Year 2015, Volume 1 , Issue 2, Pages 15 - 27 2015-12-25

OPTICAL, ELECTRICAL AND PHOTOELECTRICAL PROPERTIES OF QUERCETIN-CO(II) COMPLEX/N-SI ORGANIC-INORGANIC HYBRID DEVICE

Cihat Özaydın [1] , Ahmet Tombak [2] , Mehmet Boğa [3] , Tahsin Kılıçoğlu [4]


Quercetin is a member of the flavonoid’s class and colorful organic molecule widely distributed in nature. Quercetin is known as 2-(3,4-dihydroxyphenyl)-3,5,7-trihydroxy-4H-chromen-4-one with molecular formula C15H10O7. Also, quercetin has conjugated structure with 16 π-rich electrons. In this study, Quercetin cobalt (II) complex (Quercetin-Co(II) Complex) was synthesized. The thin films of synthesized quercetin cobalt (II) complex were formed on glass and semiconductor substrates by sol-gel spin coating technique. The absorption, reflection and transmittance spectra of the thin film were taken in 200-1100 nm wavelength range. The optical band gap of the film was determined from absorption studies and was found to be 2.59 eV for direct transitions and 1.90 eV for indirect transitions. The morphological properties of the thin film formed on the semiconductor substrates was analyzed by scanning electron microscopy (SEM) and atomic force microscopy (AFM). We fabricated Au/Quercetin-Co(II) Complex/n-Si organic-inorganic hybrid device to investigate electrical and photoelectrical properties. The current-voltage (I-V) measurement of the device was carried out at room temperature and in dark. The device has a rectification behavior with the ideality factor n of 1.55 and the barrier height ϕb of 0.77 eV. In addition, the short circuit current (Isc) and open circuit voltage (Voc) have been extracted from the I-V measurements under 100 mW/cm2 illumination conditions. Besides, the capacitance-voltage (C-V) characteristics of the device at different frequency and room temperature are discussed.


