Synthesis And Characterization Of A New (E, E)-Dioxime And Its Mono Nuclear Nickel (II) Complex Containing Diazatetrathidioxa Macrobicyclic Moieties

Year 2018, Issue: 3, 12 - 16, 31.12.2018

Gülsev Dilber Halit Kantekin

Abstract

In this study,  a novel
(E,E)-dioxim containing a diazatetrathiadioxa macrobicyclic moieties  (19E,
20E)-6,7,14,15,18,21,24,25-oktahydro-13,26-(ethanothioethano-thioethano)dibenzo

[14,15:8,9]-[1,4,10,13,7,16]dioxadithiadiazacyclooctadecino[2,3-g]
quinoxaline- 19,20,27,34-tetrone 19,20-dioxime (H₂L) has been
synthesized by reacting cyanogen-di-N-oxide with 2,3-diamino-6,7,14,15,22,23-hexahydro-8,21-(ethanothioethanothioethano)tribenzo[b,h,n][1,4,10,

13,7,16]dioxadithiadiazacyclooctadecine-25,32-dione (8), which was prepared by the reduction
of
2,3-dinitro-6,7,14,15,22,23-hexahydro-8,21-(ethanothioethanothioethano)-tribenzo[b,h,n]
[1,4,10,13,7,16]dioxodithiadiazacyclooctadecine-25,32dione (7). The macrobicyclic (7) was synthesized by the condensation
reaction of compound (5) with
compound (6) in the presence of the
Na₂CO₃ under an argon atmosphere in the refluxing
acetonitrile. Mononuclear complex (11) with metal:ligand ratio 1:2 of
this ligand has been synthesized by reacting the vic-dioxime (H₂L)
with NiCl₂.6H₂O. The new compounds were characterized by
a combination of elemental analysis, ¹H- and ¹³C-NMR, IR
and MS spectral data.

Keywords

vic-Dioximes, transition metal, macrobicyclic compound, mononuclear complex

References

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