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Year 2025, Volume: 13 Issue: 3, 793 - 809, 01.09.2025
https://doi.org/10.36306/konjes.1642332

Abstract

References

  • D. Stefanescu, J. Davis, and J. Destefani, "Metals Handbook, Vol. 15--Casting," ASM International, 1988, p. 937, 1988.
  • H. Morrogh and W. Williams, "Graphite formation in gray cast iron," Proc Inst Br Foundry, vol. 40, pp. 47-63, 1946.
  • E. Karadeniz, M. Çolak, and F. Barutçu, " Investigation of Impact of Amount and Type of Inoculants on Microstructure and Mechanical Properties Of GGG60 Spheroidal Graphite Cast Irons," Omer Halisdemir University Journal of Engineering Sciences, vol. 6, no. 1, pp. 275-282, 2017.
  • C. Ecob and C. Hartung, "An alternative route for the production of compacted graphite Irons," Indian Foundry Journal, vol. 49, no. 6, pp. 25-33, 2003.
  • H. Fredriksson, J. Stjerndahl, and J. Tinoco, "On the solidification of nodular cast iron and its relation to the expansion and contraction," Materials Science and Engineering A-Structure, vol. 413, pp. 363-372, 2005.
  • A. Pribulová, P. Futaš, and M. Pokusova, "Influence of charge composition on EN-GJS-500-7 ductile iron properties in foundry operating conditions," Materials Science Forum, vol. 998, pp. 42-47, 2020.
  • Z. Veljačić and K. Grilec, "Increasing the Wear Resistance of Marine Diesel Engines Elements Made of Ductile Iron," NAŠE MORE: znanstveni časopis za more i pomorstvo, vol. 68, no. 3, pp. 150-156, 2021.
  • H. Pacha-Gołębiowska and W. Piekarska, "Mechanical properties of ductile cast iron relation to the charge elements," in IOP Conference Series: Materials Science and Engineering, 2021, vol. 1199, no. 1: IOP Publishing, p. 012022.
  • W. Stets, H. Löblich, G. Gassner, and P. Schumacher, "Solution strengthened ferritic ductile cast iron properties, production and application," International Journal of Metalcasting, vol. 8, pp. 35-40, 2014.
  • R. M. Gouveia et al., "Comparing the structure and mechanical properties of welds on ductile cast iron (700 MPa) under different heat treatment conditions," Metals, vol. 8, no. 1, p. 72, 2018.
  • R. A. Jeshvaghani, M. Shamanian, and M. Jaberzadeh, "Enhancement of wear resistance of ductile iron surface alloyed by stellite 6," Mater Design, vol. 32, no. 4, pp. 2028-2033, 2011.
  • F. Iacoviello and V. Di Cocco, "Influence of the graphite elements morphology on the fatigue crack propagation mechanisms in a ferritic ductile cast iron," Engineering Fracture Mechanics, vol. 167, pp. 248-258, 2016.
  • H. Sübütay, M. Şimşir, M. Aydın, and B. Karaca, "Effect of chill formation on the mechanical properties and microstructure of grey and nodular cast irons used in automotive industry," Pamukkale University Journal of Engineering Sciences, vol. 22, no. 1, pp. 1-7, 2016.
  • Y. Aşkun, H. Hasirci, and U. Şeker, "Evaluation of Machinability of Ductile Irons Alloyed With Ni And Cu in Terms of Cutting Forces and Surface Quality," Pamukkale University Journal of Engineering Sciences, vol. 9, no. 2, pp. 191-199.
  • J. Feng, X. Du, Y. Sun, K. Zhao, Z. Shi, and M. Liu, "Effect of La–O–S complex inoculant on microstructure and mechanical characteristics of ductile iron," Journal of Materials Science, vol. 57, no. 8, pp. 5288-5297, 2022.
  • A. C. Melado, A. S. Nishikawa, H. Goldenstein, M. A. Giles, and P. A. Reed, "Effect of microstructure on fatigue behaviour of advanced high strength ductile cast iron produced by quenching and partitioning process," International Journal of Fatigue, vol. 104, pp. 397-407, 2017.
  • T. Borsato, P. Ferro, F. Berto, and C. Carollo, "Fatigue strength improvement of heavy-section pearlitic ductile iron castings by in-mould inoculation treatment," International Journal of Fatigue, vol. 102, pp. 221-227, 2017.
  • I. Boulifa and A. Hadji, "Study of the influence of alloying elements on the mechanical characteristics and wear behavior of a ductile cast iron," Fracture and Structural Integrity, vol. 15, no. 56, pp. 74-83, 2021.
  • M. Koch and K. Soulas, "Inoculation of grey and ductile iron," in 7th International Ankiros Foundry Congress, 2014, Istanbul, Turkey.
  • J. Pearce, "Inoculation of cast irons: Practices and developments," Foundry Trade Journal, vol. 181, no. 3651, pp. 28-31, 2008.
