Year 2018, Volume , Issue 3, Pages 27 - 32 2018-12-31

Synthesis, Molecular Structure, Spectroscopic and Computational Studies of (E)-tert-butyl (2-((3,5-di-tert-butyl-2-hydroxybenzylidene) amino)ethyl)carbamate as Functionalized Schiff Base

Pınar ŞEN [1] , Salih Zeki YILDIZ [2] , Ömer TAMER [3] , Sibel Demir KANMAZALP [4] , Necmi DEGE [5]


This work presents the synthesis and characterization of a novel compound, (E)-tert-butyl (2-((3,5-di-tert-butyl-2-hydroxybenzylidene)amino)ethyl)carbamate as the Schiff base derivative.

This compound  have been selected as a ligand for the preparation of unsymmetrical metal complexes which is a potential candidate as unsymmetrical catalyst. The spectroscopic properties of the compound were examined by FT-IR, 1H NMR, 13C NMR,  MS and elemental analyses. The molecular structure of the compound was also confirmed using X-ray single-crystal data. The molecule is stabilized through intermolecular N—H···O hydrogen bonds, which form chains extending along [100]. And also it has been calculated; molecular structure, vibrational frequencies and 1H and 13C NMR chemical shifts of the title compound by using B3LYP method with 6-311++G(dp) basis set, as well.

Synthesis, Crystal structure, Schiff base, amine, mono-Boc-protection, theoretical calculation
  • Referans1 Doç. Dr. Çiğdem Yüksektepe Ataol :yuksekc85@gmail.com-Çankırı Karatekin üniversitesi
  • Referans2 Dr. Öğretim Üyesi Ayşin Zülfikaroğlu: aysin.zulfikaroglu@amasya.edu.tr: Amasya Üniversitesi
  • Referans2 Dr. Zeynep Demircioğlu: zeynep.kelesoglu@omu.edu.tr: Sinop Üniversitesi
Primary Language en
Subjects Engineering, Chemical
Journal Section Research Article
Authors

Author: Pınar ŞEN (Primary Author)
Institution: ÜSKÜDAR ÜNİVERSİTESİ
Country: Turkey


Author: Salih Zeki YILDIZ
Institution: SAKARYA ÜNİVERSİTESİ
Country: Turkey


Author: Ömer TAMER
Institution: SAKARYA ÜNİVERSİTESİ
Country: Turkey


Author: Sibel Demir KANMAZALP
Institution: GAZİANTEP ÜNİVERSİTESİ
Country: Turkey


