İkincil Enaminon Bileşiklerinin Suda Sentezi ve Karakterizasyonu

Year 2022, Volume: 12 Issue: 2, 216 - 222, 24.12.2022

Füsun Şeyma Güngör

Abstract

Enaminon bileşikleri, sentetik organik kimyada çok geniş bir yelpazede uygulama alanına sahiptir. Özellikle son yıllarda , enaminona içeren organik sentezler ve onların katalitik uygulamalara yönelik araştırmalar çokça yapılmıştır. Bu çalışmada da üçüncül enaminoketon ve enaminoester bileşikleri ile aromatik aminlerin FeCl3.6H2O katalizörlüğünde su içinde gerçekleştirilen tepkimelerinden yüksek
verimle ve kısa sürede ikincil enaminon bileşikleri sentezlenmiştir. Yöntemde tepkimeler su içinde gerçekleştirilmiş olup bir organik çözücüye ihtiyaç duyulmamıştır. Tepkimenin su içinde gerçekleştirilmesi tepkime veriminin artmasına neden olmuştur

Keywords

Enaminon, Katalizör, Kondenzasyon, Su, Yeşil sentez

Supporting Institution

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Project Number

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Synthesis and Characterization of Secondary Enaminone Compounds in Water

Abstract

Enaminon compounds have a wide range of applications in synthetic organic chemistry. Especially in recent years, many studies have been conducted on organic syntheses containing enaminone and their catalytic applications. In this study, secondary enaminone compounds were synthesized with high yield and in a short time from the reactions of tertiary enaminoketone and enaminoester compounds and aromatic amines in water with FeCl3.6H2O as a catalyst. In the method, the reactions were carried out in the water and an organic solvent was not needed. Performing the reaction in water resulted in increased reaction yield.

Keywords

enaminone, condensation, green synthesis, water, Enaminon, Kondenzasyon

Project Number

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