  • S. O. Olsen, T. Skaland, and C. Hartung, "Inoculation of grey and ductile iron a comparison of nucleation sites and some practical advises," in 66th World Foundry Congress, 2004, pp. 891-902.
  • A. Badmos and K. Fakehinde, "Multiple inoculations of ductile iron and the effects on properties," International Journal of Engineering & Technology, vol. 4, no. 4, pp. 526-530, 2015.
  • V. Shinde, B. Ravi, and K. Narasimhan, "Solidification behaviour and mechanical properties of ductile iron castings with varying thickness," International Journal of Cast Metals Research, vol. 25, no. 6, pp. 364-373, 2012.
  • F. Bonollo and A. Tiziani, "La solidificazione delle ghise," A cura di Franco Bonollo, p. 21, 2000.
  • L. Ceschini, A. Morri, A. Morri, E Salsi, R Squatrito, I Todaro, L Tomesan, "Microstructure and mechanical properties of heavy section ductile iron castings: experimental and numerical evaluation of effects of cooling rates," International Journal of Cast Metals Research, vol. 28, no. 6, pp. 365-374, 2015.
  • H. Megahed, E. El-Kashif, A. Y. Shash, and M. A. Essam, "Effect of holding time, thickness and heat treatment on microstructure and mechanical properties of compacted graphite cast iron," Journal of Materials Research and Technology, vol. 8, no. 1, pp. 1188-1196, 2019.
  • L. Ceschini et al., "Process modeling, microstructure prediction and mechanical properties of sand cast ductile iron castings," Metallurgia Italiana, no. 1, pp. 2-11, 2013.
  • M. Tonkovič Prijanovič, P. Mrvar, J. Burja, Č. Donik, and M. Petrič, "Study on Dissolution of Ba-Containing Inoculant in Ductile Cast Iron Melt and Nucleation of Graphite," International Journal of Metalcasting, vol. 18, no. 4, pp. 2985-2995, 2024.
  • R. Elliott, Cast iron Technology. Butteworths, 1988.
  • H. Nguyen, "Manufacturing processes and engineering materials used in automotive engine blocks," Materials Science and Engineering Section B, EGR250, p. 1, 2005.
  • D. S. Dawson, "Compacted graphite Iron: mechanical and physical properties for engine design, based on a paper presented at: werkstoff und automobilantrieb (Materials in Powertrain VDI (Verein Deutscher Ingenieure)," Dresden Germany: 1999 (10): 28-29, 1999.
  • G. F. Sergeant and E. R. Evans, "Production And Properties Of Compacted Graphite Irons," Br Foundryman, Article vol. 71, no. pt 5, pp. 115-124, 1978.
  • A. Visnapuu, B. Betts, and L. Neumeier, "Influence of graphite morphology on the damping properties of selected cast iron structures," Rolla Research Centre, Bureau of Mines, US Dept of Interior, Rolla, Mo, vol. 65401, 1977.
  • N. J. Petch, "The cleavage strength of polycrystals," Journal of Iron Steel Institute, vol. 174, pp. 25-28, 1953.
  • E. Guzel, C. Yuksel, Y. Bayrak, O. Sen, and A. Ekerim, "Effect of Section Thickness on the Microstructure and Hardness of Ductile Cast Iron," Materials Testing, vol. 56, no. 4, pp. 285-288, 2014, doi: doi:10.3139/120.110558.
  • Ç. Yüksel, "Microstructural analysis of EN-GJS-450-10 ductile cast iron via vibrational casting," China Foundry, vol. 17, no. 4, pp. 272-278, 2020.
  • B. Bauer, I. Mihalic Pokopec, M. Petrič, and P. Mrvar, "Effect of cooling rate on graphite morphology and mechanical properties in high-silicon ductile iron castings," International Journal of Metalcasting, vol. 14, pp. 809-815, 2020.
  • Spheroidal graphite cast irons, DIN EN, 2012.
  • A. Keleş, R. Cengız, and M. Yildirim, "Effect of Alloying Elements and Technological Parameters of Austempering on the Structure and Mechanical Properties of Ductile Cast Iron (ADI)," Metal Science and Heat Treatment, vol. 65, no. 3, pp. 191-199, 2023.
  • C. Hartung, R. Logan, A. Plowman, D. Wilkinson, E. G. Hoel, and E. Ott, "Research on Solution Strengthened Ferritic Ductile Iron (SSFDI) Structure and Properties Using Different Treatment and Inoculation Materials," International Journal of Metalcasting, vol. 14, no. 4, pp. 1195-1209, 2020.
  • T. Borsato, P. Ferro, A. Fabrizi, F. Berto, and C. Carollo, "Long solidification time effect on solution strengthened ferritic ductile iron fatigue properties," International Journal of Fatigue, vol. 145, p. 106137, 2021.
  • J. M. Borrajo, R. A. Martinez, R. E. Boeri, and J. A. Sikora, "Shape and count of free graphite particles in thin wall ductile iron castings," ISIJ international, vol. 42, no. 3, pp. 257-263, 2002.
  • E. F. Products. "Graphite Structures in Cast Iron." ELKEM.

