Concentration, separation and determination of scandium, zirconium, hafnium and thorium with a silica-based sulphonic acid cation-exchanger. Talanta., 34:103–110.
  • Amin, AS. 2015. Novel approach for the determination of zirconium by solid-phase spectrophotometry. JTUSCI., 9: 227–236.
  • ASTM:D1179 B. 2010. Standard Test Methods for Fluoride Ion in Water. ASTM International, West Conshohocken, PA.
  • ASTM D4327 – 97. 1991. Standard Test Method for Anions in Water by Chemically Suppressed Ion Chromatography. ASTM International, West Conshohocken, PA.
  • Savik, E., Demer, S., Memis, U., Kumbul Doguc, D., Calıskan, T.A., Tugrul Sezer, M., Gültekin, F., Özgür, N. 2012. Isparta ve civarında tüketilen suların içerik ve sağlık açısından değerlendirilmesi. SDÜ Tip Fak Derg., 19(3):92-102.
  • Secilmiş, H., Karipcin, F., Alsancak, G. 2004. The Investigation of RP-LC of Zr(IV)(5-Br-PADAP) and Hf(IV) (5-Br- PADAP) complexes in methanol water binary mixtures. 4th Aegean Analytical Chemistry Days, pp. 95, Aydın, Turkey.
  • Shariati, S.. Yamini, Y., Zanjani M.K. 2008. Simultaneous preconcentra-tion and determination of U(VI), Th(IV), Zr[IV] and Hf(IV) ions in aqueou ssamples using micelle- mediated extraction coupled to inductively coupled plasma- optical emission spectrometry. J Hazard Mater., 156: 583–590.
  • Shariati, S.., Yamini, Y. 2006. Cloud point extraction and simultaneous determination of zirconium and hafnium using ICP-OES. J Colloid Interface Sci., 298:419–425.
  • Shervedani, R.K., Bagherzadeh, M. 2009. Electro chemical impedance spectroscopy as a trans duction method for electro chemical recognition of zirconium on gold electrode modified with hydroxamated self-assembled monolayer. Sens Actuators B., 139:657–664.
  • Sreedevi, P.D., Ahmed, S., Made, B., Ledoux, E., Gandolfi, J.M. 2006. Association of hydrogeological factors in the temporal variations of fluoride concentration in a crystalline aquifer India. Environ Geol., 50(1):1–11.
  • Standard Method 4110. 1992. Standard Methods for the Examination of Water and Wastewater. American Public Health Association, Washington, D.C.
  • Standard Methods 4500 FC. 1997. Ion-Selective Electrode Method. American Public Health Association, Washington, D.C.
  • Standard Methods 4500 FD. 1997. Test Method D. SPADNS Method. American Public Health Association, Washington, D.C.
  • Tohyama, E. 1996. Relationship between flüoride concentration in drinking water and mortality rate from uterine cancer in Okinawa prefecture, Japan. J Epidemiol., 6(4):184–191.
  • Tokalioglu, S., Sahin, U., Kartal, S. 2001. Determination of Fluoride and Some Metal Ion Levels in the Drinking Waters in Kayseri Province. Turk J Chem., 25:113-121.
  • Tsai, S.J.J., Yan, H.T. 1993. Determination of zirconium and molybdenum with 4,5-dihydroxybenze-1,3-disulfonic acid disodium salt by ion-pair reversed phase high-performance liquid chromatography. Analyst, 118:521–527.
  • USEPA, 1971. Fluoride, Total (Colorimetric, SPADNS with Bellack Distillation), Method 340.1. National Exposure Research Laboratory Office of Research and Development, Cincinnati OH. EPA.
  • Vivit, D.V., King, B.S.W. 2007. The determination of majör oxide and trace element concentrations in eighteen Chinese standard ref-erence samples by X-ray fluorescence spectrometry. Geostand Geoanal Res., 12:363–370.
  • Wang, Z.P., Qian, Y.H., Chen, G.S., Cheng, K.L. 1998. Studies on simultaneous fluorescence-spectrophotometric determination of ultra trace niobium(V), tantalum(V), and zirconium(IV) using par-tialleast-squares algorithm. Microchim J., 60:271–281.
  • Wejnerowska, G., Karczmarek A., Gaca, J. 2007. Determination of fluoride in toothpaste using headspace solid-phase microextraction and gas chromatography-flame ionization detection. J Chrom A., 1-2:173-177.
  • World Health Organization 1995. Guide line for drinking water quality. World Health Organization (WHO),CEHA, Amman, Vol. 1.
  • Yong, C. 2013. Determination of Zirconium, Niobium, Vanadium and Chromium in the Titanium Ore by Microwave Digestion – ICP-OES. Adv Mat Res., 641-642:346-350.
  • Zeiger, E., Shelby, M.D., Witt, K.L. 1993. Genetic toxicity of fluoride. Environ Mol Mutagen., 21(4):309–318.
  • Zaporozhets, Olga.A., Ye Tsyukalo, L. 2007. Determination of fluoride and oxalate using the indicator reaction of Zr(IV) with methyl thymol blue adsorbed on silica gel. Anal Chim Acta., 597:171–177.
  • Development, Cincinnati OH. EPA.
There are 27 citations in total.

