KALİKSAREN TÜREVİ İMMOBİLİZE EDİLMİŞ MERRIFIELD REÇİNESİ İLE KAPLI QCM SENSÖRÜNDE SULU ORTAMDA 4-NİTROFENOL ALGILANMASI
Abstract
Bu çalışma, kaliksaren hidrazin amit türevi içeren
Merrifield reçinesi (KIMR) ile modifiye edilmiş bir QCM sensörün sulu ortamdaki
p-nitrofenol (PNF) için algılama
çalışmalarını açıklamaktadır. Bu amaçla öncelikle KIMR hazırlanarak yapısı
karakterize edildi ve daha sonra QCM kristal yüzeyine kaplandı. Elde edilen
KIMR modifiyeli sensörün PNF algılama çalışmaları, PNF için iyi bir algılama
gösterdiğini ortaya çıkardı. Böylece sulu ortamda farklı konsantrasyon ve
farklı pH’larda algılama çalışmaları gerçekleştirildi. Sonuçlardan limit algılama değerinin 0,34 mM
olduğu ve en iyi algılamanın pH 10 da gerçekleştiği anlaşıldı. Ayrıca Langmuir
ve Freundlich adsorpsiyon izotermlerinden KIMR’nin adsorpsiyon kapasitesi, 372 mg/g
olarak hesaplandı.
References
- Collins, E., M., McKervey, M. A., Madigan, E., Moran, M, B., Owens, M., Ferguson, G., Harris, S. J., 1991, “Chemically Modified Calix[4]arenes. Regioselective Synthesis of 1,3-(distal) Derivatives and Related Compounds. X-Ray Crystal Structure of a Diphenol-dinitrile”, Journal of the Chemical Society, Perkin Transactions 1, Vol. 12, pp. 3137 – 3142.
- Dolaksiz, Ekin., Y., Temel, F., Tabakci, M., 2018, “Adsorption of Phenolic Compounds onto Calix[4]arene-bonded Silica Gels from Aqueous Solutions”, Reactive and Functional Polymers, Vol. 126, pp. 27 – 35.
- Gutsche, C. D., Iqbal, M., 1990, “ p-tert-BUTYLCALIX[4]ARENE”, Organic Syntheses, Vol. 68, pp. 234 – 237.
- Korpayev, S., Kavaklı, C., Tilki, S., Akkaş Kavaklı, P., 2018, “Novel Cotton Fabric Adsorbent for Efficient As(V) Adsorption”, Environmental Science and Pollution Research, Vol. 25, pp.34610 – 34622.
- Lai,, B., Zhang, Y., Chen, Z., Yang, P., Zhou, Y., Wang, J., 2014, “Removal of p-nitrophenol (PNP) in Aqueous Solution by the Micron-Scale Iron-Copper (Fe/Cu) Bimetallic Particles”, Appl Catal B Environ, Vol. 144, pp. 816 – 830.
- Maity, D., Chakraborty, A., Gunupuru, R., Paul, P., 2011, “Calix[4]arene based Molecular Sensors with Pyrene as Fluoregenic Unit: Effect of Solvent in Ion Selectivity and Colorimetric Detection of Flüoride”, Inorganica Chimica Acta, Vol. 372, pp. 126 – 135.
- Memon, S., Tabakci, M., Roundhill D. M., Yilmaz, M. 2006, “Synthesis and Evaluation of the Cr(VI) Extraction Ability of Amino/nitrile calix[4]arene Immobilized onto a Polymeric Backbone”, Reactive & Functional Polymer, Vol. 66, pp. 1342 – 1349.
- Sauerbrey, G., 1959, “Verwendung von Schwingquarzen zur Wägung dünner Schichten und zur Mikrowägung” Zeitschrift für Physik A Hadrons and Nuclei,. Vol. 155 no.2, pp. 206 – 222.
- Temel, F., 2013, Farklı Yapılardaki Kaliksaren Türevlerinin Gaz Algılama Özelliklerinin İncelenmesi, Yüksek Lisans Tezi, Selçuk Üniversitesi, Fen Bilimleri Enstitüsü, Konya.
- Temel, F., Ozcelik, E., Ture, A. G., Tabakci, M., 2017, “Sensing Abilities of Functionalized calix[4]arene Coated QCM Sensors Towards Volatile Organic Compounds in Aqueous Media”, Applied Surface Science, Vol. 412, pp. 238 – 251.
- Temel, F., Tabakci, M., 2016, “Calix[4]arene Coated QCM Sensors for Detection of VOC Emission: Methylene Chloride Sensing Studies”, Talanta, Vol. 153, pp. 221 – 227.
- Yu, P., Huang, K., Zhao, J., Zhang, C., Xie, K., Deng, F., Liu, H. 2010, “A Novel Seperation Technique: Gas-Assisted Three-Liquid-Phase Extraction for Treatment of The Phenolic Wastewater” Sep Purif Technol, Vol. 75, pp. 16 – 322.
