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GÖRÜNÜR IŞIK İLE UYARILABİLEN Ppy/ZnO@Fe KOMPOZİTİNİN FOTOKATALİTİK AKTİVİTESİNİN OPTİMİZASYONU

Year 2021, Volume: 9 , 42 - 53, 30.12.2021
https://doi.org/10.36306/konjes.979621

Abstract

Günümüzde endüstrileşmenin artması beraberinde pek çok çevre problemini getirmiştir. Tekstil endüstrisi başta olmak üzere, kağıt, deri ve kozmetik sektörlerinde kullanılan sentetik organik boyar maddelerin alıcı ortam olan sulara deşarjı çevreyi ciddi anlamda tehdit etmektedir. Bu nedenle, bu sektörlerden gelen ve sentetik boyar madde içeren atık suların çevreye salınmadan önce muhakkak arıtılması gerekmektedir. Günümüzde boyar maddelerin alıcı ortamdan uzaklaştırılması için fotokatalitik atık su arıtımı en çok tercih edilen yöntemlerden biridir. Bu çalışmada polimerizasyon ortamında ZnO@Fe nanopartikülleri ultrasonikasyon ile dağıtılarak pirol ve amonyum peroksidisülfat varlığında kimyasal oksidatif polimerizasyon yöntemi ile polipirol/ZnO@Fe (Ppy/ZnO@Fe) nanokompozitleri elde edilmiştir. Ppy/ZnO@Fe kompozitinin yapısal, morfolojik ve spektroskopik özellikleri SEM, XRD, FTIR, DSC ve UV-vis absorpsiyon yöntemleri ile aydınlatılmıştır. Ppy/ZnO@Fe kompozitinin fotokatalitik aktivitesi görünür ışık altında rodamin B (RdB) boyasının fotokatalitik olarak giderilmesi ile incelenmiştir. Fotokatalitik aktiviteye fotokatalizör miktarının, boya derişiminin, ışıma zamanın ve boya pH’ının etkisi deney tasarımı yöntemlerinden biri olan Taguchi yöntemi ile optimize edilmiştir. 60 dk sonunda RdB boyasının Ppy/ZnO@Fe katalizörlüğünde görünür ışık altında %99 oranında rengi giderilmiştir.

Supporting Institution

Konya Teknik Üniversitesi Bilimsel Araştırma Projeleri Koordinatörlüğü

Project Number

202016061

Thanks

Yazar finansal olarak desteklerinden dolayı Konya Teknik Üniversitesi, Bilimsel Araştırma Projeleri Koordinatörlüğüne (Proje No: 202016061) teşekkür etmektedir.

