Çölyak Hastaları İçin Üretilen Glutensiz Atıştırmalıkların Eser Element İçeriği ve Antioksidan Kapasitesi

Year 2017, Volume: 21 Issue: 3, 598 - 602, 23.06.2017

Görkem Yalçın

https://doi.org/10.12991/marupj.323284

Abstract

Bu çalışmada farklı glütensiz atıştırmalıkların eser element

seviyeleri ve antioksidan kapasiteleri araştırıldı. Örnekler

mikrodalga sistem kullanılarak çözünürleştirildi. Na,

Mg, K, Ca, Fe, Zn, Cu ve Mn düzeyleri indüktif eşleşmiş

plazma kütle spektrometresi ile saptandı. Antioksidan

kapasiteyi belirlemek için bakır indirgeme antioksidan

kapasite ve 2,2-difenil-1-pikrilhidrazil radikali süpürme

kapasitesi yöntemleri kullanıldı. Na, Mg, K, Ca, Fe, Zn,

Cu ve Mn düzeyleri sırasıyla 43.77 – 4905 mg/kg, 47.15

– 751 mg/kg, 44.84 – 2156 mg/kg, 95.29 – 1616 mg/kg,

69.70 – 144 mg/kg, 5.92 – 41.28 mg/kg, 3.57 – 13.25 mg/

kg ve 5.20 – 12.06 mg/kg aralığında bulundu. En yüksek

antioksidan kapasite değeri her iki antioksidan kapasite

analizinde de portakallı bardan elde edildi.

Keywords

Çölyak hastalığı, Atıştırmalık, Eser element, Antioksidan

Trace Element Content and Antioxidant Capacity of Gluten-Free Snacks Produced for Coeliac Disease Patients

Abstract

Trace element levels and antioxidant capacities of different

gluten-free snacks were investigated in this study. Samples were

digested by using microwave system. Na, Mg, K, Ca, Fe, Zn, Cu

and Mn levels were determined by inductively coupled plasma

mass spectrometry. Cupric reducing antioxidant capacity and

2,2-diphenyl-1-picrylhydrazyl radical scavenging capacity

methods were used to evaluate antioxidant capacity. Na, Mg, K,

Ca, Fe, Zn, Cu and Mn levels were found in the range of 43.77

– 4905 mg/kg, 47.15 – 751 mg/kg, 44.84 – 2156 mg/kg, 95.29

– 1616 mg/kg, 69.70 – 144 mg/kg, 5.92 – 41.28 mg/kg, 3.57 –

13.25 mg/kg and 5.20 – 12.06 mg/kg, respectively. The highest

antioxidant capacity value was obtained from orange bar in

both antioxidant capacity assays.

