KINETICS OF ADSORPTION OF ACID RED 1 ONTO CHITOSAN AND CROSS-LINKED CHITOSAN FROM AQUEOUS SOLUTION

Year 2017, Volume: 3 Issue: 1, 20 - 25, 28.08.2017

Ayfer Yıldırım Yasemin Bulut

https://doi.org/10.23884/mejs.2017.3.1.03

Abstract

Chitosan(CS) and crosslinked-Chitosan (CCS) (Chitosan+Glutaraldehite) were utilized as adsorbents to remove acid red1(AR1) from aqueous solution by adsorption. Batch experiments were conducted to study initial concentration of adsorbate and temperature on dye adsorption. The kinetic data obtained from different batch experiments were analyzed using pseudo first-order and pseudo second-order and Weber-Morris equations, and the rate constants of first-order adsorption (kpf), the rate constants of second-order adsorption (kps) and intraparticle diffusion rate constants (kid) at these concentrations and temperatures were calculated, respectively.

Keywords

chitosan, adsorption, acid red1

References

• [1] Auta, M., Hameed, B.H. (2014) . Chitosan–clay composite as highly effective and low-cost adsorbent for batch andfixed-bed adsorption of methylene blue. Chemical Engineering Journal. 237, 352–361
• [2] Demarchi, C.A., Campos, M., Rodrigues, C.A.(2013). Adsorption of textile dye Reactive Red 120 by the chitosan-Fe(III)-crosslinked: Batch and fixed-bed studies. Journl of Environmental Chemical Engineering, 1, 1350-1358.
• [3] Liu, Y., Zheng, Y., Wang, A. (2010). Enhanced adsorption of Methylene Blue from aqueous solution bychitosan-g-poly (acrylic acid)/vermiculite hydrogel composites. Journal of Environmental Science, 22(4) 486–493
• [4] Wang, L., Han, B., Wang, Z., Dai, L., Zhou, H., Li, Y., & Wang, H. (2015). Effective improvement of sensing performance of amperometric NO2 sensor by Ag-modified nano-structured CuO sensing electrode. Sensors and Actuators B: Chemical, 207, Part A(0), 791-800. doi:http://dx.doi.org/10.1016/j.snb.2014.10.125
• [5] Yan, X., Hu, D., Li, H., Li, L., Chong, X., & Wang, Y. (2011). Nanostructure and optical properties of M doped ZnO (M=Ni, Mn) thin films prepared by sol–gel process. Physica B: Condensed Matter, 406(20), 3956-3962. doi:http://dx.doi.org/10.1016/j.physb.2011.07.037
• [6] Yang, C., Su, X., Xiao, F., Jian, J., & Wang, J. (2011). Gas sensing properties of CuO nanorods synthesized by a microwave-assisted hydrothermal method. Sensors and Actuators B: Chemical, 158(1), 299-303. doi:http://dx.doi.org/10.1016/j.snb.2011.06.024
• [7] Yildiz, A., Horzum, Ş., Serin, N., & Serin, T. (2014). Hopping conduction in In-doped CuO thin films. Applied Surface Science, 318(0), 105-107. doi:http://dx.doi.org/10.1016/j.apsusc.2014.01.118
• [8] Zhang, Y., Liu, Z., Zang, D., & Feng, L. (2014). Structural and opto-electrical properties of Cu–Al–O thin films prepared by magnetron sputtering method. Vacuum, 99(0), 160-165. doi:http://dx.doi.org/10.1016/j.vacuum.2013.05.019