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Şeker Kısımları ile Graftlanmış olan Polimetilsiloksan Bazlı Polimerik Yüzey Aktif Madde Sentezi

Year 2016, Volume: 6 Issue: 2, 345 - 350, 01.06.2016

Fatma Çetin Telli

Abstract

İlk olarak, platin katalizörü varlığında hidrosililasyon reaksiyonuna girebilen enofuranoz türevi 1 hazırlandı. Sentezlenen enofuranoz türevinin allil grubunun çifte bağından silikon oligomerine bağlanması gerçekleştirildi. Polimerik yüzey aktif madde 2 şeker kısımları ile graftlanmış olan bir polimetilsilikon bazlı malzeme kullanılarak hazırlandı. Sentezlenen 1 ve 2 nolu bileşiklerin yapıları, Nükleer Manyetik Rezonans NMR ve FITR spektroskopisi ile aydınlatıldı

Keywords

Yüzey Aktif Madde Biyolojik Yüzey Aktif Maddeler Polimetilsiloksan Şeker Bazlı Yüzey Aktif Maddeler

References

  • Abert, M., Mora, N., Lacombe, J.M. 2002. Synthesis and surface-active properties of a new class of surfactants derived from D-gluconic acid. Carbohyd Res, 337: 997-1006.
  • Andersson, KN., Sauer, S., Panknin, O., Söderlind, E., Somfai, P.2006. Sythesis of New Sugar-Based Surfactants and Evaluation of Their Hemolytic Activities. J. Org. Chem., 71: 3623-3626.
  • Bauer, J., Hüsing, N., Kickelbick, G. 2001.Synthesis of new types of polysiloxane basedsurfactants, Chem Commun. 1:137-138.
  • Bazito, RC., El Seoud, OA.2001. Sugar-based anionic surfactants: sythesis and miccelle formation of sodium methyl 2-acylamido-2-deoxy-6-O-sulfo-D-glucopyranosides, Carbohyd Res, 332: 95-102.
  • Boehm, P., Mondeshki, M., Frey, H. 2012. Polysiloxane- Backbone Block Copolymers in a One-Pot Synthesis: A Silicone Platform for Facile Functionalization. Macromol Rapid Comm, 33: 1861-1867.
  • Han, F., Deng, Y., Zhou, Y., Xu, B. 2012. Carbohydrate- Modified Silicone Surfactants. J Surfact Deterg, 15:123-129.
  • Hill, RM. 1999. Silicone Surfactants, Surfactant Science Series, 86. Marcel Dekker, New York, 2-4 pp.
  • Hill, K., Le Hen-Ferrenbach, C. 2009. Sugar-based surfactants for consumer products and technical applications. Surfactant Sci. Ser.,143: 1–20.
  • Lewis, LN., Stein, J., Gao, Y., Colborn, RE., Hutchins, G. 1991. Platinum Catalysts Used in the Silicones Industry. Platinum Metals Rev, 41: 66-75.
  • attributed to Si–C groups and Si–O–Si groups, respectively. It was also seen that allyl (C=C) peak at 1647 cm-1 was lost (Zeng et al. 2015).
  • Retailleau, L., Laplace, A., Fensterbank, H., Larpent, C. 1998. Synthesis, Structural Analysis and properties of N-Alkylglucosyl(meth)acrylamides: New Reactive Augar Surfactants. J.Org.Chem., 63: 608-617.
  • Sejpka, J., Wimner, F. 1994.Proses for Peraparing Organosilicon Compounds Containing Glycoside Radicals. European Patent, 0612759 to Wacker Chemie GmbH, Germany, 1-10 pp.
  • Shing, TKM., Leung, GYC. 2002. Asymetric epoxidation catalyzed by D-glucose-derived uloses. Tetrahedron, 58: 7545- 7552.
  • Tadros, TF. 2005. Aplied Surfactants: Principles and Aplication,WILEY-VCH Verlag GmbH & Co. KGaA, Weinhe- im, 1-16 pp.
  • Telli, FÇ.2015.Syntheses and Characterization of New 3-O-Allyl Ether Chloralose Derivatives. Asian J. Chem., 27: 353-356.
  • Zeng, X., Wang, H., Chen, Y., Wang, L. 2015. Synthesis and Solution Properties of Carbohydrate-Modified Polysiloxane Bola Surfactants. J Surfact Deterg, 18: 1089–1094.
  • Reinsborough, VC., Stephenson, VC. 2004. Inclusion comple- xation involving sugar-containing species: β-cyclodextrin and sugar surfactants. Can J. Chem., 82: 45-49.

Sythesis of Polymeric Surfactant with Polymethylsilicone Backbone which is Grafted with A Sugar

Year 2016, Volume: 6 Issue: 2, 345 - 350, 01.06.2016

Fatma Çetin Telli

Abstract

The enofuranose derivative 1 was synthesised which was thought to be suitable for reaction with polymethylhydrogensiloxane, by hydrosilylation reaction in the presence of a platinum catalyst. Allyl group was introduced to the protected sugar derivative, which were further used for bonding these molecule to silicone oligomer through double bond addition. The polymeric surfactant 2 has been prepared using a polymethylsilicon backbone which was grafted with a glucose moiety. The synthesized compounds 1 and 2 were characterized by nuclear magnetic resonance NMR and Fourier transforminfrared spectroscopy FTIR .