References

  • Achehboune, M., Khenfouch, M., Boukhoubza, I., Leontie, L., Doroftei, C., Carlescu, A., Bulai, G., Mothudi, B., Zorkani, I., Jorio, A., 2021, "Microstructural, FTIR and Raman spectroscopic study of Rare earth doped ZnO nanostructures",Materials Today: Proceedings, doi.org/10.1016/j.matpr.2021.04.144
  • Avcı, A., Eskizeybek, V., Gülce, H., Haspulat, B., Şahin, Ö. S., 2013, "ZnO–TiO2 nanocomposites formed under submerged DC arc discharge: preparation, characterization and photocatalytic properties", Applied Physics A, Cilt 116, ss. 1119-1125.
  • Bawazeer, T. M., Alsoufi, M. S., Shkir, M., Al-Shehri, B. M., Hamdy, M. S., 2021, "Excellent improvement in photocatalytic nature of ZnO nanoparticles via Fe doping content", Inorganic Chemistry Communications, Cilt 130, ss. 108668
  • Caglar, Y., Caglar, M., Ilican, S. , 2018, "XRD, SEM, XPS studies of Sb doped ZnO films and electrical properties of its based Schottky diodes", Optik, Cilt 164, ss. 424-432.
  • Canıyılmaz, E., Kutay, F., 2003, "Taguchi Metodunda Varyans Analizine Alternatif Bir Yaklaşım", Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, Cilt 18, ss. 51-63.
  • Chen, Z., Fang, Y., Wang, L., Chen, X., Lin, W., Wang, X., 2021, "Remarkable oxygen evolution by Co-doped ZnO nanorods and visible light", Applied Catalysis B: Environmental, Cilt 296, ss. 120369
  • Das, A., Patra, M., Kumar P, M., Bhagavathiachari, M., Nair, R. G., 2021, "Role of type II heterojunction in ZnO–In2O3 nanodiscs for enhanced visible-light photocatalysis through the synergy of effective charge carrier separation and charge transport", Materials Chemistry and Physics, Cilt 263, ss. 124431
  • Guzel Kaya, G., Yilmaz, E., Deveci, H., 2019, "A novel silica xerogel synthesized from volcanic tuff as an adsorbent for high‐efficient removal of methylene blue: parameter optimization using Taguchi experimental design", Journal of Chemical Technology & Biotechnology, Cilt 94, ss. 2729-2737.
  • Harpale, K., Kolhe, P., Bankar, P., Khare, R., Patil, S., Maiti, N., Chaskar, M. G., More, M. A., Sonawane, K. M., 2020, "Multifunctional characteristics of polypyrrole-zinc oxide (PPy-ZnO) nanocomposite: Field emission investigations and gas sensing application", Synthetic Metals, Cilt 269, ss. 116542
  • Haspulat, B., Çınar, Ö., Kamış, H., 2014, "Synthesis of Polypyrrole in Aqueous Diethylene Glycol Solution", Selcuk University Journal of Engineering ,Science and Technology, Cilt 2, ss. 01-01.
  • Haspulat Taymaz, B., Eskizeybek, V., Kamis, H., 2021a, "A novel polyaniline/NiO nanocomposite as a UV and visible-light photocatalyst for complete degradation of the model dyes and the real textile wastewater", Environ Sci Pollut Res Int, Cilt 28, ss. 6700-6718.
  • Haspulat Taymaz, B., Kamış, H., Yoldaş, Ö., 2021b, "Photocatalytic degradation of malachite green dye using zero valent iron doped polypyrrole", Environmental Engineering Research, Cilt 27, ss. 200638-200630.
  • Haspulat Taymaz, B., Taş, R., Kamış, H., Can, M., 2021c, "Photocatalytic activity of polyaniline and neutral polyaniline for degradation of methylene blue and malachite green dyes under UV Light", Polymer Bulletin, Cilt 78, ss. 2849-2865.
  • Huang, Z. D., Ma, R., Zhou, J., Wang, L., Xie, Q., 2021, "Investigation on microstructures, electronic structures, electromagnetic properties and microwave absorption properties of Fe3Si/PPy composites", Journal of Alloys and Compounds, Cilt 873, ss. 159779
  • Janani, B., Al-Kheraif, A. A., Thomas, A. M., Syed, A., Elgorban, A. M., Raju, L. L., Das, A., Khan, S. S., 2021, "Construction of nano-heterojunction AgFeO2–ZnO for boosted photocatalytic performance and its antibacterial applications", Materials Science in Semiconductor Processing, Cilt 133, ss. 105924
  • Joshi, N. C., Kaur, K., Kumar, N., Bhandari, N. S., Thakur, A., 2021, "Synthesis and adsorption applications of PPY/Fe3O4 nanocomposite based material", Nano-Structures & Nano-Objects, Cilt 25, ss. 100669.
  • Liu, Y., Zhang, Q., Yuan, H., Luo, K., Li, J., Hu, W., Pan, Z., Xu, M., Xu, S., Levchenko, I., Bazaka, K., 2021, "Comparative study of photocatalysis and gas sensing of ZnO/Ag nanocomposites synthesized by one- and two-step polymer-network gel processes". Journal of Alloys and Compounds, Cilt 868, ss. 158723
  • Nava Núñez, M. Y., Martínez-de la Cruz, A., 2018, "Nitric oxide removal by action of ZnO photocatalyst hydrothermally synthesized in presence of EDTA", Materials Science in Semiconductor Processing, Cilt 81, ss. 94-101.
  • Rabell, G. O., Cruz, M. R. A., Juárez-Ramírez, I., 2021, "Hydrogen production of ZnO and ZnO/Ag films by photocatalysis and photoelectrocatalysis", Materials Science in Semiconductor Processing, Cilt 134, ss. 105985
  • Roguai, S., Djelloul, A., 2021, "Structural, microstructural and photocatalytic degradation of methylene blue of zinc oxide and Fe-doped ZnO nanoparticles prepared by simple coprecipitation method", Solid State Communications, Cilt 334-335, ss. 114362
  • Yashni, G., Al-Gheethi, A., Radin Mohamed, R. M. S., Dai-Viet, N. V., Al-Kahtani, A. A., Al-Sahari, M., Nor Hazhar, N. J., Noman, E., Alkhadher, S., 2021, "Bio-inspired ZnO NPs synthesized from Citrus sinensis peels extract for Congo red removal from textile wastewater via photocatalysis: Optimization, mechanisms, techno-economic analysis", Chemosphere, Cilt 281, ss. 130661.