Details

Primary Language Turkish
Journal Section Research Article
Authors

Hale Seçilmiş Canbay This is me

Güleren Alsancak This is me

Publication Date June 1, 2016
Published in Issue Year 2016 Volume: 6 Issue: 2

Cite

APA Canbay, H. S., & Alsancak, G. (2016). Yüksek Performanslı Sıvı Kromatografi ile Musluk Suyu ve Şişelenmiş Su Örneklerinde Zirkonyum ve Florürün Eser Miktarlarının Belirlenmesi. Karaelmas Fen Ve Mühendislik Dergisi, 6(2), 321-328.
AMA Canbay HS, Alsancak G. Yüksek Performanslı Sıvı Kromatografi ile Musluk Suyu ve Şişelenmiş Su Örneklerinde Zirkonyum ve Florürün Eser Miktarlarının Belirlenmesi. Karaelmas Fen ve Mühendislik Dergisi. June 2016;6(2):321-328.
Chicago Canbay, Hale Seçilmiş, and Güleren Alsancak. “Yüksek Performanslı Sıvı Kromatografi Ile Musluk Suyu Ve Şişelenmiş Su Örneklerinde Zirkonyum Ve Florürün Eser Miktarlarının Belirlenmesi”. Karaelmas Fen Ve Mühendislik Dergisi 6, no. 2 (June 2016): 321-28.
EndNote Canbay HS, Alsancak G (June 1, 2016) Yüksek Performanslı Sıvı Kromatografi ile Musluk Suyu ve Şişelenmiş Su Örneklerinde Zirkonyum ve Florürün Eser Miktarlarının Belirlenmesi. Karaelmas Fen ve Mühendislik Dergisi 6 2 321–328.
IEEE H. S. Canbay and G. Alsancak, “Yüksek Performanslı Sıvı Kromatografi ile Musluk Suyu ve Şişelenmiş Su Örneklerinde Zirkonyum ve Florürün Eser Miktarlarının Belirlenmesi”, Karaelmas Fen ve Mühendislik Dergisi, vol. 6, no. 2, pp. 321–328, 2016.
ISNAD Canbay, Hale Seçilmiş - Alsancak, Güleren. “Yüksek Performanslı Sıvı Kromatografi Ile Musluk Suyu Ve Şişelenmiş Su Örneklerinde Zirkonyum Ve Florürün Eser Miktarlarının Belirlenmesi”. Karaelmas Fen ve Mühendislik Dergisi 6/2 (June 2016), 321-328.
JAMA Canbay HS, Alsancak G. Yüksek Performanslı Sıvı Kromatografi ile Musluk Suyu ve Şişelenmiş Su Örneklerinde Zirkonyum ve Florürün Eser Miktarlarının Belirlenmesi. Karaelmas Fen ve Mühendislik Dergisi. 2016;6:321–328.
MLA Canbay, Hale Seçilmiş and Güleren Alsancak. “Yüksek Performanslı Sıvı Kromatografi Ile Musluk Suyu Ve Şişelenmiş Su Örneklerinde Zirkonyum Ve Florürün Eser Miktarlarının Belirlenmesi”. Karaelmas Fen Ve Mühendislik Dergisi, vol. 6, no. 2, 2016, pp. 321-8.
Vancouver Canbay HS, Alsancak G. Yüksek Performanslı Sıvı Kromatografi ile Musluk Suyu ve Şişelenmiş Su Örneklerinde Zirkonyum ve Florürün Eser Miktarlarının Belirlenmesi. Karaelmas Fen ve Mühendislik Dergisi. 2016;6(2):321-8.