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AZ91 Mg ALAŞIMLARINDA KOROZYON DAVRANIŞI-Fe TOLERANS SINIRI ARASINDAKİ İLİŞKİNİN ARAŞTIRILMASI

Year 2019, Volume: 7 Issue: 3, 654 - 662, 01.09.2019
https://doi.org/10.36306/konjes.613896

Abstract

Bu çalışmada, aynı şartlarda üretilmiş (benzer katılaşma hızı ve benzer
kimyasal bileşimde) farklı Fe içeriğine (% ağ. 0.025, 0.05, 0.1) sahip AZ91 Mg alaşımlarının
korozyon davranışları-Fe tolerans limit değeri arasındaki ilişki
değerlendirilmiştir. Numunelerin mikro yapı analizleri
Taramalı Elektron Mikroskobu (SEM) ve X Işını Difraktometre (XRD) kullanılarak
yapılmıştır.
Korozyon davranışları %3,5 NaCl çözeltisinde, ağırlık kaybı
ve potansiyodinamik polarizasyon test yöntemleri kullanılarak araştırılmıştır. Mikroyapı
analizlerinde, Fe içeriğinin artması ile yapıdaki “kısmen ayrışmış” veya “lameller
ötektik” tipi β fazı morfolojilerinde artış eğiliminin daha fazla olduğu
gözlenmiştir. Sonuçlar, AZ91 alaşımı Fe tolerans limit değerinin
~%0.05 olduğunu bu değerden sonra korozyon kaybının eksponansiyel olarak
arttığını göstermiştir.

Supporting Institution

Bilecik Şeyh Edebali Üniversitesi BAP

Project Number

2017-01.BSEU.03-02

Thanks

Bu çalışma Bilecik Şeyh Edebali Üniversitesi, 2017-01.BSEU.03-02 nolu BAP projesinden desteklenmiştir.

