Investigation of extraction properties of calix[4]arene dinitro derivative supported in merrifield resin towards phenolic species in aqueous media

Abstract

This article describes the preparation of calix[4]arene dinitro derivative supported in Merrifield resin (DNC[4]MR) and the investigation of its extraction properties towards some phenolic species such as phenol (PHE), p-chlorophenol (PCP), m-nitrophenol (MNP) and p-nitrophenol (PNP) which are important organic contaminants in aqueous media. Synthesized compounds were characterized by FT-IR analysis. According to results, % extraction values of phenolic species above mentioned were found 24,3, 40,5, 62,4 ve 65,9 %, respectively. Additionally, the extraction properties of DNK[4]MR were investigated towards phenolic species towards different concentrations. Finally, the extraction properties of DNK[4]MR were also evaluated for different concentrations of the ligand. Extraction equilibrium constants were calculated by log D vs. log [L] graphs. Consequently, according to both literature and this study, calixarene derivatives which have a unique three-dimensional structure and hydrogen bonding capabilities can be useful for removal of phenolic species from aqueous media.

Keywords

• Calixarene,Extraction,Hydrogen bonding,Merrifield resin,Phenolic species

MERRIFIELD REÇİNESİNE DESTEKLENMİŞ KALİKS[4]AREN DİNİTRO TÜREVİNİN SULU ORTAMDAKİ FENOLİK TÜRLERE KARŞI EKSTRAKSİYON ÖZELLİKLERİNİN İNCELENMESİ

Öz

Bu çalışmada, Merrifield reçinesine desteklenmiş kaliks[4]aren dinitro türevi (DNK[4]MR) hazırlanarak, sulu ortamda bulunan önemli organik kirleticilerden olan fenol (FEN), p-klorofenol (PKF), m-nitrofenol (MNF) ve p-nitrofenol (PNF) gibi bazı fenolik türlere karşı ekstraksiyon özellikleri incelendi. Sentezlenen bileşiklerin, FT-IR analizleri ile karakterizasyonları gerçekleştirildi. Sonuçlara göre, yukarıda bahsi geçen fenolik türlere karşı sırasıyla % 24,3, 40,5, 62,4 ve 65,9 ekstraksiyon verileri elde edildi. Ayrıca, farklı fenolik tür konsantrasyonlarına karşı DNK[4]MR'nin ekstraksiyon özellikleri incelendi. Son olarak, DNK[4]MR'nin fenolik türlere karşı ekstraksiyon kabiliyetlerinin ayrıntılı bir şekilde incelenmesi için farklı konsantrasyonlarda ligand çözeltileri hazırlanarak log D'ye karşı log [L] grafiği çizilerek etkileşim sonucu oluşan ekstraksiyon denge sabitleri (Kex) hesaplandı. Hem literatür bilgileri hem de yapılan bu çalışmanın sonuçlarına göre, kaliksaren türevlerinin kendisine özgü üç boyutlu yapısı ve hidrojen bağı yapabilme kabiliyetleri sayesinde, fenolik türlerin sulu ortamlardan uzaklaştırılması konusunda oldukça kullanışlı olabileceklerini göstermiştir.

Anahtar Kelimeler

• Ekstraksiyon,Hidrojen bağı,Fenolik türler,Kaliksaren,Merrifield reçinesi

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