Year 2018, Volume , Issue 3, Pages 12 - 16 2018-12-31

Synthesis And Characterization Of A New (E, E)-Dioxime And Its Mono Nuclear Nickel (II) Complex Containing Diazatetrathidioxa Macrobicyclic Moieties

Gülsev DİLBER [1] , Halit KANTEKİN [2]


In this study,  a novel (E,E)-dioxim containing a diazatetrathiadioxa macrobicyclic moieties  (19E, 20E)-6,7,14,15,18,21,24,25-oktahydro-13,26-(ethanothioethano-thioethano)dibenzo

[14,15:8,9]-[1,4,10,13,7,16]dioxadithiadiazacyclooctadecino[2,3-g] quinoxaline- 19,20,27,34-tetrone 19,20-dioxime (H2L) has been synthesized by reacting cyanogen-di-N-oxide with 2,3-diamino-6,7,14,15,22,23-hexahydro-8,21-(ethanothioethanothioethano)tribenzo[b,h,n][1,4,10,

13,7,16]dioxadithiadiazacyclooctadecine-25,32-dione (8), which was prepared by the reduction of 2,3-dinitro-6,7,14,15,22,23-hexahydro-8,21-(ethanothioethanothioethano)-tribenzo[b,h,n] [1,4,10,13,7,16]dioxodithiadiazacyclooctadecine-25,32dione (7). The macrobicyclic (7) was synthesized by the condensation reaction of compound (5) with compound (6) in the presence of the Na2CO3 under an argon atmosphere in the refluxing acetonitrile. Mononuclear complex (11) with metal:ligand ratio 1:2 of this ligand has been synthesized by reacting the vic-dioxime (H2L) with NiCl2.6H2O. The new compounds were characterized by a combination of elemental analysis, 1H- and 13C-NMR, IR and MS spectral data.

vic-Dioximes, transition metal, macrobicyclic compound, mononuclear complex
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Primary Language en
Journal Section Research Article
Authors

Orcid: 0000-0001-7114-4421
Author: Gülsev DİLBER (Primary Author)
Institution: KARADENİZ TEKNİK ÜNİVERSİTESİ, MAÇKA MESLEK YÜKSEKOKULU
Country: Turkey


Author: Halit KANTEKİN
Institution: KARADENİZ TEKNİK ÜNİVERSİTESİ, FEN FAKÜLTESİ, KİMYA BÖLÜMÜ
Country: Turkey


Dates

Publication Date : December 31, 2018

Bibtex @research article { kcst430028, journal = {Karadeniz Chemical Science and Technology}, issn = {}, eissn = {2636-8560}, address = {Karadeniz Chemical Science and Technology (KCST) Journal, Department of Chemistry, Faculty of Science, KTU, 61080, Trabzon, TÜRKİYE}, publisher = {KCST Founding Board}, year = {2018}, volume = {}, pages = {12 - 16}, doi = {}, title = {Synthesis And Characterization Of A New (E, E)-Dioxime And Its Mono Nuclear Nickel (II) Complex Containing Diazatetrathidioxa Macrobicyclic Moieties}, key = {cite}, author = {Dilber, Gülsev and Kantekin, Halit} }
APA Dilber, G , Kantekin, H . (2018). Synthesis And Characterization Of A New (E, E)-Dioxime And Its Mono Nuclear Nickel (II) Complex Containing Diazatetrathidioxa Macrobicyclic Moieties . Karadeniz Chemical Science and Technology , (3) , 12-16 . Retrieved from https://dergipark.org.tr/en/pub/kcst/issue/42072/430028
MLA Dilber, G , Kantekin, H . "Synthesis And Characterization Of A New (E, E)-Dioxime And Its Mono Nuclear Nickel (II) Complex Containing Diazatetrathidioxa Macrobicyclic Moieties" . Karadeniz Chemical Science and Technology (2018 ): 12-16 <https://dergipark.org.tr/en/pub/kcst/issue/42072/430028>
Chicago Dilber, G , Kantekin, H . "Synthesis And Characterization Of A New (E, E)-Dioxime And Its Mono Nuclear Nickel (II) Complex Containing Diazatetrathidioxa Macrobicyclic Moieties". Karadeniz Chemical Science and Technology (2018 ): 12-16
RIS TY - JOUR T1 - Synthesis And Characterization Of A New (E, E)-Dioxime And Its Mono Nuclear Nickel (II) Complex Containing Diazatetrathidioxa Macrobicyclic Moieties AU - Gülsev Dilber , Halit Kantekin Y1 - 2018 PY - 2018 N1 - DO - T2 - Karadeniz Chemical Science and Technology JF - Journal JO - JOR SP - 12 EP - 16 VL - IS - 3 SN - -2636-8560 M3 - UR - Y2 - 2018 ER -
EndNote %0 Karadeniz Chemical Science and Technology Synthesis And Characterization Of A New (E, E)-Dioxime And Its Mono Nuclear Nickel (II) Complex Containing Diazatetrathidioxa Macrobicyclic Moieties %A Gülsev Dilber , Halit Kantekin %T Synthesis And Characterization Of A New (E, E)-Dioxime And Its Mono Nuclear Nickel (II) Complex Containing Diazatetrathidioxa Macrobicyclic Moieties %D 2018 %J Karadeniz Chemical Science and Technology %P -2636-8560 %V %N 3 %R %U
ISNAD Dilber, Gülsev , Kantekin, Halit . "Synthesis And Characterization Of A New (E, E)-Dioxime And Its Mono Nuclear Nickel (II) Complex Containing Diazatetrathidioxa Macrobicyclic Moieties". Karadeniz Chemical Science and Technology / 3 (December 2018): 12-16 .
AMA Dilber G , Kantekin H . Synthesis And Characterization Of A New (E, E)-Dioxime And Its Mono Nuclear Nickel (II) Complex Containing Diazatetrathidioxa Macrobicyclic Moieties. Karadeniz Chem. Sci. Tech.. 2018; (3): 12-16.
Vancouver Dilber G , Kantekin H . Synthesis And Characterization Of A New (E, E)-Dioxime And Its Mono Nuclear Nickel (II) Complex Containing Diazatetrathidioxa Macrobicyclic Moieties. Karadeniz Chemical Science and Technology. 2018; (3): 12-16.
IEEE G. Dilber and H. Kantekin , "Synthesis And Characterization Of A New (E, E)-Dioxime And Its Mono Nuclear Nickel (II) Complex Containing Diazatetrathidioxa Macrobicyclic Moieties", Karadeniz Chemical Science and Technology, no. 3, pp. 12-16, Dec. 2019