EFFECTIVE POLYMER DECORATION ON NICKEL-IMINE COMPLEX TO ENHANCE CATALYTIC HYDROGEN EVOLUTION

Year 2024, Volume: 12 Issue: 1, 37 - 52, 01.03.2024

Dilek Kılınç , Ömer Şahin

https://doi.org/10.36306/konjes.1382125

Abstract

Since fossil fuels are rapidly depleting, finding alternative energy sources is becoming increasingly important. Among these alternatives, hydrogen (H2) is the most viable option. In hydrogen evolution systems, supported metal catalysts enhance the catalytic activity in the hydrolysis reaction by increasing the surface area. Therefore, this research focuses on preparing three different polymer-decorated Nickel-Imine complex catalysts (Ni@EC, Ni@EC-250, Ni@ECM) to improve their efficiency. To achieve the catalysts, a Nickel-Imine complex [1] was supported on three different polymers (EC, EC-250, and ECM). The catalysts (Ni@EC, Ni@EC-250, Ni@ECM) were then utilized to generate hydrogen from NaBH4 hydrolysis. The hydrogen evolution rates for Ni@EC, Ni@EC-250, and Ni@ECM catalysts were found as 6879; 15576; 8830 and 15459; 28689; 23417 mL H2 gcat-1.min-1, respectively at 30 oC and 50 oC. Results indicate that the Ni@EC-250 catalyst exhibited the best activity. Consequently, the subsequent steps of the catalytic hydrolysis reaction were studied using Ni@EC-250. The activation energy of the Ni@EC-250 catalyst was estimated at 39.255 kJ.mol-1. The reusability tests demonstrate that Ni@EC-250 remains active in sodium borohydride hydrolysis even after five runs. Technical abbreviations are defined upon first use. This study elucidates the reaction mechanism and kinetic data of catalytic sodium borohydride hydrolysis at various temperatures.