Author: Necmi DEGE
Institution: ONDOKUZ MAYIS ÜNİVERSİTESİ
Country: Turkey


Dates

Publication Date : December 31, 2018

Bibtex @research article { kcst439722, journal = {Karadeniz Chemical Science and Technology}, issn = {}, eissn = {2636-8560}, address = {Karadeniz Chemical Science and Technology (KCST) Journal, Department of Chemistry, Faculty of Science, KTU, 61080, Trabzon, TÜRKİYE}, publisher = {KCST Founding Board}, year = {2018}, volume = {}, pages = {27 - 32}, doi = {}, title = {Synthesis, Molecular Structure, Spectroscopic and Computational Studies of (E)-tert-butyl (2-((3,5-di-tert-butyl-2-hydroxybenzylidene) amino)ethyl)carbamate as Functionalized Schiff Base}, key = {cite}, author = {Şen, Pınar and Yıldız, Salih Zeki and Tamer, Ömer and Kanmazalp, Sibel Demir and Dege, Necmi} }
APA Şen, P , Yıldız, S , Tamer, Ö , Kanmazalp, S , Dege, N . (2018). Synthesis, Molecular Structure, Spectroscopic and Computational Studies of (E)-tert-butyl (2-((3,5-di-tert-butyl-2-hydroxybenzylidene) amino)ethyl)carbamate as Functionalized Schiff Base . Karadeniz Chemical Science and Technology , (3) , 27-32 . Retrieved from https://dergipark.org.tr/en/pub/kcst/issue/42072/439722
MLA Şen, P , Yıldız, S , Tamer, Ö , Kanmazalp, S , Dege, N . "Synthesis, Molecular Structure, Spectroscopic and Computational Studies of (E)-tert-butyl (2-((3,5-di-tert-butyl-2-hydroxybenzylidene) amino)ethyl)carbamate as Functionalized Schiff Base" . Karadeniz Chemical Science and Technology (2018 ): 27-32 <https://dergipark.org.tr/en/pub/kcst/issue/42072/439722>
Chicago Şen, P , Yıldız, S , Tamer, Ö , Kanmazalp, S , Dege, N . "Synthesis, Molecular Structure, Spectroscopic and Computational Studies of (E)-tert-butyl (2-((3,5-di-tert-butyl-2-hydroxybenzylidene) amino)ethyl)carbamate as Functionalized Schiff Base". Karadeniz Chemical Science and Technology (2018 ): 27-32
RIS TY - JOUR T1 - Synthesis, Molecular Structure, Spectroscopic and Computational Studies of (E)-tert-butyl (2-((3,5-di-tert-butyl-2-hydroxybenzylidene) amino)ethyl)carbamate as Functionalized Schiff Base AU - Pınar Şen , Salih Zeki Yıldız , Ömer Tamer , Sibel Demir Kanmazalp , Necmi Dege Y1 - 2018 PY - 2018 N1 - DO - T2 - Karadeniz Chemical Science and Technology JF - Journal JO - JOR SP - 27 EP - 32 VL - IS - 3 SN - -2636-8560 M3 - UR - Y2 - 2018 ER -
EndNote %0 Karadeniz Chemical Science and Technology Synthesis, Molecular Structure, Spectroscopic and Computational Studies of (E)-tert-butyl (2-((3,5-di-tert-butyl-2-hydroxybenzylidene) amino)ethyl)carbamate as Functionalized Schiff Base %A Pınar Şen , Salih Zeki Yıldız , Ömer Tamer , Sibel Demir Kanmazalp , Necmi Dege %T Synthesis, Molecular Structure, Spectroscopic and Computational Studies of (E)-tert-butyl (2-((3,5-di-tert-butyl-2-hydroxybenzylidene) amino)ethyl)carbamate as Functionalized Schiff Base %D 2018 %J Karadeniz Chemical Science and Technology %P -2636-8560 %V %N 3 %R %U
ISNAD Şen, Pınar , Yıldız, Salih Zeki , Tamer, Ömer , Kanmazalp, Sibel Demir , Dege, Necmi . "Synthesis, Molecular Structure, Spectroscopic and Computational Studies of (E)-tert-butyl (2-((3,5-di-tert-butyl-2-hydroxybenzylidene) amino)ethyl)carbamate as Functionalized Schiff Base". Karadeniz Chemical Science and Technology / 3 (December 2018): 27-32 .
AMA Şen P , Yıldız S , Tamer Ö , Kanmazalp S , Dege N . Synthesis, Molecular Structure, Spectroscopic and Computational Studies of (E)-tert-butyl (2-((3,5-di-tert-butyl-2-hydroxybenzylidene) amino)ethyl)carbamate as Functionalized Schiff Base. Karadeniz Chem. Sci. Tech.. 2018; (3): 27-32.
Vancouver Şen P , Yıldız S , Tamer Ö , Kanmazalp S , Dege N . Synthesis, Molecular Structure, Spectroscopic and Computational Studies of (E)-tert-butyl (2-((3,5-di-tert-butyl-2-hydroxybenzylidene) amino)ethyl)carbamate as Functionalized Schiff Base. Karadeniz Chemical Science and Technology. 2018; (3): 27-32.
IEEE P. Şen , S. Yıldız , Ö. Tamer , S. Kanmazalp and N. Dege , "Synthesis, Molecular Structure, Spectroscopic and Computational Studies of (E)-tert-butyl (2-((3,5-di-tert-butyl-2-hydroxybenzylidene) amino)ethyl)carbamate as Functionalized Schiff Base", Karadeniz Chemical Science and Technology, no. 3, pp. 27-32, Dec. 2019