Keywords

Coeliac disease, Snack, Trace element, Antioxidant

References

• 1. Rashtak S, Murray JA. Review article: coeliac disease, new approaches to therapy. Aliment Pharm Therap 2012; 35: 768- 81. 2. Nylund L, Kaukinen K, Lindfors K. The microbiota as a component of the celiac disease and non-celiac gluten sensitivity. Clin Nutr 2016; 6: 17-24. 3. Tatar G, Elsurer R, Simsek H, Balaban YH, Hascelik G, Ozcebe OI, Buyukasik Y, Sokmensuer C. Screening of tissue transglutaminase antibody in healthy blood donors for celiac disease screening in the Turkish population. Digest Dis Sci 2004; 49: 1479-84. 4. Rosell CM, Barro F, Sousa C, Mena MC. Cereals for developing gluten-free products and analytical tools for gluten detection. J Cereal Sci 2014; 59: 354-64. 5. Wagner G, Zeiler M, Grylli V, Berger G, Huber WD, Woeber C, Rhind C, Karwautz A. Coeliac disease in adolescence: Coping strategies and personality factors affecting compliance with gluten-free diet. Appetite 2016; 101: 55-61. 6. Hua Z, Yu WZ, Xin Y, Tian ZH, Chun ZY, Jun DA, Jing JJW. Determination of free amino acids and 18 elements in freezedried strawberry and blueberry fruit using an Amino Acid Analyzer and ICP-MS with micro-wave digestion. Food Chem 2014; 147: 189-94. 7. Saturni L, Ferretti G, Bacchetti T. The gluten-free diet: Safety and nutritional quality. Nutrients 2010; 2: 16-34. 8. Jubete LA, Arendt EK, Gallagher E. Nutritive value of pseudocereals and their increasing use as functional glutenfree ingredients. Trends Food Sci Tech 2010; 21: 106-13. 9. Bressy FC, Brito GB, Barbosa IS, Teixeira LSG, Korn MGA. Determination of trace element concentrations in tomato samples at different stages of maturation by ICP OES and ICP-MS following microwave-assisted digestion. Microchem J 2013; 109: 145-9. 10. Nardi EP, Evangelista FS, Tormen L, Pierre TDS, Curtius AJ, Souza SSD, Barbosa FJ. The use of inductively coupled plasma mass spectrometry (ICP-MS) for the determination of toxic and essential elements in different types of food samples. Food Chem 2009; 112: 727-32. 11. Khan N, Choi JY, Nho EY, Jamila N, Habte G, Hong JH, Hwang IM, Kim KS. Determination of minor and trace elements in aromatic spices by micro-wave assisted digestion and inductively coupled plasma-mass spectrometry. Food Chem 2014; 158: 200-6. 12. Martinez EJL, Barrales PO, Cordova MLFD, Vidal AD, Medina AR. Investigation by ICP-MS of trace element levels in vegetable edible oils produced in Spain. Food Chem 2011; 127: 1257-62. 13. Brand-Williams W, Cuvelier ME, Berset C. Use of a free radical method to evaluate antioxidant activity. Lebensm Wiss Technol 1995; 28: 25-30. 14. Apak R, Güçlü K, Özyürek M, Çelik SE. Mechanism of antioxidant capacity assays and the CUPRAC (cupric ion reducing antioxidant capacity) assay. Microchim Acta 2008; 160: 413-9. 15. Missbach B, Schwingshackl L, Billmann A, Mystek A, Hickelsberger M, Bauer G, König J. Gluten- free food database: The nutritional quality and cost of packaged gluten-free foods. PeerJ 2015; 3:e1337 16. Filipcev B, Misan A, Saric B, Simurina O. Sugar beet molasses as an ingredient to enhance the nutritional and functional properties of gluten-free cookies. Int J Food Sci Nutr 2016; 67: 249-56. 17. Singh P, Prasad S, Aalbersberg W. Bioavailability of Fe and Zn in selected legumes, cereals, meat and milk products consumed in Fiji. Food Chem 2016; 207: 125-31. 18. Orecchio S, Amorello D, Raso M, Barreca S, Lino C, Di Gaudio F. Determination of trace elements in gluten-free food for celiac people by ICP-MS. Microchem J 2014; 116: 163-72. 19. Fraga CG. Relevance, essentiality and toxicity of trace elements in human health. Mol Aspects Med 2005; 26: 235-44. 20. Hidalgo MJ, Sgroppo SC, Camina JM, Marchevsky EJ, Pellerano RG. Trace element concentrations in commercial gluten-free amaranth bars. Food Measure 2015; 9: 426-34. 21. Zegarac JP, Valek L, Martinez S, Belscak A. Fluctuations in the phenolic content and antioxidant capacity of dark fruit juices in refrigerated storage. Food Chem 2009; 113: 394-400. 22. Wronkowska M, Zielinska D, Nowak DS, Troszynska A, Smietana MS. Antioxidative and reducing capacity, macroelements content and sensorial properties of buckwheat-enhanced gluten-free bread. Int J Food Sci Tech 2010; 45: 1993-2000. 23. Sakac M, Pestoric M, Misan A, Nedeljkovic N, Jambrec D, Jovanov P, Banjac V, Torbica A, Hadnadev M, Mandic A. Antioxidant capacity, mineral content and sensory properties of gluten-free rice and buckwheat cookies. Food Technol Biotech 2015; 53: 38-47.