Optimization of Photocatalytic Activity of Visible Light Induced Ppy/ZnO@Fe Composite

Year 2021, Volume: 9 , 42 - 53, 30.12.2021
https://doi.org/10.36306/konjes.979621

Abstract

Nowadays, the increase in industrialization has brought many environmental problems. Discharge of synthetic organic dyes used in paper, leather, and cosmetics industries, especially in the textile industry; discharge wastewaters seriously threaten the environment. For this reason, wastewater from these sectors containing synthetic organic dyes must be treated before released into the environment. Today, photocatalytic wastewater treatment is one of the most preferred methods for the removal of organic dyes from the environment. In this study, polypyrrole/ZnO@Fe (Ppy/ZnO@Fe) nanocomposites were obtained by chemical oxidative polymerization method in the presence of pyrrole and ammonium peroxydisulphate by dispersing ZnO@Fe nanoparticles by ultrasonication in the polymerization medium. Structural, morphological, and spectroscopic properties of Ppy/ZnO@Fe composite were elucidated by SEM, XRD, FTIR, DSC and UV-vis absorption methods. Photocatalytic activity of Ppy/ZnO@Fe composite was investigated by photocatalytic removal of rhodamine B (RdB) dye under visible light. Photocatalytic activity of Ppy/ZnO@Fe composite was investigated by photocatalytic removal of rhodamine B (RdB) dye under visible light. The effect of the amount of photocatalyst, dye concentration, radiation time and pH of dye on the photocatalytic activity was optimized by the Taguchi method, which is one of the experimental design methods. After 60 min, the color of the RdB dye was 99% decolorized under visible light under Ppy/ZnO@Fe catalysis.