Keywords

Catalyst, Hydrogen evolution, NaBH4, Ni-Imine, Polymer

References

• D. Kılınç, O. Sahin, C. Saka, ‘’Investigation on salicylaldimine-Ni complex catalyst as an alternative to increasing the performance of catalytic hydrolysis of sodium borohydride,’’ International Journal of Hydrogen Energy, vol. 42, pp. 20625-20637, 2017.
• S. Santra, D. Das, N.S. Das, K.K. Nanda, ‘‘An efficient on-board metal-free nanocatalyst for controlled room temperature hydrogen production, ’’ Chemical Science, vol. 8, pp.2994-3001, 2017.
• L. Semiz, N. Abdullayeva, M. Sankir, ‘’Nanoporous Pt and Ru catalysts by chemical dealloying of Pt-Al and Ru-Al alloys for ultrafast hydrogen generation,’’ Journal of Alloys Compounds, vol. 744, pp. 110-115, 2018.
• M.Z. Jacobson, W.G. Colella, D.M. Golden, ‘’Cleaning the air and improving health with hydrogen fuel-cell vehicles,’’ Science, vol. 308, pp. 1901-1905, 2005.
• D. Huang, P. Zhao, F. Fu, J. Wie, X. Yang, D. Astruc, C. Wang, J. Zhu, C. Luo, ‘’Highly efficient and selective Co@ZIF-8 nanocatalyst for hydrogen release from sodium borohydride hydrolysis, ChemCatChem,’’ vol. 11, pp. 1643-1649, 2019.
• M. Sankir, L. Semiz, R.B. Serin, N.D. Sankir, ‘‘Hydrogen generation from nanoflower platinum films, ‘‘International Journal of Hydrogen Energy, vol. 40, pp. 8522–8529, 2015.
• S.C. Li, F.C. Wang, ‘‘The development of a sodium borohydride hydrogen generation system for proton exchange membrane fuel cell, ’’ International Journal of Hydrogen Energy, vol. 41, pp. 3038–3051, 2016.
• M. Sankir, R.B. Serin, L. Semiz, N.D. Sankir, ‘‘Unusual behavior of dynamic hydrogen generation from sodium borohydride, ’’ International Journal of Hydrogen Energy, vol. 39, pp. 2608–2613, 2014.
• F. Ali, S.B. Khan, A.M. Asiri, ‘’Chitosan coated cellulose cotton fibers as catalyst for the H2 production from NaBH4 methanolysis,’’ International Journal of Hydrogen Energy, vol. 44, pp. 4143–4155, 2014.
• C. Huff, T. Dushatinski, T.M. Abdel-Fattah, ‘’Gold nanoparticle/multi-walled carbon nanotube composite as novel catalyst for hydrogen evolution reactions,’’ International Journal of Hydrogen Energy, vol. 42, pp. 18985–18990, 2017.
• D. Kılınç, ‘’Effect of Al2O3-supported Cu-Schiff base complex as a catalyst for hydrogen generation in NaBH4 hydrolysis,’’ Energy Sources Part A-Recovery Utilization and Environmental Effects, vol. 40, pp. 873-885, 2018.
• E. Fangaj, A.A. Ceyhan, ‘’Apricot Kernel shell waste treated with phosphoric acid used as a green, metal-free catalyst for hydrogen generation from hydrolysis of sodium borohydride,’’ International Journal of Hydrogen Energy, vol. 45, pp. 17104-17117, 2020.
• D. Kılınc, O. Sahin, ‘’Effective TiO2 supported Cu-Complex catalyst in NaBH4 hydrolysis reaction to hydrogen generation, ‘’ International Journal of Hydrogen Energy, vol. 44: pp. 18858-18865, 2019.
• O. Akdim, U.B. Demirci, D. Muller, P. Miele, ‘’Cobalt (II) salts, performing materials for generating hydrogen from sodium borohydride,’’ International Journal of Hydrogen Energy, vol. 34, pp. 2631-7, 2019.
• J. Andrieux, D. Swierczynski, L. Laversenne, A. Garron, S. Bennici, C. Goutaudier, et al., ‘’Amultifactor study of catalyzed hydrolysis of solid NaBH4 on cobalt nanoparticles: thermodynamics and kinetics,’’ International Journal of Hydrogen Energy, vol. 34, pp. 938-51, 2019.
• O. Akdim, U.B. Demirci, P. Miele, ‘’Acetic acid, a relatively green single-use catalyst for hydrogen generation from sodium borohydride,’’ International Journal of Hydrogen Energy, vol. 34, pp. 7231-8, 2009.
• Y. Kojima, K.I. Suzuki, K. Fukumoto, M. Sasaki, T. Yamamoto, Y. Kawai, et al., ‘’Hydrogen generation using sodium borohydride solution and metal catalyst coated on metal oxide,’’ International Journal of Hydrogen Energy, vol. 27, pp. 1029-34, 2002.
• D. Xu, X. Lai, W. Guo, X. Zhang, C. Wang, P. Dai, ‘’Efficient catalytic properties of SO42- / MxOy (M = Cu, Co, Fe) catalysts for hydrogen generation by methanolysis of sodium borohydride,’’ International Journal of Hydrogen Energy, vol. 43, pp. 6594-6602, 2018.
• X. Zhang, X. Sun, D. Xu, X. Tao, P. Dai, Q. Guo, X. Liu, ‘’ Synthesis of MOF-derived Co@C composites and application for efficient hydrolysis of sodium borohydride, Applied Surface Science, vol. 469, pp. 764-769, 2019.
• D. Kılınç, Ö. Şahin, ‘’Ruthenium-Imine Catalyzed KBH4 Hydrolysis as an Efficient Hydrogen Production System, International Journal of Hydrogen Energy, vol. 46, pp. 20984-20994, 2021.
• D. Kılınç, O. Sahin ‘’Highly active and stable CeO2 supported nickel complex catalyst in hydrogen generation,’’ International Journal of Hydrogen Energy, vol. 46, pp. 499-507, 2022.