Sensing of p-Nitrophenol in Aqueous Media on QCM Sensor Coated with Calixarene Derivative Immobilized Merrifield Resin
Abstract
This
study describes the sensing studies of QCM sensor which modified with
calixarene hydrazine amide derivative immobilized Merrifield resin (CIMR) for
the p-nitrophenol (PNP) sensing in
aqueous media. For this aim, first CIMR was prepared and its structure was
characterized, and then it was coated onto the QCM crystal surface. The PNP
sensing studies of CIMR modified QCM sensor revealed good results for PNP
sensing. Thus, it was performed the sensing studies at different concentration
and pHs in aqueous media. From the results, it was found that the limit of
detection was 0.34 mM and optimum pH value was 10 for PNF sensing by CIMR modified
QCM sensor. Moreover, it was calculated the adsorption capacity of CIMR as 372
mg/g from the Langmuir and Freundlich isotherm models.
References
- Collins, E., M., McKervey, M. A., Madigan, E., Moran, M, B., Owens, M., Ferguson, G., Harris, S. J., 1991, “Chemically Modified Calix[4]arenes. Regioselective Synthesis of 1,3-(distal) Derivatives and Related Compounds. X-Ray Crystal Structure of a Diphenol-dinitrile”, Journal of the Chemical Society, Perkin Transactions 1, Vol. 12, pp. 3137 – 3142.
- Dolaksiz, Ekin., Y., Temel, F., Tabakci, M., 2018, “Adsorption of Phenolic Compounds onto Calix[4]arene-bonded Silica Gels from Aqueous Solutions”, Reactive and Functional Polymers, Vol. 126, pp. 27 – 35.
- Gutsche, C. D., Iqbal, M., 1990, “ p-tert-BUTYLCALIX[4]ARENE”, Organic Syntheses, Vol. 68, pp. 234 – 237.
- Korpayev, S., Kavaklı, C., Tilki, S., Akkaş Kavaklı, P., 2018, “Novel Cotton Fabric Adsorbent for Efficient As(V) Adsorption”, Environmental Science and Pollution Research, Vol. 25, pp.34610 – 34622.
- Lai,, B., Zhang, Y., Chen, Z., Yang, P., Zhou, Y., Wang, J., 2014, “Removal of p-nitrophenol (PNP) in Aqueous Solution by the Micron-Scale Iron-Copper (Fe/Cu) Bimetallic Particles”, Appl Catal B Environ, Vol. 144, pp. 816 – 830.
- Maity, D., Chakraborty, A., Gunupuru, R., Paul, P., 2011, “Calix[4]arene based Molecular Sensors with Pyrene as Fluoregenic Unit: Effect of Solvent in Ion Selectivity and Colorimetric Detection of Flüoride”, Inorganica Chimica Acta, Vol. 372, pp. 126 – 135.
- Memon, S., Tabakci, M., Roundhill D. M., Yilmaz, M. 2006, “Synthesis and Evaluation of the Cr(VI) Extraction Ability of Amino/nitrile calix[4]arene Immobilized onto a Polymeric Backbone”, Reactive & Functional Polymer, Vol. 66, pp. 1342 – 1349.
- Sauerbrey, G., 1959, “Verwendung von Schwingquarzen zur Wägung dünner Schichten und zur Mikrowägung” Zeitschrift für Physik A Hadrons and Nuclei,. Vol. 155 no.2, pp. 206 – 222.
- Temel, F., 2013, Farklı Yapılardaki Kaliksaren Türevlerinin Gaz Algılama Özelliklerinin İncelenmesi, Yüksek Lisans Tezi, Selçuk Üniversitesi, Fen Bilimleri Enstitüsü, Konya.
- Temel, F., Ozcelik, E., Ture, A. G., Tabakci, M., 2017, “Sensing Abilities of Functionalized calix[4]arene Coated QCM Sensors Towards Volatile Organic Compounds in Aqueous Media”, Applied Surface Science, Vol. 412, pp. 238 – 251.
- Temel, F., Tabakci, M., 2016, “Calix[4]arene Coated QCM Sensors for Detection of VOC Emission: Methylene Chloride Sensing Studies”, Talanta, Vol. 153, pp. 221 – 227.
- Yu, P., Huang, K., Zhao, J., Zhang, C., Xie, K., Deng, F., Liu, H. 2010, “A Novel Seperation Technique: Gas-Assisted Three-Liquid-Phase Extraction for Treatment of The Phenolic Wastewater” Sep Purif Technol, Vol. 75, pp. 16 – 322.
Details
| Primary Language | Turkish |
|---|---|
| Subjects | Engineering |
| Journal Section | Research Article |
| Authors | |
| Publication Date | September 1, 2019 |
| Submission Date | January 19, 2019 |
| Acceptance Date | February 27, 2019 |
| Published in Issue | Year 2019 Volume: 7 Issue: 3 |