References

  • Agarwal, S., Curtin, J., Duffy, B., Jaiswal, S., 2016, "Biodegradable magnesium alloys for orthopaedic applications: A review on corrosion, biocompatibility and surface modifications". Materials Science and Engineering C, Cilt 68, ss, 948–963.
  • Boby, A., Srinivasan, A., Pillai, U. T. S., Pai, B. C., 2015, "Mechanical characterization and corrosion behavior of newly designed Sn and Y added AZ91 alloy". Materials and Design, Cilt 88, ss, 871–879.
  • Candan, S., Candan, E., 2018a, "Comparative study on corrosion behaviors of Mg-Al-Zn alloys". Transactions of Nonferrous Metals Society of China (English Edition), Cilt 28, Sayı 4, ss, 642–650.
  • Candan, Ş., Çim, S., Emir, S., Candan, E., 2018b, "AZ Serisi Mg Alaşımlarının Korozyon Davranışlarında β-Fazının Rolü". Düzce Üniversitesi Bilim ve Teknoloji Dergisi, Cilt 6, Sayı 4, ss, 1139–1162.
  • Candan, S., Candan, E., 2017, "A comparative study on corrosion of Mg--Al--Si alloys". Transactions of Nonferrous Metals Society of China, Cilt 27, Sayı 8, ss, 1725–1734.
  • Candan, S., Celik, M., Candan, E., 2016, "Effectiveness of Ti-micro alloying in relation to cooling rate on corrosion of AZ91 Mg alloy". Journal of Alloys and Compounds, Cilt 672, ss, 197–203.
  • Candan, S., Unal, M., Koc, E., Turen, Y., Candan, E., 2011, "Effects of titanium addition on mechanical and corrosion behaviours of AZ91 magnesium alloy". Journal of Alloys and Compounds, Cilt 509, Sayı 5, ss, 1958–1963.
  • Candan, S., Unal, M., Turkmen, M., Koc, E., Turen, Y., Candan, E., 2009, "Improvement of mechanical and corrosion properties of magnesium alloy by lead addition". Materials Science and Engineering A, Cilt 501, Sayı 1–2, ss, 115–118.
  • Dahle, A. K., Lee, Y. C., Nave, M. D., Schaffer, P. L., StJohn, D. H., 2001, "Development of the as-cast microstructure in magnesium-aluminium alloys". Journal of Light Metals, Cilt 1, Sayı 1, ss, 61–72.
  • Eddy Jai Poinern, G., Brundavanam, S., Fawcett, D., 2013, "Biomedical Magnesium Alloys: A Review of Material Properties, Surface Modifications and Potential as a Biodegradable Orthopaedic Implant". American Journal of Biomedical Engineering, Cilt 2, Sayı 6, ss, 218–240.
  • Esmaily, M., Svensson, J. E., Fajardo, S., Birbilis, N., Frankel, G. S., Virtanen, S., Johansson, L. G., 2017, "Fundamentals and advances in magnesium alloy corrosion". Progress in Materials Science. Cilt 89, ss, 92–193.
  • Friedrich, H. E., Mordike, B. L., 2006, Magnesium technology: Metallurgy, design data, applications. Magnesium Technology: Metallurgy, Design Data, Applications.
  • Gusieva, K., Davies, C. H. J., Scully, J. R., & Birbilis, N., 2015, "c". International Materials Reviews. Cilt 60, Sayı 3, ss, 169-194.
  • Ikeo, N., Shimizu, J., Ishigaki, C., Sano, Y., Shimizu, Y., Mukai, T., 2015, "Magnesium Technology 2015, ed. by MV Manuel, A. Singh, M. Alderman and NR Neelameggham". Wiley.
  • Luo, A. A., Sachdev, A. K., 2012, "Applications of magnesium alloys in automotive engineering". In Advances in wrought magnesium alloys (pp. 393–426). Elsevier.
  • Nave, M. D., Dahle, A. K., StJohn, D. H., 2000, "Eutectic Growth Morphologies in Magnesium-Aluminium Alloys". In Magnesium Technology 2000 (pp. 233–242).
  • Pan, F., Chen, X., Yan, T., Liu, T., Mao, J., Luo, W., Jiang, B., 2016a, "A novel approach to melt purification of magnesium alloys". Journal of Magnesium and Alloys, Cilt 4, Sayı 1, ss, 8–14.
  • Pan, F., Yang, M., Chen, X., 2016b, "A Review on Casting Magnesium Alloys: Modification of Commercial Alloys and Development of New Alloys". Journal of Materials Science and Technology, Cilt 32, Sayı 12, ss, 1211–1221.
  • Pekguleryuz, M., 2013, "Alloying behavior of magnesium and alloy design". In Fundamentals of Magnesium Alloy Metallurgy (pp. 152–196).
  • Polmear, I. J., 2006, Light Alloys: From Traditional Alloys to Nanocrystals. Light Alloys.
  • Salman, S. A., Ichino, R., Okido, M., 2010, "A comparative electrochemical study of AZ31 and AZ91 magnesium alloy". In International Journal of Corrosion.
  • Samaniego, A., Llorente, I., Feliu, S., 2013, "Combined effect of composition and surface condition on corrosion behaviour of magnesium alloys AZ31 and AZ61". Corrosion Science, Cilt 68, ss, 66–71.
  • Singh, I. B., Singh, M., Das, S., 2015, "A comparative corrosion behavior of Mg, AZ31 and AZ91 alloys in 3.5% NaCl solution". Journal of Magnesium and Alloys, Cilt 3, Sayı 2, ss, 142–148.
  • Song, G., Atrens, A., Wu, X., Zhang, B., 1998, "Corrosion behaviour of AZ21, AZ501 and AZ91 in Sodium Chloride". Corrosion Science, Cilt 40, Sayı 10, ss, 1769–1791.
  • Song, G. L., Atrens, A., 1999, "Corrosion mechanisms of magnesium alloys". Advanced Engineering Materials, Cilt 1, Sayı 1, ss, 11–33.
  • Srinivasan, A., Pillai, U. T. S., Pai, B. C., 2007, "Effect of Pb addition on ageing behavior of AZ91 magnesium alloy". Materials Science and Engineering A, Cilt 452, Sayı , ss, 87–92.
  • Wang, L., Shinohara, T., Zhang, B. P., 2012, "Electrochemical behaviour of AZ61 magnesium alloy in dilute NaCl solutions". Materials and Design, Cilt 33, ss, 345–349.
  • Wang, T., Kevorkov, D., Mostafa, A., Medraj, M., 2014, "Experimental Investigation of the Phase Equilibria in the Al-Mn-Zn System at 400°C". In Journal of Materials.
  • Zhao, M. C., Liu, M., Song, G., Atrens, A., 2008, "Influence of the β-phase morphology on the corrosion of the Mg alloy AZ91". Corrosion Science, Cilt 50, Sayı 7, ss, 1939−1953.