COMBINED EFFECT OF INOCULANT TYPE AND SECTION THICKNESS ON THE MICROSTRUCTURAL AND MECHANICAL PROPERTIES OF EN-GJS-600-3 GRADE DUCTILE CAST IRON

Year 2025, Volume: 13 Issue: 3, 793 - 809, 01.09.2025
https://doi.org/10.36306/konjes.1642332

Abstract

This study aims to investigate the combined effects of inoculant type (Ba- or La-containing) and section thickness (5, 15, 25, 35 and 50 mm) on the microstructural features (amount of ferrite and pearlite, the nodule count and the nodularity) and the mechanical properties (hardness, elongation, yield and tensile strength) of EN-GJS-600-3 grade DI. La-inoculated specimens exhibited lower nodule count, lower nodularity and approximately 1.1 times higher pearlite amount for all section thicknesses compared to Ba-inoculated specimens. The relatively higher pearlite content in La-inoculated specimens} resulted in improved mechanical properties (higher hardness values and approximately 1.1–1.2 times higher tensile strength). As section thickness increases, the amount of pearlite decreases (12–15%), the amount of ferrite increases (12–15%), the nodule count decreases and the nodularity increases. These results can directly be attributed to the decreasing cooling rate as section thickness increases.

Ethical Statement

Both authors declare that the present paper is prepared in accordance with ethical standards

