AZ91 Mg ALAŞIMLARINDA KOROZYON DAVRANIŞI-Fe TOLERANS SINIRI ARASINDAKİ İLİŞKİNİN ARAŞTIRILMASI
Year 2019,
Volume: 7 Issue: 3, 654 - 662, 01.09.2019
Şennur Candan
,
Serdar Çim
,
Seren Emir
Ercan Candan
Abstract
Bu çalışmada, aynı şartlarda üretilmiş (benzer katılaşma hızı ve benzer
kimyasal bileşimde) farklı Fe içeriğine (% ağ. 0.025, 0.05, 0.1) sahip AZ91 Mg alaşımlarının
korozyon davranışları-Fe tolerans limit değeri arasındaki ilişki
değerlendirilmiştir. Numunelerin mikro yapı analizleri
Taramalı Elektron Mikroskobu (SEM) ve X Işını Difraktometre (XRD) kullanılarak
yapılmıştır. Korozyon davranışları %3,5 NaCl çözeltisinde, ağırlık kaybı
ve potansiyodinamik polarizasyon test yöntemleri kullanılarak araştırılmıştır. Mikroyapı
analizlerinde, Fe içeriğinin artması ile yapıdaki “kısmen ayrışmış” veya “lameller
ötektik” tipi β fazı morfolojilerinde artış eğiliminin daha fazla olduğu
gözlenmiştir. Sonuçlar, AZ91 alaşımı Fe tolerans limit değerinin ~%0.05 olduğunu bu değerden sonra korozyon kaybının eksponansiyel olarak
arttığını göstermiştir.
Supporting Institution
Bilecik Şeyh Edebali Üniversitesi BAP
Project Number
2017-01.BSEU.03-02
Thanks
Bu çalışma Bilecik Şeyh Edebali Üniversitesi, 2017-01.BSEU.03-02 nolu BAP projesinden desteklenmiştir.
References
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- Candan, S., Candan, E., 2018a, "Comparative study on corrosion behaviors of Mg-Al-Zn alloys". Transactions of Nonferrous Metals Society of China (English Edition), Cilt 28, Sayı 4, ss, 642–650.
- Candan, Ş., Çim, S., Emir, S., Candan, E., 2018b, "AZ Serisi Mg Alaşımlarının Korozyon Davranışlarında β-Fazının Rolü". Düzce Üniversitesi Bilim ve Teknoloji Dergisi, Cilt 6, Sayı 4, ss, 1139–1162.
- Candan, S., Candan, E., 2017, "A comparative study on corrosion of Mg--Al--Si alloys". Transactions of Nonferrous Metals Society of China, Cilt 27, Sayı 8, ss, 1725–1734.
- Candan, S., Celik, M., Candan, E., 2016, "Effectiveness of Ti-micro alloying in relation to cooling rate on corrosion of AZ91 Mg alloy". Journal of Alloys and Compounds, Cilt 672, ss, 197–203.
- Candan, S., Unal, M., Koc, E., Turen, Y., Candan, E., 2011, "Effects of titanium addition on mechanical and corrosion behaviours of AZ91 magnesium alloy". Journal of Alloys and Compounds, Cilt 509, Sayı 5, ss, 1958–1963.
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- Samaniego, A., Llorente, I., Feliu, S., 2013, "Combined effect of composition and surface condition on corrosion behaviour of magnesium alloys AZ31 and AZ61". Corrosion Science, Cilt 68, ss, 66–71.
- Singh, I. B., Singh, M., Das, S., 2015, "A comparative corrosion behavior of Mg, AZ31 and AZ91 alloys in 3.5% NaCl solution". Journal of Magnesium and Alloys, Cilt 3, Sayı 2, ss, 142–148.
- Song, G., Atrens, A., Wu, X., Zhang, B., 1998, "Corrosion behaviour of AZ21, AZ501 and AZ91 in Sodium Chloride". Corrosion Science, Cilt 40, Sayı 10, ss, 1769–1791.
- Song, G. L., Atrens, A., 1999, "Corrosion mechanisms of magnesium alloys". Advanced Engineering Materials, Cilt 1, Sayı 1, ss, 11–33.
- Srinivasan, A., Pillai, U. T. S., Pai, B. C., 2007, "Effect of Pb addition on ageing behavior of AZ91 magnesium alloy". Materials Science and Engineering A, Cilt 452, Sayı , ss, 87–92.
