PALADYUM TEMELLİ HİDROJEN PEROKSİT YAKIT HÜCRELERİ

Year 2021, Volume: 9 , 17 - 28, 30.12.2021

Burak Yapıcı Ozlem Sahin

https://doi.org/10.36306/konjes.978975

Abstract

Bu çalışmada hidrojen peroksit (H2O2) yakıt hücrelerinde katot katalizörü olarak kullanılmak üzere paladyum (Pd) temelli, karbon nanotüp (CNT) destekli bimetalik katalizörler sentezlenmiştir. MPd (M: Ni, Ag, Co, Mn, V, Zn) bimetalik katalizörler sodyum borhidrür (NaBH4) indirgeme yöntemi ile hazırlanmıştır. Hazırlanan katalizörlerin fiziksel karakterizasyonu XRD, XPS ve TEM teknikleriyle yapılmıştır. Katalizörlerin H2O2 elektroindirgenme reaksiyonu için elektrokimyasal karakterizasyonu dönüşümlü voltametri (CV), kronoamperometri (CA) ve elektrokimyasal impedans spektroskopisi (EIS) yöntemleri ile incelenmiştir. Elektrokimyasal ölçümler üç elektrotlu hücre sisteminde sodyum hidroksit (NaOH) elektrolit çözeltisinde gerçekleştirilmiştir. CoPd/CNT katalizörü H2O2 elektroindirgenme reaksiyonu için daha yüksek elektrokatalitik aktivite göstermiştir.

Keywords

Hidrojen peroksit, Paladyum, Yakıt hücresi

Supporting Institution

TÜBİTAK, Konya Teknik Üniversitesi Bilimsel Araştırma Projeleri Koordinatörlüğü

Project Number

2210-C Öncelikli Alanlara Yönelik Yurtiçi Yüksek Lisans Burs Programı, BAP Proje No: 18201153

Thanks

Bu çalışmayı destekleyen Konya Teknik Üniversitesi Bilimsel Araştırma Projeleri Koordinatörlüğüne (Proje No: 18201153) teşekkür ederiz. Ayrıca 2210-C Öncelikli Alanlara Yönelik Yurtiçi Yüksek Lisans Burs Programı kapsamında destekleyen TÜBİTAK’a teşekkür ederiz.

Palladium Based Hydrogen Peroxide Fuel Cells

Abstract

In this study, carbon nanotube (CNT) supported palladium (Pd) based alloy catalysts were synthesized to be used as cathode catalyst in hydrogen peroxide (H2O2) fuel cells. MPd (M: Ni, Ag, Co, Mn, V, Zn) bimetallic catalysts were prepared by the sodium borohydride (NaBH4) reduction method. The physical characterization of the prepared catalysts was performed by XRD, XPS and TEM techniques. Electrochemical characterization of catalysts for H2O2 electroreduction reaction was investigated by cyclic voltammetry (CV), chronoamperometry (CA) and electrochemical impedance spectroscopy (EIS) methods. Electrochemical measurements were carried out in sodium hydroxide (NaOH) electrolyte solution in a three-electrode cell system. CoPd/CNT catalysts showed higher activity for the H2O2 electroreduction reaction.

Keywords

Hydrogen peroxide, Palladium, Fuel cell

Project Number

2210-C Öncelikli Alanlara Yönelik Yurtiçi Yüksek Lisans Burs Programı, BAP Proje No: 18201153

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