An Investigation of Relationship Between Corrosion Behaviour- Fe Tolerance Limit in AZ91 Mg Alloys

Year 2019, Volume: 7 Issue: 3, 654 - 662, 01.09.2019
https://doi.org/10.36306/konjes.613896

Abstract

In this study, relationship
between Corrosion Behaviour-Tolerance Limit of Fe content (0.025, 0.05, 0.1 wt.
%) in AZ91 Mg alloys, cast under similar chemical composition and cooling rate,
were investigated. The microstructures of Mg alloys were analysed by Scanning
Electron Microscopy (SEM) and X Ray Diffractometry (XRD). The corrosion
behaviours were evaluated by immersion tests and electrochemical polarization
measurements in 3.5 wt. % NaCl solution. Microstructure analysis revealed that
the increase of Fe content increased the “partially divorced” or “lamella
eutectic” type β phase morphologies in the microstructure. Results indicated
that the limit content value of Fe in AZ91 alloys was
~0.05 wt. % above which the
corrosion loss had increased abruptly.

Project Number

2017-01.BSEU.03-02

References

  • Agarwal, S., Curtin, J., Duffy, B., Jaiswal, S., 2016, "Biodegradable magnesium alloys for orthopaedic applications: A review on corrosion, biocompatibility and surface modifications". Materials Science and Engineering C, Cilt 68, ss, 948–963.
  • Boby, A., Srinivasan, A., Pillai, U. T. S., Pai, B. C., 2015, "Mechanical characterization and corrosion behavior of newly designed Sn and Y added AZ91 alloy". Materials and Design, Cilt 88, ss, 871–879.
  • Candan, S., Candan, E., 2018a, "Comparative study on corrosion behaviors of Mg-Al-Zn alloys". Transactions of Nonferrous Metals Society of China (English Edition), Cilt 28, Sayı 4, ss, 642–650.
  • Candan, Ş., Çim, S., Emir, S., Candan, E., 2018b, "AZ Serisi Mg Alaşımlarının Korozyon Davranışlarında β-Fazının Rolü". Düzce Üniversitesi Bilim ve Teknoloji Dergisi, Cilt 6, Sayı 4, ss, 1139–1162.
  • Candan, S., Candan, E., 2017, "A comparative study on corrosion of Mg--Al--Si alloys". Transactions of Nonferrous Metals Society of China, Cilt 27, Sayı 8, ss, 1725–1734.
  • Candan, S., Celik, M., Candan, E., 2016, "Effectiveness of Ti-micro alloying in relation to cooling rate on corrosion of AZ91 Mg alloy". Journal of Alloys and Compounds, Cilt 672, ss, 197–203.
  • Candan, S., Unal, M., Koc, E., Turen, Y., Candan, E., 2011, "Effects of titanium addition on mechanical and corrosion behaviours of AZ91 magnesium alloy". Journal of Alloys and Compounds, Cilt 509, Sayı 5, ss, 1958–1963.
  • Candan, S., Unal, M., Turkmen, M., Koc, E., Turen, Y., Candan, E., 2009, "Improvement of mechanical and corrosion properties of magnesium alloy by lead addition". Materials Science and Engineering A, Cilt 501, Sayı 1–2, ss, 115–118.
  • Dahle, A. K., Lee, Y. C., Nave, M. D., Schaffer, P. L., StJohn, D. H., 2001, "Development of the as-cast microstructure in magnesium-aluminium alloys". Journal of Light Metals, Cilt 1, Sayı 1, ss, 61–72.
  • Eddy Jai Poinern, G., Brundavanam, S., Fawcett, D., 2013, "Biomedical Magnesium Alloys: A Review of Material Properties, Surface Modifications and Potential as a Biodegradable Orthopaedic Implant". American Journal of Biomedical Engineering, Cilt 2, Sayı 6, ss, 218–240.
  • Esmaily, M., Svensson, J. E., Fajardo, S., Birbilis, N., Frankel, G. S., Virtanen, S., Johansson, L. G., 2017, "Fundamentals and advances in magnesium alloy corrosion". Progress in Materials Science. Cilt 89, ss, 92–193.
  • Friedrich, H. E., Mordike, B. L., 2006, Magnesium technology: Metallurgy, design data, applications. Magnesium Technology: Metallurgy, Design Data, Applications.