- Wang, L., Shinohara, T., Zhang, B. P., 2012, "Electrochemical behaviour of AZ61 magnesium alloy in dilute NaCl solutions". Materials and Design, Cilt 33, ss, 345–349.
- Wang, T., Kevorkov, D., Mostafa, A., Medraj, M., 2014, "Experimental Investigation of the Phase Equilibria in the Al-Mn-Zn System at 400°C". In Journal of Materials.
- Zhao, M. C., Liu, M., Song, G., Atrens, A., 2008, "Influence of the β-phase morphology on the corrosion of the Mg alloy AZ91". Corrosion Science, Cilt 50, Sayı 7, ss, 1939−1953.
An Investigation of Relationship Between Corrosion Behaviour- Fe Tolerance Limit in AZ91 Mg Alloys
Year 2019,
Volume: 7 Issue: 3, 654 - 662, 01.09.2019
Şennur Candan
,
Serdar Çim
,
Seren Emir
Ercan Candan
Abstract
In this study, relationship
between Corrosion Behaviour-Tolerance Limit of Fe content (0.025, 0.05, 0.1 wt.
%) in AZ91 Mg alloys, cast under similar chemical composition and cooling rate,
were investigated. The microstructures of Mg alloys were analysed by Scanning
Electron Microscopy (SEM) and X Ray Diffractometry (XRD). The corrosion
behaviours were evaluated by immersion tests and electrochemical polarization
measurements in 3.5 wt. % NaCl solution. Microstructure analysis revealed that
the increase of Fe content increased the “partially divorced” or “lamella
eutectic” type β phase morphologies in the microstructure. Results indicated
that the limit content value of Fe in AZ91 alloys was ~0.05 wt. % above which the
corrosion loss had increased abruptly.
Project Number
2017-01.BSEU.03-02
References
- Agarwal, S., Curtin, J., Duffy, B., Jaiswal, S., 2016, "Biodegradable magnesium alloys for orthopaedic applications: A review on corrosion, biocompatibility and surface modifications". Materials Science and Engineering C, Cilt 68, ss, 948–963.
- Boby, A., Srinivasan, A., Pillai, U. T. S., Pai, B. C., 2015, "Mechanical characterization and corrosion behavior of newly designed Sn and Y added AZ91 alloy". Materials and Design, Cilt 88, ss, 871–879.
- Candan, S., Candan, E., 2018a, "Comparative study on corrosion behaviors of Mg-Al-Zn alloys". Transactions of Nonferrous Metals Society of China (English Edition), Cilt 28, Sayı 4, ss, 642–650.
- Candan, Ş., Çim, S., Emir, S., Candan, E., 2018b, "AZ Serisi Mg Alaşımlarının Korozyon Davranışlarında β-Fazının Rolü". Düzce Üniversitesi Bilim ve Teknoloji Dergisi, Cilt 6, Sayı 4, ss, 1139–1162.
- Candan, S., Candan, E., 2017, "A comparative study on corrosion of Mg--Al--Si alloys". Transactions of Nonferrous Metals Society of China, Cilt 27, Sayı 8, ss, 1725–1734.
- Candan, S., Celik, M., Candan, E., 2016, "Effectiveness of Ti-micro alloying in relation to cooling rate on corrosion of AZ91 Mg alloy". Journal of Alloys and Compounds, Cilt 672, ss, 197–203.
- Candan, S., Unal, M., Koc, E., Turen, Y., Candan, E., 2011, "Effects of titanium addition on mechanical and corrosion behaviours of AZ91 magnesium alloy". Journal of Alloys and Compounds, Cilt 509, Sayı 5, ss, 1958–1963.
- Candan, S., Unal, M., Turkmen, M., Koc, E., Turen, Y., Candan, E., 2009, "Improvement of mechanical and corrosion properties of magnesium alloy by lead addition". Materials Science and Engineering A, Cilt 501, Sayı 1–2, ss, 115–118.
- Dahle, A. K., Lee, Y. C., Nave, M. D., Schaffer, P. L., StJohn, D. H., 2001, "Development of the as-cast microstructure in magnesium-aluminium alloys". Journal of Light Metals, Cilt 1, Sayı 1, ss, 61–72.