Supporting Institution

No financial support is available

References

  • D. Stefanescu, J. Davis, and J. Destefani, "Metals Handbook, Vol. 15--Casting," ASM International, 1988, p. 937, 1988.
  • H. Morrogh and W. Williams, "Graphite formation in gray cast iron," Proc Inst Br Foundry, vol. 40, pp. 47-63, 1946.
  • E. Karadeniz, M. Çolak, and F. Barutçu, " Investigation of Impact of Amount and Type of Inoculants on Microstructure and Mechanical Properties Of GGG60 Spheroidal Graphite Cast Irons," Omer Halisdemir University Journal of Engineering Sciences, vol. 6, no. 1, pp. 275-282, 2017.
  • C. Ecob and C. Hartung, "An alternative route for the production of compacted graphite Irons," Indian Foundry Journal, vol. 49, no. 6, pp. 25-33, 2003.
  • H. Fredriksson, J. Stjerndahl, and J. Tinoco, "On the solidification of nodular cast iron and its relation to the expansion and contraction," Materials Science and Engineering A-Structure, vol. 413, pp. 363-372, 2005.
  • A. Pribulová, P. Futaš, and M. Pokusova, "Influence of charge composition on EN-GJS-500-7 ductile iron properties in foundry operating conditions," Materials Science Forum, vol. 998, pp. 42-47, 2020.
  • Z. Veljačić and K. Grilec, "Increasing the Wear Resistance of Marine Diesel Engines Elements Made of Ductile Iron," NAŠE MORE: znanstveni časopis za more i pomorstvo, vol. 68, no. 3, pp. 150-156, 2021.
  • H. Pacha-Gołębiowska and W. Piekarska, "Mechanical properties of ductile cast iron relation to the charge elements," in IOP Conference Series: Materials Science and Engineering, 2021, vol. 1199, no. 1: IOP Publishing, p. 012022.
  • W. Stets, H. Löblich, G. Gassner, and P. Schumacher, "Solution strengthened ferritic ductile cast iron properties, production and application," International Journal of Metalcasting, vol. 8, pp. 35-40, 2014.
  • R. M. Gouveia et al., "Comparing the structure and mechanical properties of welds on ductile cast iron (700 MPa) under different heat treatment conditions," Metals, vol. 8, no. 1, p. 72, 2018.
  • R. A. Jeshvaghani, M. Shamanian, and M. Jaberzadeh, "Enhancement of wear resistance of ductile iron surface alloyed by stellite 6," Mater Design, vol. 32, no. 4, pp. 2028-2033, 2011.
  • F. Iacoviello and V. Di Cocco, "Influence of the graphite elements morphology on the fatigue crack propagation mechanisms in a ferritic ductile cast iron," Engineering Fracture Mechanics, vol. 167, pp. 248-258, 2016.
  • H. Sübütay, M. Şimşir, M. Aydın, and B. Karaca, "Effect of chill formation on the mechanical properties and microstructure of grey and nodular cast irons used in automotive industry," Pamukkale University Journal of Engineering Sciences, vol. 22, no. 1, pp. 1-7, 2016.
  • Y. Aşkun, H. Hasirci, and U. Şeker, "Evaluation of Machinability of Ductile Irons Alloyed With Ni And Cu in Terms of Cutting Forces and Surface Quality," Pamukkale University Journal of Engineering Sciences, vol. 9, no. 2, pp. 191-199.
  • J. Feng, X. Du, Y. Sun, K. Zhao, Z. Shi, and M. Liu, "Effect of La–O–S complex inoculant on microstructure and mechanical characteristics of ductile iron," Journal of Materials Science, vol. 57, no. 8, pp. 5288-5297, 2022.
  • A. C. Melado, A. S. Nishikawa, H. Goldenstein, M. A. Giles, and P. A. Reed, "Effect of microstructure on fatigue behaviour of advanced high strength ductile cast iron produced by quenching and partitioning process," International Journal of Fatigue, vol. 104, pp. 397-407, 2017.
  • T. Borsato, P. Ferro, F. Berto, and C. Carollo, "Fatigue strength improvement of heavy-section pearlitic ductile iron castings by in-mould inoculation treatment," International Journal of Fatigue, vol. 102, pp. 221-227, 2017.
  • I. Boulifa and A. Hadji, "Study of the influence of alloying elements on the mechanical characteristics and wear behavior of a ductile cast iron," Fracture and Structural Integrity, vol. 15, no. 56, pp. 74-83, 2021.
  • M. Koch and K. Soulas, "Inoculation of grey and ductile iron," in 7th International Ankiros Foundry Congress, 2014, Istanbul, Turkey.
  • J. Pearce, "Inoculation of cast irons: Practices and developments," Foundry Trade Journal, vol. 181, no. 3651, pp. 28-31, 2008.
  • S. O. Olsen, T. Skaland, and C. Hartung, "Inoculation of grey and ductile iron a comparison of nucleation sites and some practical advises," in 66th World Foundry Congress, 2004, pp. 891-902.
  • A. Badmos and K. Fakehinde, "Multiple inoculations of ductile iron and the effects on properties," International Journal of Engineering & Technology, vol. 4, no. 4, pp. 526-530, 2015.