Quercetin-co(II) complex Thin film, Optical properties, Photoelectrical properties
  • [1] Ahn, K.-H., Ryu, G. Y., Youn, S.-W., & Shin, D.-M. (2004). The conjugation effects on the luminescence properties of oligophenylenes for the OLED. Materials Science and Engineering: C, 24(1–2), 163-165. doi:http://dx.doi.org/10.1016/j.msec.2003.09.010
  • [2] Bukhari, S. B., Memon, S., Tahir, M. M., Bhanger, M.I. (2008). Synthesis, characterization and antioxidant activity copper-quercetin complex. Journal of Molecular Structure, 892, 39–46. http://dx.doi.org/10.1016/j.saa.2008.07.030
  • [3] Card, H.C. & Rhoderick, E.H. (1971). Studies of tunnel MOS diodes I. Interface effects in silicon Schottky diodes. Journal of Physics D: Applied Physics, 4(10), 1589-1601. http://dx.doi.org/10.1088/0022-3727/4/10/319
  • [4] Chaieb, A., Vignau, L., Brown, R., Wantz, G., Huby, N., François, J., & Dagron-Lartigau, C. (2008). PL and EL properties of oligo(p-phenylene vinylene) (OPPV) derivatives and their applications in organic light-emitting diodes (OLED). Optical Materials, 31(1), 68-74. doi:http://dx.doi.org/10.1016/j.optmat.2008.01.012
  • [5] Chen, L., Deng, J., Gao, H., Yang, Q., Kong, L., Cui, M., Zhang, Z. (2016). Ellipsometric study and application of rubrene thin film in organic Schottky diode. Applied Surface Science, 388, 396-400. http://dx.doi.org/10.1016/j.apsusc.2015.12.111
  • [6] Evyapan, M., Kadem, B., Basova, T. V., Yushina, I. V., & Hassan, A. K. (2016). Study of the sensor response of spun metal phthalocyanine films to volatile organic vapors using surface plasmon resonance. Sensors and Actuators B: Chemical, 236, 605-613. doi:http://dx.doi.org/10.1016/j.snb.2016.05.070
  • [7] Haryanto, Wahyuningrum, D., & Alni, A. (2015). Study on the Nitration Reaction of N,N-diphenylamine Compounds and Its Characterization as Organic Light Emitting Diode (OLED) Material. Procedia Chemistry, 16, 586-591. doi:http://dx.doi.org/10.1016/j.proche.2015.12.096
  • [8] Güllü, Ö., Aydoğan, Ş., Türüt, A. (2012). High barrier Schottky diode with organic interlayer. Solid State Communications, 152 (5), 381-385 (2012). http://dx.doi.org/10.1016/j.ssc.2011.12.007
  • [9] Kösemen, Z. A., Kösemen, A., Öztürk, S., Canimkurbey, B., San, S. E., Yerli, Y., & Tunç, A. V. (2016). Effect of intrinsic polymer properties on the photo sensitive organic field-effect transistors (Photo-OFETs). Microelectronic Engineering, 161, 36-42. doi:http://dx.doi.org/10.1016/j.mee.2016.04.007
  • [10] Lim, C. J., Li, L., Lei, Y., Zhou, F., Wu, B., Liu, X., . . . Ng, S.-C. (2016). Synthesis and characterization of three thienopyridazine-based copolymers and their application in OFET. Tetrahedron Letters, 57(14), 1523-1527. doi:http://dx.doi.org/10.1016/j.tetlet.2016.02.049
  • [11] Nuhoğlu, Ç., & Gülen, Y. (2010). The effect of high temperature annealing on Schottky diode characteristics of Au/n-Si contacts. Vacuum, 84 (6), 812-816. http://dx.doi.org/10.1016/j.vacuum.2009.10.049
  • [12] Norde, H. (1979). A modified forward I‐V plot for Schottky diodes with high series resistance. J. Appl. Phys. 50, 5052. http://dx.doi.org/10.1063/1.325607
  • [13] Ozaydin, C., Akkilic, K. (2014). Electrical and photoelectrical properties of copper(II) complex/n-Si/Au heterojunction diode. American Journal of Optics and Photonics, 2(6), 69-74. http://dx.doi.org/10.11648/j.ajop.20140206.11
  • [14] Ozerden, E., Yildiz, M., Ocak, Y. S., Tombak, A., & Kilicoglu, T. (2014). An organic–inorganic rectifying contact based on a ZnPc derivative. Materials Science in Semiconductor Processing, 28(0), 72-76. doi:http://dx.doi.org/10.1016/j.mssp.2014.06.006
  • [15] Remya, R., & Deb, B. (2017). Ultrathin organic spin-on layers on indium tin oxide as a prospective tool for enhanced light throughput. Materials Letters, 186, 220-223. doi:http://dx.doi.org/10.1016/j.matlet.2016.10.008
  • [16] Sağlam, M., Cimilli, F. E., Türüt, A. (20049. Experimental determination of the laterally homogeneous barrier height of Au/n-Si Schottky barrier diodes. Physica B: Condensed Matter, 348 (1–4), 397-403. http://dx.doi.org/10.1016/j.physb.2004.01.002
  • [17] Shin, D., Lee, J.-Y., Hong, K.-Y., Park, J., & Seo, Y.-S. Slot-die coating of organic thin films for active-matrix organic light-emitting diode displays. Thin Solid Films. doi:http://dx.doi.org/10.1016/j.tsf.2016.11.001
  • [18] Sung, M. J., Kim, Y., Lee, S. B., Lee, G. B., An, T. K., Cha, H., . . . Kim, Y.-H. (2016). New dithienophosphole-based donor–acceptor alternating copolymers: Synthesis and structure property relationships in OFET. Dyes and Pigments, 125, 316-322. doi:http://dx.doi.org/10.1016/j.dyepig.2015.09.026
  • [19] Sze, S. M. & Ng, K. K.. (2007). Physics of Semiconductor Devices. 3rd ed., 111 River St, Hoboken, 07030 New Jersey: John Wiley and Sons, Inc.
  • [20] Tombak, A., Ocak, Y. S., Asubay, S., Kilicoglu, T., & Ozkahraman, F. (2014). Fabrication and electrical properties of an organic–inorganic device based on Coumarin 30 dye. Materials Science in Semiconductor Processing, 24, 187-192. doi:10.1016/j.mssp.2014.03.004
Subjects Physics, Applied
Journal Section Article
Authors

Author: Cihat Özaydın
Institution: Depart. Of Computer Engineering, Faculty of Engineering and Architecture, Batman University
Country: Trinidad and Tobago


Author: Ahmet Tombak
Institution: Depart. Of Physics, Faculty of Art&Science, Batman University
Country: Turkey


Author: Mehmet Boğa
Institution: Depart. Of Pharmaceutical Technology, Faculty of Pharmacy, Dicle University
Country: Turkey


Author: Tahsin Kılıçoğlu
Institution: Depart. Of Physics, Faculty of Science, Dicle University