- Eddy Jai Poinern, G., Brundavanam, S., Fawcett, D., 2013, "Biomedical Magnesium Alloys: A Review of Material Properties, Surface Modifications and Potential as a Biodegradable Orthopaedic Implant". American Journal of Biomedical Engineering, Cilt 2, Sayı 6, ss, 218–240.
- Esmaily, M., Svensson, J. E., Fajardo, S., Birbilis, N., Frankel, G. S., Virtanen, S., Johansson, L. G., 2017, "Fundamentals and advances in magnesium alloy corrosion". Progress in Materials Science. Cilt 89, ss, 92–193.
- Friedrich, H. E., Mordike, B. L., 2006, Magnesium technology: Metallurgy, design data, applications. Magnesium Technology: Metallurgy, Design Data, Applications.
- Gusieva, K., Davies, C. H. J., Scully, J. R., & Birbilis, N., 2015, "c". International Materials Reviews. Cilt 60, Sayı 3, ss, 169-194.
- Ikeo, N., Shimizu, J., Ishigaki, C., Sano, Y., Shimizu, Y., Mukai, T., 2015, "Magnesium Technology 2015, ed. by MV Manuel, A. Singh, M. Alderman and NR Neelameggham". Wiley.
- Luo, A. A., Sachdev, A. K., 2012, "Applications of magnesium alloys in automotive engineering". In Advances in wrought magnesium alloys (pp. 393–426). Elsevier.
- Nave, M. D., Dahle, A. K., StJohn, D. H., 2000, "Eutectic Growth Morphologies in Magnesium-Aluminium Alloys". In Magnesium Technology 2000 (pp. 233–242).
- Pan, F., Chen, X., Yan, T., Liu, T., Mao, J., Luo, W., Jiang, B., 2016a, "A novel approach to melt purification of magnesium alloys". Journal of Magnesium and Alloys, Cilt 4, Sayı 1, ss, 8–14.
- Pan, F., Yang, M., Chen, X., 2016b, "A Review on Casting Magnesium Alloys: Modification of Commercial Alloys and Development of New Alloys". Journal of Materials Science and Technology, Cilt 32, Sayı 12, ss, 1211–1221.
- Pekguleryuz, M., 2013, "Alloying behavior of magnesium and alloy design". In Fundamentals of Magnesium Alloy Metallurgy (pp. 152–196).
- Polmear, I. J., 2006, Light Alloys: From Traditional Alloys to Nanocrystals. Light Alloys.
- Salman, S. A., Ichino, R., Okido, M., 2010, "A comparative electrochemical study of AZ31 and AZ91 magnesium alloy". In International Journal of Corrosion.
- Samaniego, A., Llorente, I., Feliu, S., 2013, "Combined effect of composition and surface condition on corrosion behaviour of magnesium alloys AZ31 and AZ61". Corrosion Science, Cilt 68, ss, 66–71.
- Singh, I. B., Singh, M., Das, S., 2015, "A comparative corrosion behavior of Mg, AZ31 and AZ91 alloys in 3.5% NaCl solution". Journal of Magnesium and Alloys, Cilt 3, Sayı 2, ss, 142–148.
- Song, G., Atrens, A., Wu, X., Zhang, B., 1998, "Corrosion behaviour of AZ21, AZ501 and AZ91 in Sodium Chloride". Corrosion Science, Cilt 40, Sayı 10, ss, 1769–1791.
- Song, G. L., Atrens, A., 1999, "Corrosion mechanisms of magnesium alloys". Advanced Engineering Materials, Cilt 1, Sayı 1, ss, 11–33.
- Srinivasan, A., Pillai, U. T. S., Pai, B. C., 2007, "Effect of Pb addition on ageing behavior of AZ91 magnesium alloy". Materials Science and Engineering A, Cilt 452, Sayı , ss, 87–92.
- Wang, L., Shinohara, T., Zhang, B. P., 2012, "Electrochemical behaviour of AZ61 magnesium alloy in dilute NaCl solutions". Materials and Design, Cilt 33, ss, 345–349.
- Wang, T., Kevorkov, D., Mostafa, A., Medraj, M., 2014, "Experimental Investigation of the Phase Equilibria in the Al-Mn-Zn System at 400°C". In Journal of Materials.
- Zhao, M. C., Liu, M., Song, G., Atrens, A., 2008, "Influence of the β-phase morphology on the corrosion of the Mg alloy AZ91". Corrosion Science, Cilt 50, Sayı 7, ss, 1939−1953.