Chemical modification of spruce wood with combination of mesyl chloride and poly(ε-caprolactone) for improvement of dimensional stability and water absorption properties

Mahmut Ali Ermeydan

doi:10.17475/kastorman.289764

EN

Chemical modification of spruce wood with combination of mesyl chloride and poly(ε-caprolactone) for improvement of dimensional stability and water absorption properties

Abstract

Sustainability is an important issue for materials production which can be provided by using renewable resources such as wood. Wood is a natural material with excellent mechanical properties. However, humidity changes negatively affect wood’s dimensional stability. Water repellence and dimensional stability can be both improved by inserting hydrophobic molecules inside wood cell walls. In this study, a two-step modification were carried out by grafting a biodegradable polymer poly(ε-caprolactone) (PCL) onto the pre-treated wood cell walls by mesyl chloride. Confocal Raman imaging and spectroscopy were used to show the distribution of mesyl groups and poly(ε-caprolactone) within cell walls. The morphology of modified wood cell walls was monitored by scanning electron microscopy. Physical tests showed that the poly(ε-caprolactone) grafted wood has significantly better dimensional stability and water repellence compared to references.

References

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Details

Primary Language

English

Subjects

-

Journal Section

-

Authors

Mahmut Ali Ermeydan

Publication Date

December 2, 2016

Submission Date

September 3, 2016

Acceptance Date

-

Published in Issue

Year 2016 Volume: 16 Number: 2

DOI

https://doi.org/10.17475/kastorman.289764

IZ

https://izlik.org/JA39UM55HU

APA

Ermeydan, M. A. (2016). Chemical modification of spruce wood with combination of mesyl chloride and poly(ε-caprolactone) for improvement of dimensional stability and water absorption properties. Kastamonu University Journal of Forestry Faculty, 16(2). https://doi.org/10.17475/kastorman.289764

AMA

1.Ermeydan MA. Chemical modification of spruce wood with combination of mesyl chloride and poly(ε-caprolactone) for improvement of dimensional stability and water absorption properties. Kastamonu University Journal of Forestry Faculty. 2016;16(2). doi:10.17475/kastorman.289764

Chicago

Ermeydan, Mahmut Ali. 2016. “Chemical Modification of Spruce Wood With Combination of Mesyl Chloride and Poly(ε-Caprolactone) for Improvement of Dimensional Stability and Water Absorption Properties”. Kastamonu University Journal of Forestry Faculty 16 (2). https://doi.org/10.17475/kastorman.289764.

EndNote

Ermeydan MA (December 1, 2016) Chemical modification of spruce wood with combination of mesyl chloride and poly(ε-caprolactone) for improvement of dimensional stability and water absorption properties. Kastamonu University Journal of Forestry Faculty 16 2

IEEE

[1]M. A. Ermeydan, “Chemical modification of spruce wood with combination of mesyl chloride and poly(ε-caprolactone) for improvement of dimensional stability and water absorption properties”, Kastamonu University Journal of Forestry Faculty, vol. 16, no. 2, Dec. 2016, doi: 10.17475/kastorman.289764.

ISNAD

Ermeydan, Mahmut Ali. “Chemical Modification of Spruce Wood With Combination of Mesyl Chloride and Poly(ε-Caprolactone) for Improvement of Dimensional Stability and Water Absorption Properties”. Kastamonu University Journal of Forestry Faculty 16/2 (December 1, 2016). https://doi.org/10.17475/kastorman.289764.

JAMA

1.Ermeydan MA. Chemical modification of spruce wood with combination of mesyl chloride and poly(ε-caprolactone) for improvement of dimensional stability and water absorption properties. Kastamonu University Journal of Forestry Faculty. 2016;16. doi:10.17475/kastorman.289764.

MLA

Ermeydan, Mahmut Ali. “Chemical Modification of Spruce Wood With Combination of Mesyl Chloride and Poly(ε-Caprolactone) for Improvement of Dimensional Stability and Water Absorption Properties”. Kastamonu University Journal of Forestry Faculty, vol. 16, no. 2, Dec. 2016, doi:10.17475/kastorman.289764.

Vancouver

1.Mahmut Ali Ermeydan. Chemical modification of spruce wood with combination of mesyl chloride and poly(ε-caprolactone) for improvement of dimensional stability and water absorption properties. Kastamonu University Journal of Forestry Faculty. 2016 Dec. 1;16(2). doi:10.17475/kastorman.289764

Cited By

Effect of process variations of polycaprolactone modification on wood durability, dimensional stability and boron leaching

Holzforschung

https://doi.org/10.1515/hf-2018-0231