Dates

Publication Date : December 25, 2015

Bibtex @research article { mejs336216, journal = {Middle East Journal of Science}, issn = {}, eissn = {2618-6136}, address = {}, publisher = {INESEG YAYINCILIK}, year = {2015}, volume = {1}, pages = {15 - 27}, doi = {10.23884/mejs.2015.1.2.01}, title = {OPTICAL, ELECTRICAL AND PHOTOELECTRICAL PROPERTIES OF QUERCETIN-CO(II) COMPLEX/N-SI ORGANIC-INORGANIC HYBRID DEVICE}, key = {cite}, author = {Özaydın, Cihat and Tombak, Ahmet and Boğa, Mehmet and Kılıçoğlu, Tahsin} }
APA Özaydın, C , Tombak, A , Boğa, M , Kılıçoğlu, T . (2015). OPTICAL, ELECTRICAL AND PHOTOELECTRICAL PROPERTIES OF QUERCETIN-CO(II) COMPLEX/N-SI ORGANIC-INORGANIC HYBRID DEVICE. Middle East Journal of Science , 1 (2) , 15-27 . DOI: 10.23884/mejs.2015.1.2.01
MLA Özaydın, C , Tombak, A , Boğa, M , Kılıçoğlu, T . "OPTICAL, ELECTRICAL AND PHOTOELECTRICAL PROPERTIES OF QUERCETIN-CO(II) COMPLEX/N-SI ORGANIC-INORGANIC HYBRID DEVICE". Middle East Journal of Science 1 (2015 ): 15-27 <https://dergipark.org.tr/en/pub/mejs/issue/31032/336216>
Chicago Özaydın, C , Tombak, A , Boğa, M , Kılıçoğlu, T . "OPTICAL, ELECTRICAL AND PHOTOELECTRICAL PROPERTIES OF QUERCETIN-CO(II) COMPLEX/N-SI ORGANIC-INORGANIC HYBRID DEVICE". Middle East Journal of Science 1 (2015 ): 15-27
RIS TY - JOUR T1 - OPTICAL, ELECTRICAL AND PHOTOELECTRICAL PROPERTIES OF QUERCETIN-CO(II) COMPLEX/N-SI ORGANIC-INORGANIC HYBRID DEVICE AU - Cihat Özaydın , Ahmet Tombak , Mehmet Boğa , Tahsin Kılıçoğlu Y1 - 2015 PY - 2015 N1 - doi: 10.23884/mejs.2015.1.2.01 DO - 10.23884/mejs.2015.1.2.01 T2 - Middle East Journal of Science JF - Journal JO - JOR SP - 15 EP - 27 VL - 1 IS - 2 SN - -2618-6136 M3 - doi: 10.23884/mejs.2015.1.2.01 UR - https://doi.org/10.23884/mejs.2015.1.2.01 Y2 - 2019 ER -
EndNote %0 Middle East Journal of Science OPTICAL, ELECTRICAL AND PHOTOELECTRICAL PROPERTIES OF QUERCETIN-CO(II) COMPLEX/N-SI ORGANIC-INORGANIC HYBRID DEVICE %A Cihat Özaydın , Ahmet Tombak , Mehmet Boğa , Tahsin Kılıçoğlu %T OPTICAL, ELECTRICAL AND PHOTOELECTRICAL PROPERTIES OF QUERCETIN-CO(II) COMPLEX/N-SI ORGANIC-INORGANIC HYBRID DEVICE %D 2015 %J Middle East Journal of Science %P -2618-6136 %V 1 %N 2 %R doi: 10.23884/mejs.2015.1.2.01 %U 10.23884/mejs.2015.1.2.01
ISNAD Özaydın, Cihat , Tombak, Ahmet , Boğa, Mehmet , Kılıçoğlu, Tahsin . "OPTICAL, ELECTRICAL AND PHOTOELECTRICAL PROPERTIES OF QUERCETIN-CO(II) COMPLEX/N-SI ORGANIC-INORGANIC HYBRID DEVICE". Middle East Journal of Science 1 / 2 (December 2015): 15-27 . https://doi.org/10.23884/mejs.2015.1.2.01
AMA Özaydın C , Tombak A , Boğa M , Kılıçoğlu T . OPTICAL, ELECTRICAL AND PHOTOELECTRICAL PROPERTIES OF QUERCETIN-CO(II) COMPLEX/N-SI ORGANIC-INORGANIC HYBRID DEVICE. MEJS. 2015; 1(2): 15-27.
Vancouver Özaydın C , Tombak A , Boğa M , Kılıçoğlu T . OPTICAL, ELECTRICAL AND PHOTOELECTRICAL PROPERTIES OF QUERCETIN-CO(II) COMPLEX/N-SI ORGANIC-INORGANIC HYBRID DEVICE. Middle East Journal of Science. 2015; 1(2): 27-15.