This work presents the synthesis and characterization of a novel compound, (E)-tert-butyl (2-((3,5-di-tert-butyl-2-hydroxybenzylidene)amino)ethyl)carbamate as the Schiff base derivative.
This compound have been selected as a ligand for the preparation of unsymmetrical metal complexes which is a potential candidate as unsymmetrical catalyst. The spectroscopic properties of the compound were examined by FT-IR, 1H NMR, 13C NMR, MS and elemental analyses. The molecular structure of the compound was also confirmed using X-ray single-crystal data. The molecule is stabilized through intermolecular N—H···O hydrogen bonds, which form chains extending along [100]. And also it has been calculated; molecular structure, vibrational frequencies and 1H and 13C NMR chemical shifts of the title compound by using B3LYP method with 6-311++G(dp) basis set, as well.
| Primary Language | en |
|---|---|
| Subjects | Engineering, Chemical |
| Journal Section | Research Article |
| Authors |
|
| Dates |
Publication Date : December 31, 2018 |
| Bibtex | @research article { kcst439722,
journal = {Karadeniz Chemical Science and Technology},
issn = {},
eissn = {2636-8560},
address = {Karadeniz Chemical Science and Technology (KCST) Journal, Department of Chemistry, Faculty of Science, KTU, 61080, Trabzon, TÜRKİYE},
publisher = {KCST Founding Board},
year = {2018},
volume = {},
pages = {27 - 32},
doi = {},
title = {Synthesis, Molecular Structure, Spectroscopic and Computational Studies of (E)-tert-butyl (2-((3,5-di-tert-butyl-2-hydroxybenzylidene) amino)ethyl)carbamate as Functionalized Schiff Base},
key = {cite},
author = {Şen, Pınar and Yıldız, Salih Zeki and Tamer, Ömer and Kanmazalp, Sibel Demir and Dege, Necmi}
} |
| APA | Şen, P , Yıldız, S , Tamer, Ö , Kanmazalp, S , Dege, N . (2018). Synthesis, Molecular Structure, Spectroscopic and Computational Studies of (E)-tert-butyl (2-((3,5-di-tert-butyl-2-hydroxybenzylidene) amino)ethyl)carbamate as Functionalized Schiff Base . Karadeniz Chemical Science and Technology , (3) , 27-32 . Retrieved from https://dergipark.org.tr/en/pub/kcst/issue/42072/439722 |
| MLA | Şen, P , Yıldız, S , Tamer, Ö , Kanmazalp, S , Dege, N . "Synthesis, Molecular Structure, Spectroscopic and Computational Studies of (E)-tert-butyl (2-((3,5-di-tert-butyl-2-hydroxybenzylidene) amino)ethyl)carbamate as Functionalized Schiff Base" . Karadeniz Chemical Science and Technology (2018 ): 27-32 <https://dergipark.org.tr/en/pub/kcst/issue/42072/439722> |
| Chicago | Şen, P , Yıldız, S , Tamer, Ö , Kanmazalp, S , Dege, N . "Synthesis, Molecular Structure, Spectroscopic and Computational Studies of (E)-tert-butyl (2-((3,5-di-tert-butyl-2-hydroxybenzylidene) amino)ethyl)carbamate as Functionalized Schiff Base". Karadeniz Chemical Science and Technology (2018 ): 27-32 |
| RIS | TY - JOUR T1 - Synthesis, Molecular Structure, Spectroscopic and Computational Studies of (E)-tert-butyl (2-((3,5-di-tert-butyl-2-hydroxybenzylidene) amino)ethyl)carbamate as Functionalized Schiff Base AU - Pınar Şen , Salih Zeki Yıldız , Ömer Tamer , Sibel Demir Kanmazalp , Necmi Dege Y1 - 2018 PY - 2018 N1 - DO - T2 - Karadeniz Chemical Science and Technology JF - Journal JO - JOR SP - 27 EP - 32 VL - IS - 3 SN - -2636-8560 M3 - UR - Y2 - 2018 ER - |
| EndNote | %0 Karadeniz Chemical Science and Technology Synthesis, Molecular Structure, Spectroscopic and Computational Studies of (E)-tert-butyl (2-((3,5-di-tert-butyl-2-hydroxybenzylidene) amino)ethyl)carbamate as Functionalized Schiff Base %A Pınar Şen , Salih Zeki Yıldız , Ömer Tamer , Sibel Demir Kanmazalp , Necmi Dege %T Synthesis, Molecular Structure, Spectroscopic and Computational Studies of (E)-tert-butyl (2-((3,5-di-tert-butyl-2-hydroxybenzylidene) amino)ethyl)carbamate as Functionalized Schiff Base %D 2018 %J Karadeniz Chemical Science and Technology %P -2636-8560 %V %N 3 %R %U |
| ISNAD | Şen, Pınar , Yıldız, Salih Zeki , Tamer, Ömer , Kanmazalp, Sibel Demir , Dege, Necmi . "Synthesis, Molecular Structure, Spectroscopic and Computational Studies of (E)-tert-butyl (2-((3,5-di-tert-butyl-2-hydroxybenzylidene) amino)ethyl)carbamate as Functionalized Schiff Base". Karadeniz Chemical Science and Technology / 3 (December 2018): 27-32 . |
| AMA | Şen P , Yıldız S , Tamer Ö , Kanmazalp S , Dege N . Synthesis, Molecular Structure, Spectroscopic and Computational Studies of (E)-tert-butyl (2-((3,5-di-tert-butyl-2-hydroxybenzylidene) amino)ethyl)carbamate as Functionalized Schiff Base. Karadeniz Chem. Sci. Tech.. 2018; (3): 27-32. |
| Vancouver | Şen P , Yıldız S , Tamer Ö , Kanmazalp S , Dege N . Synthesis, Molecular Structure, Spectroscopic and Computational Studies of (E)-tert-butyl (2-((3,5-di-tert-butyl-2-hydroxybenzylidene) amino)ethyl)carbamate as Functionalized Schiff Base. Karadeniz Chemical Science and Technology. 2018; (3): 27-32. |
| IEEE | P. Şen , S. Yıldız , Ö. Tamer , S. Kanmazalp and N. Dege , "Synthesis, Molecular Structure, Spectroscopic and Computational Studies of (E)-tert-butyl (2-((3,5-di-tert-butyl-2-hydroxybenzylidene) amino)ethyl)carbamate as Functionalized Schiff Base", Karadeniz Chemical Science and Technology, no. 3, pp. 27-32, Dec. 2019 |