Keywords

Surfactants Biosurfactants Polymethylsilicon Sugar based surface active agents

References

  • Abert, M., Mora, N., Lacombe, J.M. 2002. Synthesis and surface-active properties of a new class of surfactants derived from D-gluconic acid. Carbohyd Res, 337: 997-1006.
  • Andersson, KN., Sauer, S., Panknin, O., Söderlind, E., Somfai, P.2006. Sythesis of New Sugar-Based Surfactants and Evaluation of Their Hemolytic Activities. J. Org. Chem., 71: 3623-3626.
  • Bauer, J., Hüsing, N., Kickelbick, G. 2001.Synthesis of new types of polysiloxane basedsurfactants, Chem Commun. 1:137-138.
  • Bazito, RC., El Seoud, OA.2001. Sugar-based anionic surfactants: sythesis and miccelle formation of sodium methyl 2-acylamido-2-deoxy-6-O-sulfo-D-glucopyranosides, Carbohyd Res, 332: 95-102.
  • Boehm, P., Mondeshki, M., Frey, H. 2012. Polysiloxane- Backbone Block Copolymers in a One-Pot Synthesis: A Silicone Platform for Facile Functionalization. Macromol Rapid Comm, 33: 1861-1867.
  • Han, F., Deng, Y., Zhou, Y., Xu, B. 2012. Carbohydrate- Modified Silicone Surfactants. J Surfact Deterg, 15:123-129.
  • Hill, RM. 1999. Silicone Surfactants, Surfactant Science Series, 86. Marcel Dekker, New York, 2-4 pp.
  • Hill, K., Le Hen-Ferrenbach, C. 2009. Sugar-based surfactants for consumer products and technical applications. Surfactant Sci. Ser.,143: 1–20.
  • Lewis, LN., Stein, J., Gao, Y., Colborn, RE., Hutchins, G. 1991. Platinum Catalysts Used in the Silicones Industry. Platinum Metals Rev, 41: 66-75.
  • attributed to Si–C groups and Si–O–Si groups, respectively. It was also seen that allyl (C=C) peak at 1647 cm-1 was lost (Zeng et al. 2015).
  • Retailleau, L., Laplace, A., Fensterbank, H., Larpent, C. 1998. Synthesis, Structural Analysis and properties of N-Alkylglucosyl(meth)acrylamides: New Reactive Augar Surfactants. J.Org.Chem., 63: 608-617.
  • Sejpka, J., Wimner, F. 1994.Proses for Peraparing Organosilicon Compounds Containing Glycoside Radicals. European Patent, 0612759 to Wacker Chemie GmbH, Germany, 1-10 pp.
  • Shing, TKM., Leung, GYC. 2002. Asymetric epoxidation catalyzed by D-glucose-derived uloses. Tetrahedron, 58: 7545- 7552.
  • Tadros, TF. 2005. Aplied Surfactants: Principles and Aplication,WILEY-VCH Verlag GmbH & Co. KGaA, Weinhe- im, 1-16 pp.
  • Telli, FÇ.2015.Syntheses and Characterization of New 3-O-Allyl Ether Chloralose Derivatives. Asian J. Chem., 27: 353-356.
  • Zeng, X., Wang, H., Chen, Y., Wang, L. 2015. Synthesis and Solution Properties of Carbohydrate-Modified Polysiloxane Bola Surfactants. J Surfact Deterg, 18: 1089–1094.
  • Reinsborough, VC., Stephenson, VC. 2004. Inclusion comple- xation involving sugar-containing species: β-cyclodextrin and sugar surfactants. Can J. Chem., 82: 45-49.
There are 17 citations in total.

Details

Primary Language English
Journal Section Research Article
Authors

Fatma Çetin Telli This is me

Publication Date June 1, 2016
Published in Issue Year 2016 Volume: 6 Issue: 2

Cite

APA Çetin Telli, F. (2016). Sythesis of Polymeric Surfactant with Polymethylsilicone Backbone which is Grafted with A Sugar. Karaelmas Fen Ve Mühendislik Dergisi, 6(2), 345-350.
AMA Çetin Telli F. Sythesis of Polymeric Surfactant with Polymethylsilicone Backbone which is Grafted with A Sugar. Karaelmas Fen ve Mühendislik Dergisi. June 2016;6(2):345-350.
Chicago Çetin Telli, Fatma. “Sythesis of Polymeric Surfactant With Polymethylsilicone Backbone Which Is Grafted With A Sugar”. Karaelmas Fen Ve Mühendislik Dergisi 6, no. 2 (June 2016): 345-50.
EndNote Çetin Telli F (June 1, 2016) Sythesis of Polymeric Surfactant with Polymethylsilicone Backbone which is Grafted with A Sugar. Karaelmas Fen ve Mühendislik Dergisi 6 2 345–350.
IEEE F. Çetin Telli, “Sythesis of Polymeric Surfactant with Polymethylsilicone Backbone which is Grafted with A Sugar”, Karaelmas Fen ve Mühendislik Dergisi, vol. 6, no. 2, pp. 345–350, 2016.
ISNAD Çetin Telli, Fatma. “Sythesis of Polymeric Surfactant With Polymethylsilicone Backbone Which Is Grafted With A Sugar”. Karaelmas Fen ve Mühendislik Dergisi 6/2 (June 2016), 345-350.
JAMA Çetin Telli F. Sythesis of Polymeric Surfactant with Polymethylsilicone Backbone which is Grafted with A Sugar. Karaelmas Fen ve Mühendislik Dergisi. 2016;6:345–350.
MLA Çetin Telli, Fatma. “Sythesis of Polymeric Surfactant With Polymethylsilicone Backbone Which Is Grafted With A Sugar”. Karaelmas Fen Ve Mühendislik Dergisi, vol. 6, no. 2, 2016, pp. 345-50.
Vancouver Çetin Telli F. Sythesis of Polymeric Surfactant with Polymethylsilicone Backbone which is Grafted with A Sugar. Karaelmas Fen ve Mühendislik Dergisi. 2016;6(2):345-50.