  • Gusieva, K., Davies, C. H. J., Scully, J. R., & Birbilis, N., 2015, "c". International Materials Reviews. Cilt 60, Sayı 3, ss, 169-194.
  • Ikeo, N., Shimizu, J., Ishigaki, C., Sano, Y., Shimizu, Y., Mukai, T., 2015, "Magnesium Technology 2015, ed. by MV Manuel, A. Singh, M. Alderman and NR Neelameggham". Wiley.
  • Luo, A. A., Sachdev, A. K., 2012, "Applications of magnesium alloys in automotive engineering". In Advances in wrought magnesium alloys (pp. 393–426). Elsevier.
  • Nave, M. D., Dahle, A. K., StJohn, D. H., 2000, "Eutectic Growth Morphologies in Magnesium-Aluminium Alloys". In Magnesium Technology 2000 (pp. 233–242).
  • Pan, F., Chen, X., Yan, T., Liu, T., Mao, J., Luo, W., Jiang, B., 2016a, "A novel approach to melt purification of magnesium alloys". Journal of Magnesium and Alloys, Cilt 4, Sayı 1, ss, 8–14.
  • Pan, F., Yang, M., Chen, X., 2016b, "A Review on Casting Magnesium Alloys: Modification of Commercial Alloys and Development of New Alloys". Journal of Materials Science and Technology, Cilt 32, Sayı 12, ss, 1211–1221.
  • Pekguleryuz, M., 2013, "Alloying behavior of magnesium and alloy design". In Fundamentals of Magnesium Alloy Metallurgy (pp. 152–196).
  • Polmear, I. J., 2006, Light Alloys: From Traditional Alloys to Nanocrystals. Light Alloys.
  • Salman, S. A., Ichino, R., Okido, M., 2010, "A comparative electrochemical study of AZ31 and AZ91 magnesium alloy". In International Journal of Corrosion.
  • Samaniego, A., Llorente, I., Feliu, S., 2013, "Combined effect of composition and surface condition on corrosion behaviour of magnesium alloys AZ31 and AZ61". Corrosion Science, Cilt 68, ss, 66–71.
  • Singh, I. B., Singh, M., Das, S., 2015, "A comparative corrosion behavior of Mg, AZ31 and AZ91 alloys in 3.5% NaCl solution". Journal of Magnesium and Alloys, Cilt 3, Sayı 2, ss, 142–148.
  • Song, G., Atrens, A., Wu, X., Zhang, B., 1998, "Corrosion behaviour of AZ21, AZ501 and AZ91 in Sodium Chloride". Corrosion Science, Cilt 40, Sayı 10, ss, 1769–1791.
  • Song, G. L., Atrens, A., 1999, "Corrosion mechanisms of magnesium alloys". Advanced Engineering Materials, Cilt 1, Sayı 1, ss, 11–33.
  • Srinivasan, A., Pillai, U. T. S., Pai, B. C., 2007, "Effect of Pb addition on ageing behavior of AZ91 magnesium alloy". Materials Science and Engineering A, Cilt 452, Sayı , ss, 87–92.
  • Wang, L., Shinohara, T., Zhang, B. P., 2012, "Electrochemical behaviour of AZ61 magnesium alloy in dilute NaCl solutions". Materials and Design, Cilt 33, ss, 345–349.
  • Wang, T., Kevorkov, D., Mostafa, A., Medraj, M., 2014, "Experimental Investigation of the Phase Equilibria in the Al-Mn-Zn System at 400°C". In Journal of Materials.
  • Zhao, M. C., Liu, M., Song, G., Atrens, A., 2008, "Influence of the β-phase morphology on the corrosion of the Mg alloy AZ91". Corrosion Science, Cilt 50, Sayı 7, ss, 1939−1953.
There are 29 citations in total.

Details

Primary Language Turkish
Subjects Engineering
Journal Section Research Article
Authors

Şennur Candan

Serdar Çim

Seren Emir This is me

Ercan Candan This is me

Project Number 2017-01.BSEU.03-02
Publication Date September 1, 2019
Submission Date January 20, 2019
Acceptance Date March 13, 2019
Published in Issue Year 2019 Volume: 7 Issue: 3

Cite

IEEE Ş. Candan, S. Çim, S. Emir, and E. Candan, “AZ91 Mg ALAŞIMLARINDA KOROZYON DAVRANIŞI-Fe TOLERANS SINIRI ARASINDAKİ İLİŞKİNİN ARAŞTIRILMASI”, KONJES, vol. 7, no. 3, pp. 654–662, 2019, doi: 10.36306/konjes.613896.