Project Number

202016061

References

  • Achehboune, M., Khenfouch, M., Boukhoubza, I., Leontie, L., Doroftei, C., Carlescu, A., Bulai, G., Mothudi, B., Zorkani, I., Jorio, A., 2021, "Microstructural, FTIR and Raman spectroscopic study of Rare earth doped ZnO nanostructures",Materials Today: Proceedings, doi.org/10.1016/j.matpr.2021.04.144
  • Avcı, A., Eskizeybek, V., Gülce, H., Haspulat, B., Şahin, Ö. S., 2013, "ZnO–TiO2 nanocomposites formed under submerged DC arc discharge: preparation, characterization and photocatalytic properties", Applied Physics A, Cilt 116, ss. 1119-1125.
  • Bawazeer, T. M., Alsoufi, M. S., Shkir, M., Al-Shehri, B. M., Hamdy, M. S., 2021, "Excellent improvement in photocatalytic nature of ZnO nanoparticles via Fe doping content", Inorganic Chemistry Communications, Cilt 130, ss. 108668
  • Caglar, Y., Caglar, M., Ilican, S. , 2018, "XRD, SEM, XPS studies of Sb doped ZnO films and electrical properties of its based Schottky diodes", Optik, Cilt 164, ss. 424-432.
  • Canıyılmaz, E., Kutay, F., 2003, "Taguchi Metodunda Varyans Analizine Alternatif Bir Yaklaşım", Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, Cilt 18, ss. 51-63.
  • Chen, Z., Fang, Y., Wang, L., Chen, X., Lin, W., Wang, X., 2021, "Remarkable oxygen evolution by Co-doped ZnO nanorods and visible light", Applied Catalysis B: Environmental, Cilt 296, ss. 120369
  • Das, A., Patra, M., Kumar P, M., Bhagavathiachari, M., Nair, R. G., 2021, "Role of type II heterojunction in ZnO–In2O3 nanodiscs for enhanced visible-light photocatalysis through the synergy of effective charge carrier separation and charge transport", Materials Chemistry and Physics, Cilt 263, ss. 124431
  • Guzel Kaya, G., Yilmaz, E., Deveci, H., 2019, "A novel silica xerogel synthesized from volcanic tuff as an adsorbent for high‐efficient removal of methylene blue: parameter optimization using Taguchi experimental design", Journal of Chemical Technology & Biotechnology, Cilt 94, ss. 2729-2737.
  • Harpale, K., Kolhe, P., Bankar, P., Khare, R., Patil, S., Maiti, N., Chaskar, M. G., More, M. A., Sonawane, K. M., 2020, "Multifunctional characteristics of polypyrrole-zinc oxide (PPy-ZnO) nanocomposite: Field emission investigations and gas sensing application", Synthetic Metals, Cilt 269, ss. 116542
  • Haspulat, B., Çınar, Ö., Kamış, H., 2014, "Synthesis of Polypyrrole in Aqueous Diethylene Glycol Solution", Selcuk University Journal of Engineering ,Science and Technology, Cilt 2, ss. 01-01.
  • Haspulat Taymaz, B., Eskizeybek, V., Kamis, H., 2021a, "A novel polyaniline/NiO nanocomposite as a UV and visible-light photocatalyst for complete degradation of the model dyes and the real textile wastewater", Environ Sci Pollut Res Int, Cilt 28, ss. 6700-6718.
  • Haspulat Taymaz, B., Kamış, H., Yoldaş, Ö., 2021b, "Photocatalytic degradation of malachite green dye using zero valent iron doped polypyrrole", Environmental Engineering Research, Cilt 27, ss. 200638-200630.
  • Haspulat Taymaz, B., Taş, R., Kamış, H., Can, M., 2021c, "Photocatalytic activity of polyaniline and neutral polyaniline for degradation of methylene blue and malachite green dyes under UV Light", Polymer Bulletin, Cilt 78, ss. 2849-2865.
  • Huang, Z. D., Ma, R., Zhou, J., Wang, L., Xie, Q., 2021, "Investigation on microstructures, electronic structures, electromagnetic properties and microwave absorption properties of Fe3Si/PPy composites", Journal of Alloys and Compounds, Cilt 873, ss. 159779
  • Janani, B., Al-Kheraif, A. A., Thomas, A. M., Syed, A., Elgorban, A. M., Raju, L. L., Das, A., Khan, S. S., 2021, "Construction of nano-heterojunction AgFeO2–ZnO for boosted photocatalytic performance and its antibacterial applications", Materials Science in Semiconductor Processing, Cilt 133, ss. 105924
  • Joshi, N. C., Kaur, K., Kumar, N., Bhandari, N. S., Thakur, A., 2021, "Synthesis and adsorption applications of PPY/Fe3O4 nanocomposite based material", Nano-Structures & Nano-Objects, Cilt 25, ss. 100669.
  • Liu, Y., Zhang, Q., Yuan, H., Luo, K., Li, J., Hu, W., Pan, Z., Xu, M., Xu, S., Levchenko, I., Bazaka, K., 2021, "Comparative study of photocatalysis and gas sensing of ZnO/Ag nanocomposites synthesized by one- and two-step polymer-network gel processes". Journal of Alloys and Compounds, Cilt 868, ss. 158723
  • Nava Núñez, M. Y., Martínez-de la Cruz, A., 2018, "Nitric oxide removal by action of ZnO photocatalyst hydrothermally synthesized in presence of EDTA", Materials Science in Semiconductor Processing, Cilt 81, ss. 94-101.
  • Rabell, G. O., Cruz, M. R. A., Juárez-Ramírez, I., 2021, "Hydrogen production of ZnO and ZnO/Ag films by photocatalysis and photoelectrocatalysis", Materials Science in Semiconductor Processing, Cilt 134, ss. 105985
  • Roguai, S., Djelloul, A., 2021, "Structural, microstructural and photocatalytic degradation of methylene blue of zinc oxide and Fe-doped ZnO nanoparticles prepared by simple coprecipitation method", Solid State Communications, Cilt 334-335, ss. 114362
  • Yashni, G., Al-Gheethi, A., Radin Mohamed, R. M. S., Dai-Viet, N. V., Al-Kahtani, A. A., Al-Sahari, M., Nor Hazhar, N. J., Noman, E., Alkhadher, S., 2021, "Bio-inspired ZnO NPs synthesized from Citrus sinensis peels extract for Congo red removal from textile wastewater via photocatalysis: Optimization, mechanisms, techno-economic analysis", Chemosphere, Cilt 281, ss. 130661.
There are 21 citations in total.

Details

Primary Language Turkish
Subjects Engineering
Journal Section Research Article
Authors

Bircan Haspulat-taymaz 0000-0002-5170-322X

Project Number 202016061
Publication Date December 30, 2021
Submission Date August 6, 2021
Acceptance Date October 31, 2021
Published in Issue Year 2021 Volume: 9

Cite

IEEE B. Haspulat-taymaz, “GÖRÜNÜR IŞIK İLE UYARILABİLEN Ppy/ZnO@Fe KOMPOZİTİNİN FOTOKATALİTİK AKTİVİTESİNİN OPTİMİZASYONU”, KONJES, vol. 9, pp. 42–53, 2021, doi: 10.36306/konjes.979621.