• J. Lee, H. Shin, K.S. Choi, J. Lee, J.Y. Choi, H.K. Yu, ‘’Carbon layer supported nickel catalyst for sodium borohydride (NaBH4) dehydrogenation,’’ International Journal of Hydrogen Energy, vol. 44 pp. 2943-2950, 2019.
• A.A. Ceyhan, S. Edebali, E. Fangaj, ‘’A study on hydrogen generation from NaBH4 solution using Co-loaded resin catalysts,’’ International Journal of Hydrogen Energy, vol. 45, pp. 45:34761-34772,2020.
• A. Pozio, M. De Francesco, G. Monteleone, R. Oronzio, S. Galli, C. D’Angelo, et al., ‘’Apparatus for the production of hydrogen from sodium borohydride in alkaline solution,’’ International Journal of Hydrogen Energy, vol. 33, pp. 51-56, 2008.
• N. Patel, R. Fernandes, N. Bazzanella, A. Miotello, ‘’Co-P-B catalyst thin films prepared by electroless and pulsed laser deposition for hydrogen generation by hydrolysis of alkaline sodium borohydride: a comparison,’’ Thin Solid Films, vol. 518, pp. 4779-4785, 2010.
• S.C. Amendola, S.L. Sharp-Goldman, M. Saleem Janjua, N.C. Spencer, M.T. Kelly, P.J. Petillo, et al., ‘’A safe, portable, hydrogen gas generator using aqueous borohydride solution and Ru catalyst,’’ International Journal of Hydrogen Energy vol. 25, pp. 969-75, 2010.
• J.P. Holgado, J. Morales, A. Caballero, A.R. Gonza´ lez-Elipe, ‘’Plate reactor for testing catalysts in the form of thin films,’’ Applied Catalysis B: Environment and Energy, vol. 31, pp. 31-36,2001.
• N. Malvadkar, S. Park, ‘’Urquidi-MacDonald M, Wang H, Demirel MC. Catalytic activity of cobalt deposited on nanostructured poly(p-xylylene) films,’’ Journal of Power Source, vol. 182, pp. 323-8, 2008.
• D. Kılınc, ‘’Co complex modified on Eupergit C as a highly active catalyst for enhanced hydrogen production,’’ International Journal of Hydrogen Energy, vol. 47, pp. 11894-11903, 2022.
• D. Kılınc, O. Sahin, C. Saka, ‘’Salicylaldimine-Ni complex supported on Al2O3: Highly efficient catalyst for hydrogen production from hydrolysis of sodium borohydride,’’ International Journal of Hydrogen Energy, vol. 43, pp. 251-261, 2018.
• D. Kılınç, Ö. Şahin, ‘’Synthesis of polymer supported Ni (II)-Schiff Base complex and its usage as a catalyst in sodium borohydride hydrolysis,’’ International Journal of Hydrogen Energy, vol. 43, pp. 10717-10727, 2018.
• G.P. Rachiero, U.B. Demirci, P. Miele, ‘'Bimetallic RuCo and RuCu catalysts supported on ɣ-Al2O3. A comparative study of their activity in hydrolysis ofammonia-borane,’’ International Journal of Hydrogen Energy, vol. 36, pp. 7051-7065, 2011.
• J.Q. Wu, D.L. Wang, X.M. Xu, N.B. Long, R.F. Zhang, ‘’Efficient synthesis of DHA/EPA-rich phosphatidylcholine by inhibition of hydrolysis reaction using immobilized phospholipase A1 on macroporous SiO2/cationic polymer nano-composited support,’’ Molecular Catalysis, vol. 499, pp. 111278, 2021.
• M. Grigoras, C.O. Catanescu, ‘’Imine oligomers and polymer,’’ Journal of Macromolecular Science, Part C: Polymer Reviews, vol. 44, pp. 131-173, 2004.
• D. Kılınç, O. Sahin, S. Horoz, ‘’Use of low-cost Zn (II) complex efficiently in a dye-sensitized solar cell device, ‘’ Journal of Materials Science: Materials in Electronics, vol. 30, pp. 11464-11467, 2019.
• A. Xavier, N. Srividhya, ‘’Synthesis and study of Schiff base ligands,’’ Journal of Applied Chemistry, vol. 7, pp. 6-15, 2014.
• M.S. Karthikeyan, D.J. Prasad, B. Poojary, K.S. Bhat, B.S. Holla, N.S. Kumari, ‘’Synthesis and biological activity of Schiff and Mannich bases bearing 2, 4-dichloro-5-fluorophenyl moiety,’’ Bioorganic & Medicinal Chemistry, vol.14, pp. 7482-7489, 2006.
• D. Kılınç, O. Sahin ‘’High volume hydrogen evolution from KBH4 hydrolysis with palladium complex catalyst,’’ Renewable Energy, vol. 161, pp. 257-264, 2019.
• D. Kılınç, O. Sahin ‘’Development of highly efficient and reusable Ruthenium complex catalyst for hydrogen evolution,’’ International Journal of Hydrogen Energy, vol. 47, pp. 3876-3885, 2022.
• K. Nejati, Z. Rezvani, ‘’Syntheses, characterization and mesomorphic properties of new bis(alkoxyphenylazo)- substituted N, N’ salicylidene diiminato Ni (II), Cu (II) and VO(IV) complexes,’’ New J Chem, vol. 27, pp. 1665, 2003.
• K. Naresh Kumar K, R. Ramesh, ‘’Synthesis, luminescent, redox and catalytic properties of Ru (II) carbonyl complexes containing 2N2O donors, ’’Polyhedron, vol. 24, pp. 1885-92, 2005.
• T. Rosu, E. Pahontu, C. Maxim, R. Georgescu, N. Stanica, A. Gulea, ‘’Some new Cu (II) complexes containing an on-donor Schiff base: synthesis, characterization and antibacterial activity, ’’Polyhedron, vol. 30, pp. 154-62, 2011.
• M.R.P. Kurup, B. Varghese, M. Sithambaresan, S. Krishnan, S.R. Sheeja, E. Suresh, ‘’Synthesis, spectral characterization and crystal structure of copper (II) complexes of 2- benzoyl pyridine-N (4)-phenyl semicarbazone,’’ Polyhedron, vol.30, pp. 70-8, 2011.