  • V. Shinde, B. Ravi, and K. Narasimhan, "Solidification behaviour and mechanical properties of ductile iron castings with varying thickness," International Journal of Cast Metals Research, vol. 25, no. 6, pp. 364-373, 2012.
  • F. Bonollo and A. Tiziani, "La solidificazione delle ghise," A cura di Franco Bonollo, p. 21, 2000.
  • L. Ceschini, A. Morri, A. Morri, E Salsi, R Squatrito, I Todaro, L Tomesan, "Microstructure and mechanical properties of heavy section ductile iron castings: experimental and numerical evaluation of effects of cooling rates," International Journal of Cast Metals Research, vol. 28, no. 6, pp. 365-374, 2015.
  • H. Megahed, E. El-Kashif, A. Y. Shash, and M. A. Essam, "Effect of holding time, thickness and heat treatment on microstructure and mechanical properties of compacted graphite cast iron," Journal of Materials Research and Technology, vol. 8, no. 1, pp. 1188-1196, 2019.
  • L. Ceschini et al., "Process modeling, microstructure prediction and mechanical properties of sand cast ductile iron castings," Metallurgia Italiana, no. 1, pp. 2-11, 2013.
  • M. Tonkovič Prijanovič, P. Mrvar, J. Burja, Č. Donik, and M. Petrič, "Study on Dissolution of Ba-Containing Inoculant in Ductile Cast Iron Melt and Nucleation of Graphite," International Journal of Metalcasting, vol. 18, no. 4, pp. 2985-2995, 2024.
  • R. Elliott, Cast iron Technology. Butteworths, 1988.
  • H. Nguyen, "Manufacturing processes and engineering materials used in automotive engine blocks," Materials Science and Engineering Section B, EGR250, p. 1, 2005.
  • D. S. Dawson, "Compacted graphite Iron: mechanical and physical properties for engine design, based on a paper presented at: werkstoff und automobilantrieb (Materials in Powertrain VDI (Verein Deutscher Ingenieure)," Dresden Germany: 1999 (10): 28-29, 1999.
  • G. F. Sergeant and E. R. Evans, "Production And Properties Of Compacted Graphite Irons," Br Foundryman, Article vol. 71, no. pt 5, pp. 115-124, 1978.
  • A. Visnapuu, B. Betts, and L. Neumeier, "Influence of graphite morphology on the damping properties of selected cast iron structures," Rolla Research Centre, Bureau of Mines, US Dept of Interior, Rolla, Mo, vol. 65401, 1977.
  • N. J. Petch, "The cleavage strength of polycrystals," Journal of Iron Steel Institute, vol. 174, pp. 25-28, 1953.
  • E. Guzel, C. Yuksel, Y. Bayrak, O. Sen, and A. Ekerim, "Effect of Section Thickness on the Microstructure and Hardness of Ductile Cast Iron," Materials Testing, vol. 56, no. 4, pp. 285-288, 2014, doi: doi:10.3139/120.110558.
  • Ç. Yüksel, "Microstructural analysis of EN-GJS-450-10 ductile cast iron via vibrational casting," China Foundry, vol. 17, no. 4, pp. 272-278, 2020.
  • B. Bauer, I. Mihalic Pokopec, M. Petrič, and P. Mrvar, "Effect of cooling rate on graphite morphology and mechanical properties in high-silicon ductile iron castings," International Journal of Metalcasting, vol. 14, pp. 809-815, 2020.
  • Spheroidal graphite cast irons, DIN EN, 2012.
  • A. Keleş, R. Cengız, and M. Yildirim, "Effect of Alloying Elements and Technological Parameters of Austempering on the Structure and Mechanical Properties of Ductile Cast Iron (ADI)," Metal Science and Heat Treatment, vol. 65, no. 3, pp. 191-199, 2023.
  • C. Hartung, R. Logan, A. Plowman, D. Wilkinson, E. G. Hoel, and E. Ott, "Research on Solution Strengthened Ferritic Ductile Iron (SSFDI) Structure and Properties Using Different Treatment and Inoculation Materials," International Journal of Metalcasting, vol. 14, no. 4, pp. 1195-1209, 2020.
  • T. Borsato, P. Ferro, A. Fabrizi, F. Berto, and C. Carollo, "Long solidification time effect on solution strengthened ferritic ductile iron fatigue properties," International Journal of Fatigue, vol. 145, p. 106137, 2021.
  • J. M. Borrajo, R. A. Martinez, R. E. Boeri, and J. A. Sikora, "Shape and count of free graphite particles in thin wall ductile iron castings," ISIJ international, vol. 42, no. 3, pp. 257-263, 2002.
  • E. F. Products. "Graphite Structures in Cast Iron." ELKEM.
There are 43 citations in total.

Details

Primary Language English
Subjects Metals and Alloy Materials
Journal Section Research Article
Authors

Mehmet Yıldırım 0000-0003-4768-4537

Mustafa Çekici 0000-0002-2568-4176

Publication Date September 1, 2025
Submission Date February 20, 2025
Acceptance Date June 23, 2025
Published in Issue Year 2025 Volume: 13 Issue: 3

Cite

IEEE M. Yıldırım and M. Çekici, “COMBINED EFFECT OF INOCULANT TYPE AND SECTION THICKNESS ON THE MICROSTRUCTURAL AND MECHANICAL PROPERTIES OF EN-GJS-600-3 GRADE DUCTILE CAST IRON”, KONJES, vol. 13, no. 3, pp. 793–809, 2025, doi: 10.36306/konjes.1642332.